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- Genre: Masters Thesis
Description
The morphology of mountainous areas is strongly influenced by stream bed incision rates, but most studies of landscape evolution consider erosion at basin scales or larger. The research here attempts to understand the smaller-scale mechanics of erosion on exposed bedrock channels in the conceptual framework of an established saltation-abrasion model by Sklar and Dietrich [2004]. The recirculating flume used in this experiment allows independent control of bed slope, water discharge rate, sediment flux, and sediment grain size – all factors often bundled together in simple models of river incision and typically cross-correlated in natural settings. This study investigates the mechanics of erosion on exposed bedrock channels caused by abrasion of transported particles. Of particular interest are saltating particles, as well as sediment near the threshold between saltation and suspension - sediment vigorously transported but with significant interaction with the bed. The size of these erosive tools are varied over an order of magnitude in mean grain diameter, including a sand of D¬50 = 0.56 mm, and three gravel sizes of 3.39, 4.63, and 5.88 mm. Special consideration was taken to prevent any flow conditions that created a persistent alluvial cover. The erodible concrete substrate is fully exposed at all times during experiments reported here. Rates of erosion into the concrete substrate (a bedrock proxy) were measured by comparing topographic data before and after each experimental run, made possible by a precision laser mounted on a high speed computer-controlled cart. The experimental flume was able to produce flow discharge as high as 75 liters per second, sediment fluxes (of many varieties) up to 215 grams per second, and bed slopes up to 10%. I find a general positive correlation is found between erosion rate and bed slope, shear stress, grain size, and sediment flux.
ContributorsAdams, Mark (Author) / Whipple, Kelin (Thesis advisor) / Heimsath, Arjun (Committee member) / Schmeeckle, Mark (Committee member) / Arizona State University (Publisher)
Created2016
Description
Banded iron formations (BIFs) are among the earliest possible indicators for oxidation of the Archean biosphere. However, the origin of BIFs remains debated. Proposed formation mechanisms include oxidation of Fe(II) by O2 (Cloud, 1973), photoferrotrophy (Konhauser et al., 2002), and abiotic UV photooxidation (Braterman et al., 1983; Konhauser et al., 2007). Resolving this debate could help determine whether BIFs are really indicators of O2, biological activity, or neither.
To examine the viability of abiotic UV photooxidation of Fe, laboratory experiments were conducted in which Fe-bearing solutions were irradiated with different regions of the ultraviolet (UV) spectrum and Fe oxidation and precipitation were measured. The goal was to revisit previous experiments that obtained conflicting results, and extend these experiments by using a realistic bicarbonate buffered solution and a xenon (Xe) lamp to better match the solar spectrum and light intensity.
In experiments reexamining previous work, Fe photooxidation and precipitation was observed. Using a series of wavelength cut-off filters, the reaction was determined not to be caused by light > 345 nm. Experiments using a bicarbonate buffered solution, simulating natural waters, and using unbuffered solutions, as in prior work showed the same wavelength sensitivity. In an experiment with a Xe lamp and realistic concentrations of Archean [Fe(II)], Fe precipitation was observed in hours, demonstrating the ability for photooxidation to occur significantly in a simulated natural setting.
These results lead to modeled Fe photooxidation rates of 25 mg Fe cm-2 yr-1—near the low end of published BIF deposition rates, which range from 9 mg Fe cm-2 yr-1 to as high as 254 mg Fe cm-2 yr-1 (Konhauser et al., 2002; Trendall and Blockley, 1970). Because the rates are on the edge and the model has unquantified, favorable assumptions, these results suggest that photooxidation could contribute to, but might not be completely responsible for, large rapidly deposited BIFs such those in the Hamersley Basin. Further work is needed to improve the model and test photooxidation with other solution components. Though possibly unable to fully explain BIFs, UV light has significant oxidizing power, so the importance of photooxidation in the Archean as an environmental process and its impact on paleoredox proxies need to be determined.
To examine the viability of abiotic UV photooxidation of Fe, laboratory experiments were conducted in which Fe-bearing solutions were irradiated with different regions of the ultraviolet (UV) spectrum and Fe oxidation and precipitation were measured. The goal was to revisit previous experiments that obtained conflicting results, and extend these experiments by using a realistic bicarbonate buffered solution and a xenon (Xe) lamp to better match the solar spectrum and light intensity.
In experiments reexamining previous work, Fe photooxidation and precipitation was observed. Using a series of wavelength cut-off filters, the reaction was determined not to be caused by light > 345 nm. Experiments using a bicarbonate buffered solution, simulating natural waters, and using unbuffered solutions, as in prior work showed the same wavelength sensitivity. In an experiment with a Xe lamp and realistic concentrations of Archean [Fe(II)], Fe precipitation was observed in hours, demonstrating the ability for photooxidation to occur significantly in a simulated natural setting.
These results lead to modeled Fe photooxidation rates of 25 mg Fe cm-2 yr-1—near the low end of published BIF deposition rates, which range from 9 mg Fe cm-2 yr-1 to as high as 254 mg Fe cm-2 yr-1 (Konhauser et al., 2002; Trendall and Blockley, 1970). Because the rates are on the edge and the model has unquantified, favorable assumptions, these results suggest that photooxidation could contribute to, but might not be completely responsible for, large rapidly deposited BIFs such those in the Hamersley Basin. Further work is needed to improve the model and test photooxidation with other solution components. Though possibly unable to fully explain BIFs, UV light has significant oxidizing power, so the importance of photooxidation in the Archean as an environmental process and its impact on paleoredox proxies need to be determined.
ContributorsCastleberry, Parker (Author) / Anbar, Ariel D (Thesis advisor) / Herckes, Pierre (Committee member) / Lyons, James (Committee member) / Arizona State University (Publisher)
Created2017
Description
The following thesis document entitled, "A 'Reasonable Reader of Poetry's' Briefed Introduction: A Sam Harris Application on the Lack of Authorship in Poetry and Poems" explores the concept of writing itself applied to the world of poetry. This document uses Sam Harris' critique and redefinition of free will as an illusion applied to authorship and the concept of self within poetry. This thesis upholds Sam Harris' application of the illusion of free will against and within conventions of experimental poetry to do with the persona poem, deviated syntax, memory, Confessionalist poetry, and so on. The document pulls in examples from Modernist poetry, Confessionalist poetry, prose poetry, contemporary poetry, L=A=N=G=U=A=G=E poetry, and experimental poetry. This thesis ends with the conclusion that further research needs to be done with regard to how this lack of authorship applies to copyright law within the poetry field.
ContributorsBoca, Ana (Author) / Hummer, Terry (Thesis advisor) / Dubie, Norman (Committee member) / Savard, Jeannine (Committee member) / Arizona State University (Publisher)
Created2015