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Description
At present, almost 70% of the electric energy in the United States is produced utilizing fossil fuels. Combustion of fossil fuels contributes CO2 to the atmosphere, potentially exacerbating the impact on global warming. To make the electric power system (EPS) more sustainable for the future, there has been an emphasis

At present, almost 70% of the electric energy in the United States is produced utilizing fossil fuels. Combustion of fossil fuels contributes CO2 to the atmosphere, potentially exacerbating the impact on global warming. To make the electric power system (EPS) more sustainable for the future, there has been an emphasis on scaling up generation of electric energy from wind and solar resources. These resources are renewable in nature and have pollution free operation. Various states in the US have set up different goals for achieving certain amount of electrical energy to be produced from renewable resources. The Southwestern region of the United States receives significant solar radiation throughout the year. High solar radiation makes concentrated solar power and solar PV the most suitable means of renewable energy production in this region. However, the majority of the projects that are presently being developed are either residential or utility owned solar PV plants. This research explores the impact of significant PV penetration on the steady state voltage profile of the electric power transmission system. This study also identifies the impact of PV penetration on the dynamic response of the transmission system such as rotor angle stability, frequency response and voltage response after a contingency. The light load case of spring 2010 and the peak load case of summer 2018 have been considered for analyzing the impact of PV. If the impact is found to be detrimental to the normal operation of the EPS, mitigation measures have been devised and presented in the thesis. Commercially available software tools/packages such as PSLF, PSS/E, DSA Tools have been used to analyze the power network and validate the results.
ContributorsPrakash, Nitin (Author) / Heydt, Gerald T. (Thesis advisor) / Vittal, Vijay (Thesis advisor) / Ayyanar, Raja (Committee member) / Arizona State University (Publisher)
Created2013
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Description
ABSTRACT The heat recovery steam generator (HRSG) is a key component of Combined Cycle Power Plants (CCPP). The exhaust (flue gas) from the CCPP gas turbine flows through the HRSG − this gas typically contains a high concentration of NO and cannot be discharged directly to the atmosphere because of

ABSTRACT The heat recovery steam generator (HRSG) is a key component of Combined Cycle Power Plants (CCPP). The exhaust (flue gas) from the CCPP gas turbine flows through the HRSG − this gas typically contains a high concentration of NO and cannot be discharged directly to the atmosphere because of environmental restrictions. In the HRSG, one method of reducing the flue gas NO concentration is to inject ammonia into the gas at a plane upstream of the Selective Catalytic Reduction (SCR) unit through an injection grid (AIG); the SCR is where the NO is reduced to N2 and H2O. The amount and spatial distribution of the injected ammonia are key considerations for NO reduction while using the minimum possible amount of ammonia. This work had three objectives. First, a flow network model of the Ammonia Flow Control Unit (AFCU) was to be developed to calculate the quantity of ammonia released into the flue gas from each AIG perforation. Second, CFD simulation of the flue gas flow was to be performed to obtain the velocity, temperature, and species concentration fields in the gas upstream and downstream of the SCR. Finally, performance characteristics of the ammonia injection system were to be evaluated. All three objectives were reached. The AFCU was modeled using JAVA - with a graphical user interface provided for the user. The commercial software Fluent was used for CFD simulation. To evaluate the efficacy of the ammonia injection system in reducing the flue gas NO concentration, the twelve butterfly valves in the AFCU ammonia delivery piping (risers) were throttled by various degrees in the model and the NO concentration distribution computed for each operational scenario. When the valves were kept fully open, it was found that it led to a more uniform reduction in NO concentration compared to throttling the valves such that the riser flows were equal. Additionally, the SCR catalyst was consumed somewhat more uniformly, and ammonia slip (ammonia not consumed in reaction) was found lower. The ammonia use could be decreased by 10 percent while maintaining the NO concentration limit in the flue gas exhausting into the atmosphere.
ContributorsAdulkar, Sajesh (Author) / Roy, Ramendra (Thesis advisor) / Lee, Taewoo (Thesis advisor) / Phelan, Patrick (Committee member) / Arizona State University (Publisher)
Created2011
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Description
Nanoparticles are ubiquitous in various fields due to their unique properties not seen in similar bulk materials. Among them, core-shell composite nanoparticles are an important class of materials which are attractive for their applications in catalysis, sensing, electromagnetic shielding, drug delivery, and environmental remediation. This dissertation focuses on the study

