Description

Using non-linear dielectric techniques, we have measured the dynamics of 5-methyl-3-heptanol at a temperature at which the Kirkwood correlation factor g[subscript K] indicates the coexistence of ring- and chain-like hydrogen-bonded

Using non-linear dielectric techniques, we have measured the dynamics of 5-methyl-3-heptanol at a temperature at which the Kirkwood correlation factor g[subscript K] indicates the coexistence of ring- and chain-like hydrogen-bonded structures. Steady state permittivity spectra recorded in the presence of a high dc bias electric field (17 MV/m) reveal that both the amplitude and the time constant are increased by about 10% relative to the low field limit.

application/pdf

Download count: 0

Details

Contributors
Date Created
  • 2016-08-16
Resource Type
  • Text
  • Collections this item is in
    Identifier
    • Digital object identifier: 10.1063/1.4961022
    • Identifier Type
      International standard serial number
      Identifier Value
      1833-3672
    • Identifier Type
      International standard serial number
      Identifier Value
      1839-3527
    Note

    Citation and reuse

    Cite this item

    This is a suggested citation. Consult the appropriate style guide for specific citation guidelines.

    Young-Gonzales, A. R., & Richert, R. (2016). Field induced changes in the ring/chain equilibrium of hydrogen bonded structures: 5-methyl-3-heptanol. The Journal of Chemical Physics, 145(7), 074503. doi:10.1063/1.4961022

    Machine-readable links