Laboratory and Field Evaluation of Enzyme Induced Carbonate Precipitation (EICP) for Fugitive Dust Mitigation

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Description
Enzyme induced carbonate precipitation (EICP) treatment is a stabilization method of dust mitigation that applies a spray-on treatment to form a soil crust and increase the wind erosion resistance of a disturbed soil surface. The purpose of this work was

Enzyme induced carbonate precipitation (EICP) treatment is a stabilization method of dust mitigation that applies a spray-on treatment to form a soil crust and increase the wind erosion resistance of a disturbed soil surface. The purpose of this work was to evaluate the EICP treatment with multiple field and laboratory test methods for measuring the wind erosion resistance of EICP treated soil. The threshold friction velocity (TFV) is defined as the minimum wind speed required to initiate continuous particle movement and represents the wind erosion resistance of a soil surface. Tested soil type and textures included a clean fine sand to a loamy sandy soil that contained a significant amount of fines. Dry untreated soil and disturbed field soil surfaces were compared to a chloride salt solution treatment and an EICP treatment solution in both laboratory and field testing to evaluate the wind erosion resistance of the treatments.
Date Created
2023
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Efficacy and Durability of Microbially/Enzyme-Induced Carbonate Precipitation (MICP/EICP) for Dust Mitigation of Various Soil Types and Under Different Environmental Conditions

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Description
Microbially- and enzyme-induced carbonate precipitation (EICP and MICP) offer potentially sustainable and cost-effective mitigation methods for fugitive dust by forming an erosion-resistant crust on the soil through precipitation of a natural calcium carbonate (CaCO3) cement. While there have been isolated

Microbially- and enzyme-induced carbonate precipitation (EICP and MICP) offer potentially sustainable and cost-effective mitigation methods for fugitive dust by forming an erosion-resistant crust on the soil through precipitation of a natural calcium carbonate (CaCO3) cement. While there have been isolated studies on the efficacy of the carbonate precipitation process, there are few systematic studies of the influence of the properties of the soil being treated (e.g., gradation, salt content) on the precipitation and the resulting wind erosion resistance. Moreover, the influence of environmental conditions on the durability of the crust formed by the induced carbonate precipitation has not been systematically investigated. In this research program, the efficacy and durability of EICP and MICP for dust mitigation were investigated for a variety of soil types and in different environmental conditions. Soil samples from seven sites with fugitive dust problems were treated with MICP or EICP and subjected to lab or field testing. The results of these tests showed that the effectiveness of biocementation treatment varies depending on the grain size distribution of soil and mineralogical composition. Testing on iron ore tailings materials demonstrated that treating by application of EICP solutions at lower concentrations (i.e., 0.5M and 0.75M of urea and calcium chloride) yielded effective results for poorly graded fine sand-sized tailings but the same solutions were ineffective for the well graded sand-sized tailings that contained large gravel-sized particles. Additionally, the application of MICP and EICP on sediments adjacent to a shrinking lake (the Salton Sea) with different salt contents exhibited enhanced performance in soils with lower salt content. The effect of temperature during deployment and precipitation cycles are shown to be significant environmental factors by simulating wetting-drying and freeze-thaw cycles in the laboratory. A dust-resistance crust formed through biocementation remained mostly intact after undergoing multiple cycles of wetting-drying. However, the durability of a dust-resistance crust formed through biocementation to multiple cycles of freeze-thaw depended on treatment solution concentration and soil grain size. Additionally, high temperature during field deployment of MICP adversely effected crust formation due to rapid evaporation that inhibited the complete hydrolysis of urea and the precipitation of carbonate.
Date Created
2023
Agent

Preliminary Study on Robotic Turning in Granular Media

Description
Underground robots, or "burrowbots," have the potential to revolutionize undergroundexploration and study subterranean environments. The objective of this thesis is to preliminary explore a turning mechanism in burrowbots inside granular media. Building on the recent progress on bio-mimetic self-burrowing robots, specifically, inspirations

