ETDs

This collection includes most of the ASU Theses and Dissertations from 2011 to present. ASU Theses and Dissertations are available in downloadable PDF format; however, a small percentage of items are under embargo. Information about the dissertations/theses includes degree information, committee members, an abstract, supporting data or media.

In addition to the electronic theses found in the ASU Digital Repository, ASU Theses and Dissertations can be found in the ASU Library Catalog.

Dissertations and Theses granted by Arizona State University are archived and made available through a joint effort of the ASU Graduate College and the ASU Libraries. For more information or questions about this collection contact or visit the Digital Repository ETD Library Guide or contact the ASU Graduate College at gradformat@asu.edu.

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The shift of precipitation maxima on the annual maximum series using regional climate model precipitation data

Description
Ten regional climate models (RCMs) and atmosphere-ocean generalized model parings from the North America Regional Climate Change Assessment Program were used to estimate the shift of extreme precipitation due to climate change using present-day and future-day climate scenarios. RCMs emulate winter storms and one-day duration events at the sub-regional level.…

Ten regional climate models (RCMs) and atmosphere-ocean generalized model parings from the North America Regional Climate Change Assessment Program were used to estimate the shift of extreme precipitation due to climate change using present-day and future-day climate scenarios. RCMs emulate winter storms and one-day duration events at the sub-regional level. Annual maximum series were derived for each model pairing, each modeling period; and for annual and winter seasons. The reliability ensemble average (REA) method was used to qualify each RCM annual maximum series to reproduce historical records and approximate average predictions, because there are no future records. These series determined (a) shifts in extreme precipitation frequencies and magnitudes, and (b) shifts in parameters during modeling periods. The REA method demonstrated that the winter season had lower REA factors than the annual season. For the winter season the RCM pairing of the Hadley regional Model 3 and the Geophysical Fluid-Dynamics Laboratory atmospheric-land generalized model had the lowest REA factors. However, in replicating present-day climate, the pairing of the Abdus Salam International Center for Theoretical Physics' Regional Climate Model Version 3 with the Geophysical Fluid-Dynamics Laboratory atmospheric-land generalized model was superior. Shifts of extreme precipitation in the 24-hour event were measured using precipitation magnitude for each frequency in the annual maximum series, and the difference frequency curve in the generalized extreme-value-function parameters. The average trend of all RCM pairings implied no significant shift in the winter annual maximum series, however the REA-selected models showed an increase in annual-season precipitation extremes: 0.37 inches for the 100-year return period and for the winter season suggested approximately 0.57 inches for the same return period. Shifts of extreme precipitation were estimated using predictions 70 years into the future based on RCMs. Although these models do not provide climate information for the intervening 70 year period, the models provide an assertion on the behavior of future climate. The shift in extreme precipitation may be significant in the frequency distribution function, and will vary depending on each model-pairing condition. The proposed methodology addresses the many uncertainties associated with the current methodologies dealing with extreme precipitation.
ContributorsRiaño, Alejandro (Author) / Mays, Larry W. (Thesis advisor) / Vivoni, Enrique (Committee member) / Huang, Huei-Ping (Committee member) / Arizona State University (Publisher)
Created2013
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Innovations in Detecting and Modeling Dryland Hydrologic Changes

Description
The hydrologic cycle in drylands is complex with large spatiotemporal variationsacross scales and is particularly vulnerable to changes in climate and land cover. To address the challenges posed by hydrologic changes, a synergistic approach that combines numerical models, ground and remotely sensed observations, and data analysis is crucial. This dissertation uses innovative detection…

