Evaluation of Mass Transport Losses in Micro-Tubular Solid Oxide Fuel Cells Anodes

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Description
Solid Oxide Fuel Cells (SOFCs) generate electricity using only hydrogen and oxygen and they form H2O as the only byproduct, giving them the potential to significantly reduce carbon emissions and the impacts of global warming. In order to meet the

Solid Oxide Fuel Cells (SOFCs) generate electricity using only hydrogen and oxygen and they form H2O as the only byproduct, giving them the potential to significantly reduce carbon emissions and the impacts of global warming. In order to meet the global power demands today, SOFCs need to significantly increase their power density and improve robustness in startup and cycling operations. This study explores the impact of decreasing the anode thickness to improve the mass transport of the fuel through the anode of a micro-tubular (mT) SOFC because few studies have reported the correlation between the two. Decreasing the thickness decreases the chance for concentration overpotential which is caused by not enough of the reactants being able to reach the reaction site while products are not able to be removed quickly enough. Experiments were performed in a split tube furnace heated to 750°C with nickel-yttria stabilized zirconia (Ni-YSZ) supported cells. Pure hydrogen was supplied to the cell at rates of 10, 20, 30, and 40 mL/min while the cathode was supplied air from the environment. The cell's performance was studied using the current-voltage method to generate polarization curves and electrochemical impedance spectroscopy to create Bode and Nyquist plots. The results from the electrochemical impedance spectroscopy show a lower impedance for the frequencies pertaining to the gas diffusion in the anode for the thinner cells. This suggests that decreasing the anode thickness increases the mass transport of the gas. Additionally, through a distribution of relaxation times (DRT) analysis, the peaks vary between the two cell thicknesses at the frequencies pertaining to gas diffusion in anode-supported cells, implicating the decreased resistance created by thinning the anode layer.
Date Created
2023
Agent

Fabricating Micro-Tubular Solid Oxide Fuel Cells and Studying the Kinetics of CO and H2 as Fuels

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Description

One of the most promising technologies for creating power without emissions is Solid Oxide Fuel Cells (SOFC) because it uses oxygen and hydrogen to create electricity with the only byproduct being water. To figure out the optimal design of the

One of the most promising technologies for creating power without emissions is Solid Oxide Fuel Cells (SOFC) because it uses oxygen and hydrogen to create electricity with the only byproduct being water. To figure out the optimal design of the fuel cell, a literature review was conducted to determine the effects of adding both internal and external current collectors as well as the difference length has on the performance. To learn more about the kinetics of the reaction, hydrogen and carbon monoxide disappearance rates were measured to compare the rate at which each species disappears.

Date Created
2022-05
Agent