ASU Electronic Theses and Dissertations
This collection includes most of the ASU Theses and Dissertations from 2011 to present. ASU Theses and Dissertations are available in downloadable PDF format; however, a small percentage of items are under embargo. Information about the dissertations/theses includes degree information, committee members, an abstract, supporting data or media.
In addition to the electronic theses found in the ASU Digital Repository, ASU Theses and Dissertations can be found in the ASU Library Catalog.
Dissertations and Theses granted by Arizona State University are archived and made available through a joint effort of the ASU Graduate College and the ASU Libraries. For more information or questions about this collection contact or visit the Digital Repository ETD Library Guide or contact the ASU Graduate College at gradformat@asu.edu.
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- Creators: Mobasher, Barzin
- Creators: Abbaszadegan, Morteza
Description
Radioactive cesium (137Cs), released from nuclear power plants and nuclear accidental releases, is a problem due to difficulties regarding its removal. Efforts have been focused on removing cesium and the remediation of the contaminated environment. Traditional treatment techniques include Prussian blue and nano zero-valent ion (nZVI) and nano-Fe/Cu particles to remove Cs from water; however, they are not efficient at removing Cs when present at low concentrations of about 10 parts-per-billion (ppb), typical of concentrations found in the radioactive contaminated sites.
The objective of this study was to develop an innovative and simple method to remove Cs+ present at low concentrations by engineering a proteoliposome transporter composed of an uptake protein reconstituted into a liposome vesicle. To achieve this, the uptake protein, Kup, from E. coli, was isolated through protein extraction and purification procedures. The new and simple extraction methodology developed in this study was highly efficient and resulted in purified Kup at ~1 mg/mL. A new method was also developed to insert purified Kup protein into the bilayers of liposome vesicles. Finally, removal of CsCl (10 and 100 ppb) was demonstrated by spiking the constructed proteoliposome in lab-fortified water, followed by incubation and ultracentrifugation, and measuring Cs+ with inductively coupled plasma mass spectrometry (ICP-MS).
The ICP-MS results from testing water contaminated with 100 ppb CsCl, revealed that adding 0.1 – 8 mL of Kup proteoliposome resulted in 0.29 – 12.7% Cs removal. Addition of 0.1 – 2 mL of proteoliposome to water contaminated with 10 ppb CsCl resulted in 0.65 – 3.43% Cs removal. These removal efficiencies were greater than the control, liposome with no protein.
A linear relationship was observed between the amount of proteoliposome added to the contaminated water and removal percentage. Consequently, by adding more volumes of proteoliposome, removal can be simply improved. This suggests that with ~ 60-70 mL of proteoliposome, removal of about 90% can be achieved. The novel technique developed herein is a contribution to emerging technologies in the water and wastewater treatment industry.
The objective of this study was to develop an innovative and simple method to remove Cs+ present at low concentrations by engineering a proteoliposome transporter composed of an uptake protein reconstituted into a liposome vesicle. To achieve this, the uptake protein, Kup, from E. coli, was isolated through protein extraction and purification procedures. The new and simple extraction methodology developed in this study was highly efficient and resulted in purified Kup at ~1 mg/mL. A new method was also developed to insert purified Kup protein into the bilayers of liposome vesicles. Finally, removal of CsCl (10 and 100 ppb) was demonstrated by spiking the constructed proteoliposome in lab-fortified water, followed by incubation and ultracentrifugation, and measuring Cs+ with inductively coupled plasma mass spectrometry (ICP-MS).
The ICP-MS results from testing water contaminated with 100 ppb CsCl, revealed that adding 0.1 – 8 mL of Kup proteoliposome resulted in 0.29 – 12.7% Cs removal. Addition of 0.1 – 2 mL of proteoliposome to water contaminated with 10 ppb CsCl resulted in 0.65 – 3.43% Cs removal. These removal efficiencies were greater than the control, liposome with no protein.
A linear relationship was observed between the amount of proteoliposome added to the contaminated water and removal percentage. Consequently, by adding more volumes of proteoliposome, removal can be simply improved. This suggests that with ~ 60-70 mL of proteoliposome, removal of about 90% can be achieved. The novel technique developed herein is a contribution to emerging technologies in the water and wastewater treatment industry.