Nanoparticles are ubiquitous in various fields due to their unique properties not seen in similar bulk materials. Among them, core-shell composite nanoparticles are an important class of materials which are attractive for their applications in catalysis, sensing, electromagnetic shielding, drug delivery, and environmental remediation. This dissertation focuses on the study of core-shell type of nanoparticles where a polymer serves as the core and inorganic nanoparticles are the shell. This is an interesting class of supramolecular building blocks and can "exhibit unusual, possibly unique, properties which cannot be obtained simply by co-mixing polymer and inorganic particles". The one-step Pickering emulsion polymerization method was successfully developed and applied to synthesize polystyrene-silica core-shell composite particles. Possible mechanisms of the Pickering emulsion polymerization were also explored. The silica nanoparticles were thermodynamically favorable to self-assemble at liquid-liquid interfaces at the initial stage of polymerization and remained at the interface to finally form the shells of the composite particles. More importantly, Pickering emulsion polymerization was employed to synthesize polystyrene/poly(N-isopropylacrylamide) (PNIPAAm)-silica core-shell nanoparticles with N-isopropylacrylamide incorporated into the core as a co-monomer. The composite nanoparticles were temperature sensitive and could be up-taken by human prostate cancer cells and demonstrated effectiveness in drug delivery and cancer therapy. Similarly, by incorporating poly-2-(N,N)-dimethylamino)ethyl methacrylate (PDMA) into the core, pH sensitive core-shell composite nanoparticles were synthesized and applied as effective carriers to release a rheological modifier upon a pH change. Finally, the research focuses on facile approaches to engineer the transition of the temperature-sensitive particles and develop composite core-shell nanoparticles with a metallic shell.
ContributorsSanyal, Sriya (Author) / Dai, Lenore L. (Thesis advisor) / Jiang, Hanqing (Committee member) / Lind, Mary L. (Committee member) / Phelan, Patrick (Committee member) / Rege, Kaushal (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Shunt capacitors are often added in transmission networks at suitable locations to improve the voltage profile. In this thesis, the transmission system in Arizona is considered as a test bed. Many shunt capacitors already exist in the Arizona transmission system and more are planned to be added. Addition of

Shunt capacitors are often added in transmission networks at suitable locations to improve the voltage profile. In this thesis, the transmission system in Arizona is considered as a test bed. Many shunt capacitors already exist in the Arizona transmission system and more are planned to be added. Addition of these shunt capacitors may create resonance conditions in response to harmonic voltages and currents. Such resonance, if it occurs, may create problematic issues in the system. It is main objective of this thesis to identify potential problematic effects that could occur after placing new shunt capacitors at selected buses in the Arizona network. Part of the objective is to create a systematic plan for avoidance of resonance issues.

For this study, a method of capacitance scan is proposed. The bus admittance matrix is used as a model of the networked transmission system. The calculations on the admittance matrix were done using Matlab. The test bed is the actual transmission system in Arizona; however, for proprietary reasons, bus names are masked in the thesis copy in-tended for the public domain. The admittance matrix was obtained from data using the PowerWorld Simulator after equivalencing the 2016 summer peak load (planning case). The full Western Electricity Coordinating Council (WECC) system data were used. The equivalencing procedure retains only the Arizona portion of the WECC.

The capacitor scan results for single capacitor placement and multiple capacitor placement cases are presented. Problematic cases are identified in the form of ‘forbidden response. The harmonic voltage impact of known sources of harmonics, mainly large scale HVDC sources, is also presented.

Specific key results for the study indicated include:

• The forbidden zones obtained as per the IEEE 519 standard indicates the bus 10 to be the most problematic bus.

• The forbidden zones also indicate that switching values for the switched shunt capacitor (if used) at bus 3 should be should be considered carefully to avoid resonance condition from existing.

