Description

Two pentacoordinate mononuclear iron carbonyls of the form (bdt)Fe(CO)P[subscript 2] [bdt = benzene-1,2-dithiolate; P[subscript 2] = 1,1′-diphenylphosphinoferrocene (1) or methyl-2-{bis(diphenylphosphinomethyl)amino}acetate (2)] were prepared as functional, biomimetic models for the distal

Two pentacoordinate mononuclear iron carbonyls of the form (bdt)Fe(CO)P[subscript 2] [bdt = benzene-1,2-dithiolate; P[subscript 2] = 1,1′-diphenylphosphinoferrocene (1) or methyl-2-{bis(diphenylphosphinomethyl)amino}acetate (2)] were prepared as functional, biomimetic models for the distal iron (Fe[subscript d]) of the active site of [FeFe]-hydrogenase. X-ray crystal structures of the complexes reveal that, despite similar ν(CO) stretching band frequencies, the two complexes have different coordination geometries.

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Date Created
  • 2014-09-01
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  • Text
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    Identifier
    • Digital object identifier: 10.1021/ic5012988
    • Identifier Type
      International standard serial number
      Identifier Value
      0020-1669
    • Identifier Type
      International standard serial number
      Identifier Value
      1520-510X

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    Roy, Souvik, Mazinani, Shobeir K. S., Groy, Thomas L., Gan, Lu, Tarakeshwar, Pilarisetty, Mujica, Vladimiro, & Jones, Anne K. (2014). Catalytic Hydrogen Evolution by Fe(II) Carbonyls Featuring a Dithiolate and a Chelating Phosphine. INORGANIC CHEMISTRY, 53(17), 8919-8929. http://dx.doi.org/10.1021/ic5012988

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