ContributorsHakim Elahi, Sepideh (Author) / Conroy-Ben, Otakuye (Thesis advisor) / Abbaszadegan, Morteza (Committee member) / Fox, Peter (Committee member) / Arizona State University (Publisher)
Created2018
Description
Phase change materials (PCMs) are combined sensible-and-latent thermal energy storage materials that can be used to store and dissipate energy in the form of heat. PCMs incorporated into wall-element systems have been well-studied with respect to energy efficiency of building envelopes. New applications of PCMs in infrastructural concrete, e.g., for mitigating early-age cracking and freeze-and-thaw induced damage, have also been proposed. Hence, the focus of this dissertation is to develop a detailed understanding of the physic-chemical and thermo-mechanical characteristics of cementitious systems and novel coating systems for wall-elements containing PCM. The initial phase of this work assesses the influence of interface properties and inter-inclusion interactions between microencapsulated PCM, macroencapsulated PCM, and the cementitious matrix. The fact that these inclusions within the composites are by themselves heterogeneous, and contain multiple components necessitate careful application of models to predict the thermal properties. The next phase observes the influence of PCM inclusions on the fracture and fatigue behavior of PCM-cementitious composites. The compliant nature of the inclusion creates less variability in the fatigue life for these composites subjected to cyclic loading. The incorporation of small amounts of PCM is found to slightly improve the fracture properties compared to PCM free cementitious composites. Inelastic deformations at the crack-tip in the direction of crack opening are influenced by the microscale PCM inclusions. After initial laboratory characterization of the microstructure and evaluation of the thermo-mechanical performance of these systems, field scale applicability and performance were evaluated. Wireless temperature and strain sensors for smart monitoring were embedded within a conventional portland cement concrete pavement (PCCP) and a thermal control smart concrete pavement (TCSCP) containing PCM. The TCSCP exhibited enhanced thermal performance over multiple heating and cooling cycles. PCCP showed significant shrinkage behavior as a result of compressive strains in the reinforcement that were twice that of the TCSCP. For building applications, novel PCM-composites coatings were developed to improve and extend the thermal efficiency. These coatings demonstrated a delay in temperature by up to four hours and were found to be more cost-effective than traditional building insulating materials.
The results of this work prove the feasibility of PCMs as a temperature-regulating technology. Not only do PCMs reduce and control the temperature within cementitious systems without affecting the rate of early property development but they can also be used as an auto-adaptive technology capable of improving the thermal performance of building envelopes.
The results of this work prove the feasibility of PCMs as a temperature-regulating technology. Not only do PCMs reduce and control the temperature within cementitious systems without affecting the rate of early property development but they can also be used as an auto-adaptive technology capable of improving the thermal performance of building envelopes.
ContributorsAguayo, Matthew Joseph (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Mobasher, Barzin (Committee member) / Underwood, Benjamin (Committee member) / Liu, Yongming (Committee member) / Arizona State University (Publisher)
Created2018
Description
With the growth of global population, the demand for sustainable infrastructure is significantly increasing. Substructures with appropriate materials are required to be built in or above soil that can support the massive volume of construction demand. However, increased structural requirements often require ground improvement to increase the soil capacity. Moreover, certain soils are prone to liquefaction during an earthquake, which results in significant structural damage and loss of lives. While various soil treatment methods have been developed in the past to improve the soil’s load carrying ability, most of these traditional treatment methods have been found either hazardous and may cause irreversible damage to natural environment, or too disruptive to use beneath or adjacent to existing structures. Thus, alternative techniques are required to provide a more natural and sustainable solution. Biomediated methods of strengthening soil through mineral precipitation, in particular through microbially induced carbonate precipitation (MICP), have recently emerged as a promising means of soil improvement. In MICP, the precipitation of carbonate (usually in the form of calcium carbonate) is mediated by microorganisms and the process is referred to as biomineralization. The precipitated carbonate coats soil particles, precipitates in the voids, and bridges between soil particles, thereby improving the mechanical properties (e.g., strength, stiffness, and dilatancy). Although it has been reported that the soil’s mechanical properties can be extensively enhanced through MICP, the micro-scale mechanisms that influence the macro-scale constitutive response remain to be clearly explained.
