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- Genre: Masters Thesis
Description
The use of Reclaimed Asphalt Pavements (RAP) in newly produced asphalt mixtures has been gaining a wide attention from state Departments of Transportations (DOTs) during the past four decades. However, the performance of these mixtures in harsh and hot climate areas such as Phoenix, Arizona has not been carefully addressed. This research focuses on evaluating the laboratory and field performance of Hot Mix Asphalt Mixtures (HMA) produced with two different RAP contents 15%, and 25%. A road section was identified by the City of Phoenix where three test sections were constructed; the first being a control (0% RAP), the second and the third sections with 15% and 25% RAP contents, respectively. The 25% RAP mixture used a lower Performance Grade (PG) asphalt per local practices. During construction, loose HMA mixtures were sampled and transported to the laboratory for advanced material characterization.
The testing included Dynamic Modulus (DM) test to characterize the stiffness of the material, Flow Number (FN) test to characterize the rutting resistance of the mixtures, IDEAL CT test to characterize the crack initiation properties, C* Fracture test to investigate the crack propagation properties, Uniaxial Fatigue to evaluate fatigue cracking potential, and Tensile Strength Ratio test (TSR) to evaluate the moisture susceptibility. Field cores were obtained from each test section and were tested for indirect tensile strength characteristics. In addition, asphalt binder testing was done on the extracted and recovered binders.
The laboratory results, compared to the control mixture, indicated that adding 15% and 25% RAP to the mix did not have significant effect on the stiffness, improved the rutting potential, had comparable cracking potential, and gave an acceptable passing performance against potential moisture damage. The binder testing that was done on the extracted and recovered binders indicated that the blended RAP binder yields a high stiffness. Based on results obtained from this study, it is recommended that the City of Phoenix should consider incorporating RAP in their asphalt mixtures using these low to moderate RAP contents. In the future implementation process, it is also recommended to include specifications where proper mixture designs are followed and supported with some of the laboratory tests outlined in this research.
The testing included Dynamic Modulus (DM) test to characterize the stiffness of the material, Flow Number (FN) test to characterize the rutting resistance of the mixtures, IDEAL CT test to characterize the crack initiation properties, C* Fracture test to investigate the crack propagation properties, Uniaxial Fatigue to evaluate fatigue cracking potential, and Tensile Strength Ratio test (TSR) to evaluate the moisture susceptibility. Field cores were obtained from each test section and were tested for indirect tensile strength characteristics. In addition, asphalt binder testing was done on the extracted and recovered binders.
The laboratory results, compared to the control mixture, indicated that adding 15% and 25% RAP to the mix did not have significant effect on the stiffness, improved the rutting potential, had comparable cracking potential, and gave an acceptable passing performance against potential moisture damage. The binder testing that was done on the extracted and recovered binders indicated that the blended RAP binder yields a high stiffness. Based on results obtained from this study, it is recommended that the City of Phoenix should consider incorporating RAP in their asphalt mixtures using these low to moderate RAP contents. In the future implementation process, it is also recommended to include specifications where proper mixture designs are followed and supported with some of the laboratory tests outlined in this research.
ContributorsZalghout, Ali Ahmad (Author) / Kaloush, Kamil (Thesis advisor) / Fini, Elham (Committee member) / Mamlouk, Michael (Committee member) / Arizona State University (Publisher)
Created2019
Description
Polypropylene, a non-biodegradable plastic with a higher c-c bond disassociation energy than other conventional polymers like Polyethylene (PE), is used to manufacture these three-layered masks. The amount of plastic pollution in the environment has grown tremendously, nearing million tons in a short period of time. As a result, the purpose of this study is to reduce the environmental damage caused by facemasks. This M.S. thesis offers a concise overview of various thermochemical methods employed to depolymerize plastic waste materials. It emphasizes environmentally conscious and sustainable practices, specifically focusing on solvothermal processing. This innovative approach aims to convert discarded face masks into valuable resources, including hydrocarbons suitable for jet fuel and other useful products.
The thesis provides an in-depth exploration of experimental investigations into solvothermal liquefaction techniques. Operating under specific conditions, namely, a temperature of 350°C and a reaction duration of 90 minutes, the results were notably impressive. These results included an exceptional conversion rate of 99.8%, an oil yield of 39.3%, and higher heating values (HHV) of 46.81 MJ/kg for the generated oil samples. It's worth noting that the HHV of the oil samples obtained through the solvothermal liquefaction (STL) method, at 46.82 MJ/kg, surpasses the HHV of gasoline, which stands at 43.4 MJ/kg.
The significant role of the solvent in the depolymerization process involves the dissolution and dispersion of the feedstock through solvation. This reduces the required thermal cracking temperature by enhancing mass and thermal energy transfer. While solvolysis reactions between the solvent and feedstock are limited in thermal liquefaction, the primary depolymerization process follows thermal cracking. This involves the random scission of polypropylene (PP) molecules during heat treatment, with minimal polymerization, cyclization, and radical recombination reactions occurring through free radical mechanisms.
Overall, this work demonstrates the feasibility of a highly promising technique for the effective chemical upcycling of polypropylene-based plastics into valuable resources, particularly in the context of jet fuel hydrocarbons, showcasing the comprehensive analytical methods employed to characterize the products of this innovative process.
ContributorsAkula, kapil Chandra (Author) / Deng, Shuguang (Thesis advisor) / Fini, Elham (Committee member) / Salifu, Emmanuel (Committee member) / Arizona State University (Publisher)
Created2023