The hydrologic cycle in drylands is complex with large spatiotemporal variationsacross scales and is particularly vulnerable to changes in climate and land cover. To address the challenges posed by hydrologic changes, a synergistic approach that combines numerical models, ground and remotely sensed observations, and data analysis is crucial. This dissertation uses innovative detection and modeling techniques to assess key hydrologic variables in drylands, including irrigated water use, streamflow, and snowpack conditions, answering following research questions that also have broad societal implications: (1) What are the individual and combined effects of future climate and land use change on irrigation water use (IWU) in the Phoenix Metropolitan Area (PMA)?; (2) How can temporal changes in streamflow and the impacts of flash flooding be detected in dryland rivers?; and (3) What are the impacts of rainfall-snow partitioning on future snowpack and streamflow in the Colorado River Basin (CRB)? Firstly, I conducted a scenario modeling using the Variable Infiltration Capacity (VIC) model under future climate and land use change scenarios. Results showed that future IWU will change from -0.5% to +6.8% in the far future (2071-2100) relative to the historical period (1981-2010). Secondly, I employed CubeSat imagery to map streamflow presence in the Hassayampa River of Arizona, finding that the imaging capacity of CubeSats enabled the detection of ephemeral flow events using the surface reflectance of the near-infrared (NIR) band. Results showed that 12% of reaches were classified as intermittent, with the remaining as ephemeral. Finally, I implemented a physically-based rainfall-snow partitioning scheme in the VIC model that estimates snowfall fraction from the wet-bulb temperature using a sigmoid function. The new scheme predicts more significant declines in snowfall (-8 to -11%) and streamflow (-14 to -27%) by the end of the 21st century over the CRB, relative to historical conditions. Overall, this dissertation demonstrates how innovative technologies can enhance the understanding of dryland hydrologic changes and inform decision-making of water resources management. The findings offer important insights for policymakers, water managers, and researchers who seek to ensure water resources sustainability under the effects of climate and land use change.
ContributorsWang, Zhaocheng (Author) / Vivoni, Enrique R (Thesis advisor) / White, Dave D (Committee member) / Mascaro, Giuseppe (Committee member) / Huang, Huei-Ping (Committee member) / Wang, Zhihua (Committee member) / Arizona State University (Publisher)
Created2023
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Direct Ink Written Luminous Monoliths for Hydrogen Sulfide Photocatalysis

Description
The conversion of H2S enables the recycling of a waste gas into a potential source of hydrogen at a lower thermodynamic energy cost as compared to water splitting. However, studies on the photocatalytic decomposition of H2S focus on traditional deployment of catalyst materials to facilitate this conversion, and operation only…

The conversion of H2S enables the recycling of a waste gas into a potential source of hydrogen at a lower thermodynamic energy cost as compared to water splitting. However, studies on the photocatalytic decomposition of H2S focus on traditional deployment of catalyst materials to facilitate this conversion, and operation only when a light source is available. In this study, the efficacy of Direct Ink Written (DIW) luminous structures for H2S conversion has been investigated, with the primary objective of sustaining H2S conversion when a light source has been terminated. Additionally, as a secondary objective, improving light distribution within monoliths for photocatalytic applications is desired. The intrinsic illumination of the 3D printed monoliths developed in this work could serve as an alternative to monolith systems that employ light transmitting fiber optic cables that have been previously proposed to improve light distribution in photocatalytic systems. The results that were obtained demonstrate that H2S favorable adsorbents, a wavelength compatible long afterglow phosphor, and a photocatalyst can form viscoelastic inks that are printable into DIW luminous monolithic contactors. Additionally, rheological, optical and porosity analyses conducted, provide design guidelines for future studies seeking to develop DIW luminous monoliths from compatible catalyst-phosphor pairs. The monoliths that were developed demonstrate not only improved conversion when exposed to light, but more significantly, extended H2S conversion from the afterglow of the monoliths when an external light source was removed. Lastly, considering growing interests in attaining a global circular economy, the techno-economic feasibility of a H2S-CO2 co-utilization plant leveraging hydrogen from H2S photocatalysis as a feed source for a downstream CO2 methanation plant has been assessed. The work provides preliminary information to guide future chemical kinetic design characteristics that are important to strive for if using H2S as a source of hydrogen in a CO2 methanation facility.
ContributorsAbdullahi, Adnan (Author) / Andino, Jean (Thesis advisor) / Phelan, Patrick (Thesis advisor) / Bhate, Dhruv (Committee member) / Wang, Robert (Committee member) / Huang, Huei-Ping (Committee member) / Arizona State University (Publisher)
Created2023