• The highest sensitivity of 0.0033 per unit for HVDC sources of harmonics was observed at bus 7 when all the HVDC sources were active at the same time.
ContributorsPatil, Hardik U (Author) / Heydt, Gerald T (Thesis advisor) / Karady, George G. (Committee member) / Ayyanar, Raja (Committee member) / Arizona State University (Publisher)
Created2015
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Description
In this study, two novel sorbents (zeolite 4A and sodium polyacrylate) are tested to investigate if utilizing ultrasonic acoustic energy could decrease the amount of time and overall energy required to regenerate these materials for use in cooling applications. To do this, an experiment was designed employing a cartridge heater

In this study, two novel sorbents (zeolite 4A and sodium polyacrylate) are tested to investigate if utilizing ultrasonic acoustic energy could decrease the amount of time and overall energy required to regenerate these materials for use in cooling applications. To do this, an experiment was designed employing a cartridge heater and a piezoelectric element to be simultaneously providing heat and acoustic power to a custom designed desorption bed while measuring the bed mass and sorbent temperature at various locations. The results prove to be promising showing that early in the desorption process ultrasound may expedite the desorption process in zeolite by as much as five times and in sodium polyacrylate as much as three times in comparison to providing heat alone. The results also show that in zeolite desorption utilizing ultrasound may be particularly beneficial to initiate desorption whereas in sodium polyacrylate ultrasound appears most promising in the after a temperature threshold is met. These are exciting results and may prove to be significant in the future as more novel heat-based cooling cycles are developed.
ContributorsBertrand, Weston Kyle (Author) / Phelan, Patrick (Thesis advisor) / Bocanegra, Luis (Committee member) / Wang, Liping (Committee member) / Devasenathipathy, Shankar (Committee member) / Arizona State University (Publisher)
Created2018
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Description
Hydrogel polymers have been the subject of many studies, due to their fascinating ability to alternate between being hydrophilic and hydrophobic, upon the application of appropriate stimuli. In particular, thermo-responsive hydrogels such as N-Isopropylacrylamide (NIPAM), which possess a unique lower critical solution temperature (LCST) of 32°C, have been leveraged for

Hydrogel polymers have been the subject of many studies, due to their fascinating ability to alternate between being hydrophilic and hydrophobic, upon the application of appropriate stimuli. In particular, thermo-responsive hydrogels such as N-Isopropylacrylamide (NIPAM), which possess a unique lower critical solution temperature (LCST) of 32°C, have been leveraged for membrane-based processes such as using NIPAM as a draw agent for forward osmosis (FO) desalination. The low LCST temperature of NIPAM ensures that fresh water can be recovered, at a modest energy cost as compared to other thermally based desalination processes which require water recovery at higher temperatures. This work studies by experimentation, key process parameters involved in desalination by FO using NIPAM and a copolymer of NIPAM and Sodium Acrylate (NIPAM-SA). It encompasses synthesis of the hydrogels, development of experiments to effectively characterize synthesized products, and the measuring of FO performance for the individual hydrogels. FO performance was measured using single layers of NIPAM and NIPAM-SA respectively. The values of permeation flux obtained were compared to relevant published literature and it was found to be within reasonable range. Furthermore, a conceptual design for future large-scale implementation of this technology is proposed. It is proposed that perhaps more effort should focus on physical processes that have the ability to increase the low permeation flux of hydrogel driven FO desalination systems, rather than development of novel classes of hydrogels
ContributorsAbdullahi, Adnan None (Author) / Phelan, Patrick (Thesis advisor) / Wang, Robert (Committee member) / Dai, Lenore (Committee member) / Arizona State University (Publisher)
Created2019
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Description
Thermodynamic development and balance of plant study is completed for a 30 MW solar thermochemical water splitting process that generates hydrogen gas and electric power. The generalized thermodynamic model includes 23 components and 45 states. Quasi-steady state simulations are completed for design point system sizing, annual performance analysis and sensitivity