The utilization of alternative techniques such as MICP requires an in-depth understanding of the particle-scale contact mechanisms and the ability to predict the improvement in soil properties resulting from calcite precipitation. For this purpose, the discrete element method (DEM), which is extensively used to investigate granular materials, is adopted in this dissertation. Three-dimensional discrete element method (DEM) based numerical models are developed to simulate the response of bio-cemented sand under static and dynamic loading conditions and the micro-scale mechanisms of MICP are numerically investigated. Special focus is paid to the understanding of the particle scale mechanisms that are dominant in the common laboratory scale experiments including undrained and drained triaxial compression when calcite bridges are present in the soil, that enhances its load capacity. The mechanisms behind improvement of liquefaction resistance in cemented sands are also elucidated through the use of DEM. The thesis thus aims to provide the fundamental link that is important in ensuring proper material design for granular materials to enhance their mechanical performance.
The utilization of alternative techniques such as MICP requires an in-depth understanding of the particle-scale contact mechanisms and the ability to predict the improvement in soil properties resulting from calcite precipitation. For this purpose, the discrete element method (DEM), which is extensively used to investigate granular materials, is adopted in this dissertation. Three-dimensional discrete element method (DEM) based numerical models are developed to simulate the response of bio-cemented sand under static and dynamic loading conditions and the micro-scale mechanisms of MICP are numerically investigated. Special focus is paid to the understanding of the particle scale mechanisms that are dominant in the common laboratory scale experiments including undrained and drained triaxial compression when calcite bridges are present in the soil, that enhances its load capacity. The mechanisms behind improvement of liquefaction resistance in cemented sands are also elucidated through the use of DEM. The thesis thus aims to provide the fundamental link that is important in ensuring proper material design for granular materials to enhance their mechanical performance.
ContributorsYang, Pu (Author) / Neithalath, Narayanan (Thesis advisor) / Kavazanjian, Edward (Committee member) / Rajan, S.D. (Committee member) / Mobasher, Barzin (Committee member) / Jiao, Yang (Committee member) / Arizona State University (Publisher)
Created2018
Description
One of the two objectives of this dissertation is an investigation into the possible correlation between rainfall events and increased levels of E. coli and Mycobacterium using an existing data set. The literature states that levels of microbial concentrations do increase after rainfall events, but there are no studies to indicate this correlation applies in any Arizona water systems. The data analyzed for the bacterial concentrations project suggested the possibility of a correlation along one river but it is not conclusive to state that any correlation exists between rainfall events and the microbial concentration for many other sites included in the analysis. This is most likely due to the highly engineered water delivery systems that are not directly impacted.
The secondary objective was to determine if there are environmental variables collected from an ongoing project which would be a good candidate for making predictions about any of the project data parameters. Of the 79 possible opportunities for the model to accurately predict the dependent variable, it showed strong statistical favorability as well as experimentally favorable results towards Dissolved Organic Carbon as the best dependent variable from the data set, resulting in an accuracy of 41%. This is relevant since Dissolved Organic Carbon is one of the most important water quality parameters of concern for drinking water treatment plants where disinfection by-products are a limiting factor. The need for further analysis and additional data collection is an obvious result from both studies. The use of hydrograph data instead of rainfall would be a logical new direction for the heavily engineered water delivery systems.
The secondary objective was to determine if there are environmental variables collected from an ongoing project which would be a good candidate for making predictions about any of the project data parameters. Of the 79 possible opportunities for the model to accurately predict the dependent variable, it showed strong statistical favorability as well as experimentally favorable results towards Dissolved Organic Carbon as the best dependent variable from the data set, resulting in an accuracy of 41%. This is relevant since Dissolved Organic Carbon is one of the most important water quality parameters of concern for drinking water treatment plants where disinfection by-products are a limiting factor. The need for further analysis and additional data collection is an obvious result from both studies. The use of hydrograph data instead of rainfall would be a logical new direction for the heavily engineered water delivery systems.
