ASU Electronic Theses and Dissertations
This collection includes most of the ASU Theses and Dissertations from 2011 to present. ASU Theses and Dissertations are available in downloadable PDF format; however, a small percentage of items are under embargo. Information about the dissertations/theses includes degree information, committee members, an abstract, supporting data or media.
In addition to the electronic theses found in the ASU Digital Repository, ASU Theses and Dissertations can be found in the ASU Library Catalog.
Dissertations and Theses granted by Arizona State University are archived and made available through a joint effort of the ASU Graduate College and the ASU Libraries. For more information or questions about this collection contact or visit the Digital Repository ETD Library Guide or contact the ASU Graduate College at gradformat@asu.edu.
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- Genre: Doctoral Dissertation
The utilization of alternative techniques such as MICP requires an in-depth understanding of the particle-scale contact mechanisms and the ability to predict the improvement in soil properties resulting from calcite precipitation. For this purpose, the discrete element method (DEM), which is extensively used to investigate granular materials, is adopted in this dissertation. Three-dimensional discrete element method (DEM) based numerical models are developed to simulate the response of bio-cemented sand under static and dynamic loading conditions and the micro-scale mechanisms of MICP are numerically investigated. Special focus is paid to the understanding of the particle scale mechanisms that are dominant in the common laboratory scale experiments including undrained and drained triaxial compression when calcite bridges are present in the soil, that enhances its load capacity. The mechanisms behind improvement of liquefaction resistance in cemented sands are also elucidated through the use of DEM. The thesis thus aims to provide the fundamental link that is important in ensuring proper material design for granular materials to enhance their mechanical performance.
Methods are presented for characterizing contaminants in water (groundwater and surface waters) and indoor air. These techniques are integrative, providing information averaged over time and/or space, as opposed to instantaneous point measurements. Contaminants are concentrated from the environment, making these methods applicable to trace contaminants. These methods have the potential to complement existing techniques, providing the practitioner with opportunities to reduce costs and improve the quality of the data used in decision making.
A conceptual model for integrative sampling of environmental waters is developed and a literature review establishes an advantage in precision for active samplers. A programmable sampler was employed to measure the concentration of chromate in a shallow aquifer exhibiting time-dependent contaminant concentrations, providing a unique data set and sustainability benefits. The analysis of heat exchanger condensate, a waste stream generated by air conditioning, is demonstrated in a non-intrusive method for indoor air quality assessment. In sum, these studies present new opportunities for effective, sustainable environmental characterization.
In this study, first, the water retention curve (WRC) and relative permeability in hydrate bearing sediments are explored to obtain fitting parameters for semi-empirical equations. Second, immiscible fluid invasion into porous media is investigated to identify fluid displacement pattern and displacement efficiency that are affected by pore size distribution and connectivity. Finally, fluid flow through granular media is studied to obtain fluid-particle interaction. This study utilizes the combined techniques of discrete element method simulation, micro-focus X-ray computed tomography (CT), pore-network model simulation algorithms for gas invasion, gas expansion, and relative permeability calculation, transparent micromodels, and water retention curve measurement equipment modified for hydrate-bearing sediments. In addition, a photoelastic disk set-up is fabricated and the image processing technique to correlate the force chain to the applied contact forces is developed.
The results show that the gas entry pressure and the capillary pressure increase with increasing hydrate saturation. Fitting parameters are suggested for different hydrate saturation conditions and morphologies. And, a new model for immiscible fluid invasion and displacement is suggested in which the boundaries of displacement patterns depend on the pore size distribution and connectivity. Finally, the fluid-particle interaction study shows that the fluid flow increases the contact forces between photoelastic disks in parallel direction with the fluid flow.