Thermodynamic development and balance of plant study is completed for a 30 MW solar thermochemical water splitting process that generates hydrogen gas and electric power. The generalized thermodynamic model includes 23 components and 45 states. Quasi-steady state simulations are completed for design point system sizing, annual performance analysis and sensitivity analysis. Detailed consideration is given to water splitting reaction kinetics with governing equations generalized for use with any redox-active metal oxide material. Specific results for Ceria illustrate particle reduction in two solar receivers for target oxygen partial pressure of 10 Pa and particle temperature of 1773 K at a design point DNI of 900 W/m2. Sizes of the recuperator, steam generator and hydrogen separator are calculated at the design point DNI to achieve 100,000 kg of hydrogen production per day from the plant. The total system efficiency of 39.52% is comprised of 50.7% hydrogen fraction and 19.62% electrical fraction. Total plant capital costs and operating costs are estimated to equate a hydrogen production cost of $4.40 per kg for a 25-year plant life. Sensitivity analysis explores the effect of environmental parameters and design parameters on system performance and cost. Improving recuperator effectiveness from 0.7 to 0.8 is a high-value design modification resulting in a 12.1% decrease in hydrogen cost for a modest 2.0% increase in plant $2.85M. At the same time, system efficiency is relatively inelastic to recuperator effectiveness because 81% of excess heat is recovered from the system for electricity production 39 MWh/day and revenue is $0.04 per kWh. Increasing water inlet pressure up to 20 bar reduces the size and cost of super heaters but further pressure rises increasing pump at a rate that outweighs super heater cost savings.
ContributorsBudama, Vishnu Kumar (Author) / Johnson, Nathan (Thesis advisor) / Stechel, Ellen (Committee member) / Rykaczewski, Konrad (Committee member) / Phelan, Patrick (Committee member) / Wang, Robert (Committee member) / Arizona State University (Publisher)
Created2018
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Description
Corrective transmission topology control schemes are an essential part of grid operations and are used to improve the reliability of the grid as well as the operational efficiency. However, topology control schemes are frequently established based on the operator's past knowledge of the system as well as other ad-hoc methods.

Corrective transmission topology control schemes are an essential part of grid operations and are used to improve the reliability of the grid as well as the operational efficiency. However, topology control schemes are frequently established based on the operator's past knowledge of the system as well as other ad-hoc methods. This research presents robust corrective topology control, which is a transmission switching methodology used for system reliability as well as to facilitate renewable integration.

This research presents three topology control (corrective transmission switching) methodologies along with the detailed formulation of robust corrective switching. The robust model can be solved off-line to suggest switching actions that can be used in a dynamic security assessment tool in real-time. The proposed robust topology control algorithm can also generate multiple corrective switching actions for a particular contingency. The solution obtained from the robust topology control algorithm is guaranteed to be feasible for the entire uncertainty set, i.e., a range of system operating states.

Furthermore, this research extends the benefits of robust corrective topology control to renewable resource integration. In recent years, the penetration of renewable resources in electrical power systems has increased. These renewable resources add more complexities to power system operations, due to their intermittent nature. This research presents robust corrective topology control as a congestion management tool to manage power flows and the associated renewable uncertainty. The proposed day-ahead method determines the maximum uncertainty in renewable resources in terms of do-not-exceed limits combined with corrective topology control. The results obtained from the topology control algorithm are tested for system stability and AC feasibility.

The scalability of do-not-exceed limits problem, from a smaller test case to a realistic test case, is also addressed in this research. The do-not-exceed limit problem is simplified by proposing a zonal do-not-exceed limit formulation over a detailed nodal do-not-exceed limit formulation. The simulation results show that the zonal approach is capable of addressing scalability of the do-not-exceed limit problem for a realistic test case.
ContributorsKorad, Akshay Shashikumar (Author) / Hedman, Kory W (Thesis advisor) / Ayyanar, Raja (Committee member) / Vittal, Vijay (Committee member) / Zhang, Muhong (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Two significant trends of recent power system evolution are: (1) increasing installa-tion of dynamic loads and distributed generation resources in distribution systems; (2) large-scale renewable energy integration at the transmission system level. A majority of these devices interface with power systems through power electronic converters. However, existing transient stability (TS)

Two significant trends of recent power system evolution are: (1) increasing installa-tion of dynamic loads and distributed generation resources in distribution systems; (2) large-scale renewable energy integration at the transmission system level. A majority of these devices interface with power systems through power electronic converters. However, existing transient stability (TS) simulators are inadequate to represent the dynamic behavior of these devices accurately. On the other hand, simulating a large system using an electromagnetic transient (EMT) simulator is computationally impractical. EMT-TS hybrid simulation approach is an alternative to address these challenges. Furthermore, to thoroughly analyze the increased interactions among the transmission and distribution systems, an integrated modeling and simulation approach is essential.

