ASU Electronic Theses and Dissertations
This collection includes most of the ASU Theses and Dissertations from 2011 to present. ASU Theses and Dissertations are available in downloadable PDF format; however, a small percentage of items are under embargo. Information about the dissertations/theses includes degree information, committee members, an abstract, supporting data or media.
In addition to the electronic theses found in the ASU Digital Repository, ASU Theses and Dissertations can be found in the ASU Library Catalog.
Dissertations and Theses granted by Arizona State University are archived and made available through a joint effort of the ASU Graduate College and the ASU Libraries. For more information or questions about this collection contact or visit the Digital Repository ETD Library Guide or contact the ASU Graduate College at gradformat@asu.edu.
Filtering by
- All Subjects: Reliability
- Creators: Rogers, Bradley
Characterization and analysis of long term field aged photovoltaic modules and encapsulant materials
Accelerated testing is vital in learning about the reliability of solar PV modules. The unique streamlined approach taken saves time and resources with a statistically significant number of samples being tested in one chamber under multiple experimental stress conditions that closely mirror field conditions that induce encapsulant browning and solder bond degradation. With short circuit current (Isc) and series resistance (Rs) degradation data sets at multiple temperatures, the activation energies (Ea) for encapsulant browning and solder bond degradation was calculated.
Regular degradation was replaced by the wear-out stages of encapsulant browning and solder bond degradation by subjecting two types of field-aged modules to further accelerated testing. For browning, the Ea calculated through the Arrhenius model was 0.37 ± 0.17 eV and 0.71 ± 0.07 eV. For solder bond degradation, the Arrhenius model was used to calculate an Ea of 0.12 ± 0.05 eV for solder with 2wt% Ag and 0.35 ± 0.04 eV for Sn60Pb40 solder.
To study the effect of types of encapsulant, backsheet, and solder on encapsulant browning and solder bond degradation, 9-cut-cell samples maximizing available data points while minimizing resources underwent accelerated tests described for modules. A ring-like browning feature was observed in samples with UV pass EVA above and UV cut EVA below the cells. The backsheet permeability influences the extent of oxygen photo-bleaching. In samples with solder bond degradation, increased bright spots and cell darkening resulted in increased Rs. Combining image processing with fluorescence imaging and electroluminescence imaging would yield great insight into the two degradation modes.
Part 1 of this thesis determines the most dominant failure modes of field aged photovoltaic (PV) modules using experimental data and statistical analysis, FMECA (Failure Mode, Effect, and Criticality Analysis). The failure and degradation modes of about 5900 crystalline-Si glass/polymer modules fielded for 6 to 16 years in three different photovoltaic (PV) power plants with different mounting systems under the hot-dry desert climate of Arizona are evaluated. A statistical reliability tool, FMECA that uses Risk Priority Number (RPN) is performed for each PV power plant to determine the dominant failure modes in the modules by means of ranking and prioritizing the modes. This study on PV power plants considers all the failure and degradation modes from both safety and performance perspectives, and thus, comes to the conclusion that solder bond fatigue/failure with/without gridline/metallization contact fatigue/failure is the most dominant failure mode for these module types in the hot-dry desert climate of Arizona.
Part 2 of this thesis determines the best method to compute degradation rates of PV modules. Three different PV systems were evaluated to compute degradation rates using four methods and they are: I-V measurement, metered kWh, performance ratio (PR) and performance index (PI). I-V method, being an ideal method for degradation rate computation, were compared to the results from other three methods. The median degradation rates computed from kWh method were within ±0.15% from I-V measured degradation rates (0.9-1.37 %/year of three models). Degradation rates from the PI method were within ±0.05% from the I-V measured rates for two systems but the calculated degradation rate was remarkably different (±1%) from the I-V method for the third system. The degradation rate from the PR method was within ±0.16% from the I-V measured rate for only one system but were remarkably different (±1%) from the I-V measured rate for the other two systems. Thus, it was concluded that metered raw kWh method is the best practical method, after I-V method and PI method (if ground mounted POA insolation and other weather data are available) for degradation computation as this method was found to be fairly accurate, easy, inexpensive, fast and convenient.