ContributorsBuell, Andrew (Author) / Fox, Peter (Thesis advisor) / Abbaszadegan, Morteza (Thesis advisor) / Alum, Absar (Committee member) / Arizona State University (Publisher)
Created2018
Description
A comprehensive study was performed on non-proprietary ultra-high-performance concrete (UHPC) material and several design methods were suggested based on numerous experimental results. Several sets of compression tests, direct tensile tests, and flexural tests were performed on UHPC to provide a better understanding of the mechanisms involved in the mechanical behavior of the fiber reinforced material. In addition to compressive tests, flexural tests, based on ASTM C1609 and EN 14651, were performed. The effect of the strain rate on the UHPC material was also investigated through the high-speed tensile tests at different strain rates. Alongside the usual measurement tools such as linear variable differential transformers (LVDT) and clip gages, digital image correlation (DIC) method was also used to capture the full-range deformations in the samples and localized crack propagations. Analytical approaches were suggested, based on the experimental results of the current research and other research groups, to provide design solutions for different applications and design approaches for UHPC and hybrid reinforced concrete (HRC) sections. The suggested methods can be used both in the ultimate limit state (ULS) and the serviceability limit state (SLS) design methods. Closed form relationships, based on the non-linear design of reinforced concrete, were used in the calculation of the load-deflection response of UHPC. The procedures were used in obtaining material properties from the flexural data using procedures that are based on back-calculation of material properties from the experimental results. Model simulations were compared with other results available in the literature. Performance of flexural reinforced UHPC concrete beam sections tested under different types of loading was addressed using a combination of fibers and rebars. The same analytical approach was suggested for the fiber reinforced concrete (FRC) sections strengthened (rehabilitated) by fiber reinforced polymers (FRP) and textile reinforced concrete (TRC). The objective is to validate the proper design procedures for flexural members as well as connection elements. The proposed solutions can be used to reduce total reinforcement by means of increasing the ductility of the FRC, HRC, and UHPC members in order to meet the required flexural reinforcement, which in some cases leads to total elimination of rebars.
ContributorsKianmofrad, Farrokh (Author) / Mobasher, Barzin (Thesis advisor) / Rajan, Subramaniam Dharma (Committee member) / Hoover, Christian G. (Committee member) / Arizona State University (Publisher)
Created2018
Description
A simplified bilinear moment-curvature model are derived based on the moment-curvature response generated from a parameterized stress-strain response of strain softening and or strain-hardening material by Dr. Barzin Mobasher and Dr. Chote Soranakom. Closed form solutions are developed for deflection calculations of determinate beams subjected to usual loading patterns at any load stage. The solutions are based on a bilinear moment curvature response characterized by the flexural crack initiation and ultimate capacity based on a deflection hardening behavior. Closed form equations for deflection calculation are presented for simply supported beams under three point bending, four point bending, uniform load, concentrated moment at the middle, pure bending, and for cantilever beam under a point load at the end, a point load with an arbitrary distance from the fixed end, and uniform load. These expressions are derived for pre-cracked and post cracked regions. A parametric study is conducted to examine the effects of moment and curvature at the ultimate stage to moment and curvature at the first crack ratios on the deflection. The effectiveness of the simplified closed form solution is demonstrated by comparing the analytical load deflection response and the experimental results for three point and four point bending. The simplified bilinear moment-curvature model is modified by imposing the deflection softening behavior so that it can be widely implemented in the analysis of 2-D panels. The derivations of elastic solutions and yield line approach of 2-D panels are presented. Effectiveness of the proposed moment-curvature model with various types of panels is verified by comparing the simulated data with the experimental data of panel test.
ContributorsWang, Xinmeng (Author) / Mobasher, Barzin (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Neithalath, Narayanan (Committee member) / Arizona State University (Publisher)
Created2015
Description
The need for rapid, specific and sensitive assays that provide a detection of bacterial indicators are important for monitoring water quality. Rapid detection using biosensor is a novel approach for microbiological testing applications. Besides, validation of rapid methods is an obstacle in adoption of such new bio-sensing technologies. In this study, the strategy developed is based on using the compound 4-methylumbelliferyl glucuronide (MUG), which is hydrolyzed rapidly by the action of E. coli β-D-glucuronidase (GUD) enzyme to yield a fluorogenic product that can be quantified and directly related to the number of E. coli cells present in water samples. The detection time required for the biosensor response ranged from 30 to 120 minutes, depending on the number of bacteria. The specificity of the MUG based biosensor platform assay for the detection of E. coli was examined by pure cultures of non-target bacterial genera and also non-target substrates. GUD activity was found to be specific for E. coli and no such enzymatic activity was detected in other species. Moreover, the sensitivity of rapid enzymatic assays was investigated and repeatedly determined to be less than 10 E. coli cells per reaction vial concentrated from 100 mL of water samples. The applicability of the method was tested by performing fluorescence assays under pure and mixed bacterial flora in environmental samples. In addition, the procedural QA/QC for routine monitoring of drinking water samples have been validated by comparing the performance of the biosensor platform for the detection of E. coli and culture-based standard techniques such as Membrane Filtration (MF). The results of this study indicated that the fluorescence signals generated in samples using specific substrate molecules can be utilized to develop a bio-sensing platform for the detection of E. coli in drinking water. The procedural QA/QC of the biosensor will provide both industry and regulatory authorities a useful tool for near real-time monitoring of E. coli in drinking water samples. Furthermore, this system can be applied independently or in conjunction with other methods as a part of an array of biochemical assays in order to reliably detect E. coli in water.