The thesis is divided into three parts. The first part focuses on an improved hybrid simulation approach and software development. Compared to the previous work, the pro-posed approach has three salient features: three-sequence TS simulation algorithm, three-phase/three-sequence network equivalencing and flexible switching of the serial and par-allel interaction protocols.

The second part of the thesis concentrates on the applications of the hybrid simula-tion tool. The developed platform is first applied to conduct a detailed fault-induced de-layed voltage recovery (FIDVR) study on the Western Electricity Coordinating Council (WECC) system. This study uncovers that after a normally cleared single line to ground fault at the transmission system could cause air conditioner motors to stall in the distribu-tion systems, and the motor stalling could further propagate to an unfaulted phase under certain conditions. The developed tool is also applied to simulate power systems inter-faced with HVDC systems, including classical HVDC and the new generation voltage source converter (VSC)-HVDC system.

The third part centers on the development of integrated transmission and distribution system simulation and an advanced hybrid simulation algorithm with a capability of switching from hybrid simulation mode to TS simulation. Firstly, a modeling framework suitable for integrated transmission and distribution systems is proposed. Secondly, a power flow algorithm and a diakoptics based dynamic simulation algorithm for the integrated transmission and distribution system are developed. Lastly, the EMT-TS hybrid simulation algorithm is combined with the diakoptics based dynamic simulation algorithm to realize flexible simulation mode switching to increase the simulation efficiency.
ContributorsHuang, Qiuhua (Author) / Vittal, Vijay (Thesis advisor) / Undrill, John M. (Committee member) / Heydt, Gerald T. (Committee member) / Ayyanar, Raja (Committee member) / Arizona State University (Publisher)
Created2016
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Description
This dissertation presents innovative techniques to develop performance-based models and complete transient models of induction motor drive systems with vector controls in electro-magnetic transient (EMT) and positive sequence transient stability (PSTS) simulation programs. The performance-based model is implemented by obtaining the characteristic transfer functions of perturbed active and reactive power

This dissertation presents innovative techniques to develop performance-based models and complete transient models of induction motor drive systems with vector controls in electro-magnetic transient (EMT) and positive sequence transient stability (PSTS) simulation programs. The performance-based model is implemented by obtaining the characteristic transfer functions of perturbed active and reactive power consumptions with respect to frequency and voltage perturbations. This level of linearized performance-based model is suitable for the investigation of the damping of small-magnitude low-frequency oscillations. The complete transient model is proposed by decomposing the motor, converter and control models into d-q axes components and developing a compatible electrical interface to the positive-sequence network in the PSTS simulators. The complete transient drive model is primarily used to examine the system response subject to transient voltage depression considering increasing penetration of converter-driven motor loads.

For developing the performance-based model, modulations are performed on the supply side of the full drive system to procure magnitude and phase responses of active and reactive powers with respect to the supply voltage and frequency for a range of discrete frequency points. The prediction error minimization (PEM) technique is utilized to generate the curve-fitted transfer functions and corresponding bode plots. For developing the complete drive model in the PSTS simulation program, a positive-sequence voltage source is defined properly as the interface of the model to the external system. The dc-link of the drive converter is implemented by employing the average model of the PWM converter, and is utilized to integrate the line-side rectifier and machine-side inverter.

Numerical simulation is then conducted on sample test systems, synthesized with suitable characteristics to examine performance of the developed models. The simulation results reveal that with growing amount of drive loads being distributed in the system, the small-signal stability of the system is improved in terms of the desirable damping effects on the low-frequency system oscillations of voltage and frequency. The transient stability of the system is also enhanced with regard to the stable active power and reactive power controls of the loads, and the appropriate VAr support capability provided by the drive loads during a contingency.
ContributorsLiu, Yuan (Author) / Vittal, Vijay (Thesis advisor) / Undrill, John (Committee member) / Ayyanar, Raja (Committee member) / Qin, Jiangchao (Committee member) / Arizona State University (Publisher)
Created2016