Underground robots, or "burrowbots," have the potential to revolutionize undergroundexploration and study subterranean environments. The objective of this thesis is to preliminary explore a turning mechanism in burrowbots inside granular media. Building on the recent progress on bio-mimetic self-burrowing robots, specifically, inspirations were taken from both biological and engineering solutions for general angular motion over a single axis, inside granular media. The newly proposed robot draws turning inspiration from hydraulic skeleton found in organisms like earthworm, incorporating a segmented body with ball-socket joint connections that allow for greater flexibility and maneuverability like in the human spine and, using the pivot-based turning mechanism used in Tunnel Boring Machine. The focus of this thesis is on the bending and turning aspects of the robot. The design of the robot is described in detail, including the process used to assemble the segments and ball joints and including the control mechanism to initiate turning. The bending / turning capabilities of the robot are evaluated through physical testing in a controlled environment. The robot's performance is assessed in glass bead with 2 mm particle size. The results demonstrate that the robot's segmented design with the ball-socket joint connections enable it to turn inside the particulate media. This ability makes it a promising candidate for soil exploration tasks. The thesis proposes an analytical framework for the amount of torque required to rotate an elementary body (cylindrical rod) when compared to the segmented robot design, to understand the relationship of torque and angle inside granular media. In conclusion, this thesis initiates a preliminary study in the field of soil exploration through the development of a robot with a unique design inspired by biology, exploring the capabilities of an underground robot equipped with a turning mechanism that allows it to change direction. The results demonstrate that the robot is able to turn inside the media which can pave the way for future research and applications in the field of underground robotics. (Keywords: preliminary, granular media, burrowbots, ball-joint connection, segmenteddesign)
Date Created
2023
Agent

Stabilization of Expansive Soils Using Plant-Extracted Silicate Solution

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Description
Expansive soils pose considerable geotechnical and structural challenges all over the world. Many cities, towns, transport systems, and structures are built on expansive soils. This study evaluates stabilization of expansive soils using silicate solution extracted from rice husk taking advantage

Expansive soils pose considerable geotechnical and structural challenges all over the world. Many cities, towns, transport systems, and structures are built on expansive soils. This study evaluates stabilization of expansive soils using silicate solution extracted from rice husk taking advantage of an agricultural material waste. Rice husk ash production was optimized considering several factors including rinsing solution, rinsing temperature, burning time, and burning temperature. Results indicated that washing the rice husk with HCl (1M) produced an ash with surface area of 320 m2/g and 97% of silicon oxide. Two local soils were treated with sodium silicate solution, silica gel at pH 1.5, and silica gel at pH 4 to evaluate its mechanical properties at curing times of 1 day, 7 days, and 14 days. Results indicated that sodium silicate solution reduced the one-dimensional swell by 48% for Soil A, however, swell for soil B remained about the same. Silica gel at pH 1.5 reduced the one-dimensional swell by 67% for soil A and by 35% for soil B. Silica gel at pH 4 did also reduce the free swell by 40% for soil A and by 35% for soil B. Results also indicated that the swell pressures for all treated soils increased significantly compared to untreated soils. Soils treated with sodium silicate solution showed irregular compaction curves. Silica gel-treated soils showed a reduction in the maximum dry unit weight for both soils but optimum water content decreased for soil A and increased for soil B. Atterberg limits were also reduced for sodium silicate and silica gels-treated soils. Swelling index for bentonite showed a reduction by 53% for all treated bentonites. Soil-water characteristics curves (SWCC) for sodium silicate-treated soils remined almost the same as untreated soils. However, silica gels-treated soils retain more water. Surface area (SSA) decreased for sodium silicate-treated soil but increased for all silica gels-treated soils. It was concluded that curing times did not show additional improvement in most of the experiments, but the results remained about the same as 1-day treatment. The study demonstrated that silicate solution is promising and sustainable technique for stabilization of expansive soils.
Date Created
2020
Agent

Volume Change Behavior of Expansive Clay Stabilized with Bio-based Silica Gel

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Description
This document presents the assessment of the swelling behavior of expansive clay stabilized with bio-based silica gel and subjected to wetting and drying cycles. The expansive clay used in this research was obtained from Anthem, Arizona. Rice husk is a

This document presents the assessment of the swelling behavior of expansive clay stabilized with bio-based silica gel and subjected to wetting and drying cycles. The expansive clay used in this research was obtained from Anthem, Arizona. Rice husk is a rich silica by-product of rice production with commercial uses and applications in the industry. Rice husk ash from two different sources -California (named ASU) and India- were subjected to chemical characterization. Fourier Transform Infra-red Spectroscopy was used to verify the functional groups of the gel formed. Results showed differences between the ashes from different sources and confirmed the presence of silica structure bonds. X-Ray Diffraction (XRF) results showed that the ASU ash contained more amorphous silica than the Indian ash.One dimensional swell and consolidation tests were performed to investigate the volume change behavior of the untreated and silica gel treated remoulded samples. The free swell of the clay decreased from 12.3% (untreated sample) to 7.2% (ASU sample) and 11.4% (Indian sample). The effect of the wet and dry cycles on the swelling and consolidation characteristics of the untreated clay demonstrated that the treatment is irreversible after three cycles. Swelling of clay treated with ASU ash was reduced after the first cycle, while that of the clay treated with Indian ash was reduced after three cycles. This was due to the gelation time difference between treatments. Scanning Electron Microscopy images showed that the structure of the untreated clay was discontinuous, flaky and without aggregations whereas particles in the treated samples were aggregated and new bonds were created, decreasing the surface area. The X-Ray Diffraction (XRF) results showed that the main mineral responsible for expansive behavior of the clay studied was illite. The d-spacing of the illite decreased from 4.47Å for the untreated clay to 3.33Å for the treated clay. This study demonstrates a promising technique for clay swelling reduction and a more sustainable solution than that available to current practicing engineering.
Date Created
2020
Agent

Properties of Sand Stabilized with Bio-Based Sodium Silicate Solution

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Description
This study evaluates the use of plant-extracted silica solution as a bio-based grout material for improvement of granular soils. Although silicate grout is a very well-established and popular technique in the ground improvement market, efforts have been initiated to replace

This study evaluates the use of plant-extracted silica solution as a bio-based grout material for improvement of granular soils. Although silicate grout is a very well-established and popular technique in the ground improvement market, efforts have been initiated to replace chemically-synthesized silicate grout with plant-extracted silica grout. This initiative will increase the level of sustainability and consequently improve the existing market acceptability. The silica-rich plant source used for extraction was rice husk, which is an abundantly produced agricultural waste. The extraction method includes acid-leaching, temperature-controlled rice husk ash production and the preparation of an aqueous sodium silicate solution from the ash through an alkaline leachate method. Silica ash was in amorphous form containing 95% of silica content which is suitable for soil treatment. Gelation time was controlled in the absence and presence of sand under different pH values. Bio-based silica grouting showed an improvement of the shear strength of the soil as well as the hydraulic conductivity reduction.
Date Created
2019
Agent

Safety of Earthen Stormwater Infiltration Best Management Practices (BMP) Adjacent to Highways

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Description
The California Department of Transportation (Caltrans) is required to comply

with the National Pollution Discharge Elimination (NPDES) permit, which includes the infiltration of stormwater runoff from highways and implementing soil based best managements practices (BMPs). Stormwater BMPs are in place

The California Department of Transportation (Caltrans) is required to comply

with the National Pollution Discharge Elimination (NPDES) permit, which includes the infiltration of stormwater runoff from highways and implementing soil based best managements practices (BMPs). Stormwater BMPs are in place to prevent pollution in stormwater runoff as well as to facilitate the stormwater discharge from the road. Per this new permit, Caltrans is to install soil based BMPs that can absorb the 85th percentile of a 24-hour stormwater event. In order to absorb the stormwater runoff, the area used is the Clear Recovery Zone (CRZ), which are the road embankments/slopes located adjacent to the roadside. The CRZ must be traversable and recoverable in order to meet roadside traffic safety standards. A major concern for Caltrans is the uncertainty on how these BMPs will affect the safety of a vehicle, if a vehicle were to interact with the soft soils.

In order to provide an insight on the effects of the BMPs, the modeling and simulation of vehicle dynamics under certain interactions between the roadside, soil, and vehicle was completed. The research used computer simulations to quantify the probability of rollover accidents under several different vehicle, driving and ground conditions. The vehicles traversing typical archetype roadsides on soft soil are simulated using MsMac3D software. It was important to model the properties of the vehicle, roadside, mechanical and hydraulic properties of soils realistically in order to obtain an accurate representation of a real-world vehicle and soil interaction.

The outcome was a library of simulations that provided quantifiable data on the effect that soft soils have on the safety and rollover potential of a vehicle traversing the CRZ.
Date Created
2019
Agent