ContributorsHesari, Nikou (Author) / Abbaszadegan, Morteza (Thesis advisor) / Alum, Absar (Committee member) / Fox, Peter (Committee member) / Stout, Valerie (Committee member) / Arizona State University (Publisher)
Created2015
Description
Composite materials are finally providing uses hitherto reserved for metals in structural systems applications – airframes and engine containment systems, wraps for repair and rehabilitation, and ballistic/blast mitigation systems. They have high strength-to-weight ratios, are durable and resistant to environmental effects, have high impact strength, and can be manufactured in a variety of shapes. Generalized constitutive models are being developed to accurately model composite systems so they can be used in implicit and explicit finite element analysis. These models require extensive characterization of the composite material as input. The particular constitutive model of interest for this research is a three-dimensional orthotropic elasto-plastic composite material model that requires a total of 12 experimental stress-strain curves, yield stresses, and Young’s Modulus and Poisson’s ratio in the material directions as input. Sometimes it is not possible to carry out reliable experimental tests needed to characterize the composite material. One solution is using virtual testing to fill the gaps in available experimental data. A Virtual Testing Software System (VTSS) has been developed to address the need for a less restrictive method to characterize a three-dimensional orthotropic composite material. The system takes in the material properties of the constituents and completes all 12 of the necessary characterization tests using finite element (FE) models. Verification and validation test cases demonstrate the capabilities of the VTSS.
ContributorsHarrington, Joseph (Author) / Rajan, Subramaniam D. (Thesis advisor) / Neithalath, Narayanan (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2015
Description
In order to verify the dispersive nature of transverse displacement in a beam, a deep understanding of the governing partial differential equation is developed. Using the finite element method and Newmark’s method, along with Fourier transforms and other methods, the aim is to obtain consistent results across each numerical technique. An analytical solution is also analyzed for the Euler-Bernoulli beam in order to gain confidence in the numerical techniques when used for more advance beam theories that do not have a known analytical solution. Three different beam theories are analyzed in this report: The Euler-Bernoulli beam theory, Rayleigh beam theory and Timoshenko beam theory. A comparison of the results show the difference between each theory and the advantages of using a more advanced beam theory for higher frequency vibrations.
ContributorsTschetter, Ryan William (Author) / Hjelmstad, Keith D. (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2016
Description
The motivation of this work is based on development of new construction products with strain hardening cementitious composites (SHCC) geared towards sustainable residential applications. The proposed research has three main objectives: automation of existing manufacturing systems for SHCC laminates; multi-level characterization of mechanical properties of fiber, matrix, interface and composites phases using servo-hydraulic and digital image correlation techniques. Structural behavior of these systems were predicted using ductility based design procedures using classical laminate theory and structural mechanics. SHCC sections are made up of thin sections of matrix with Portland cement based binder and fine aggregates impregnating continuous one-dimensional fibers in individual or bundle form or two/three dimensional woven, bonded or knitted textiles. Traditional fiber reinforced concrete (FRC) use random dispersed chopped fibers in the matrix at a low volume fractions, typically 1-2% to avoid to avoid fiber agglomeration and balling. In conventional FRC, fracture localization occurs immediately after the first crack, resulting in only minor improvement in toughness and tensile strength. However in SHCC systems, distribution of cracking throughout the specimen is facilitated by the fiber bridging mechanism. Influence of material properties of yarn, composition, geometry and weave patterns of textile in the behavior of laminated SHCC skin composites were investigated. Contribution of the cementitious matrix in the early age and long-term performance of laminated composites was studied with supplementary cementitious materials such as fly ash, silica fume, and wollastonite. A closed form model with classical laminate theory and ply discount method, coupled with a damage evolution model was utilized to simulate the non-linear tensile response of these composite materials. A constitutive material model developed earlier in the group was utilized to characterize and correlate the behavior of these structural composites under uniaxial tension and flexural loading responses. Development and use of analytical models enables optimal design for application of these materials in structural applications. Another area of immediate focus is the development of new construction products from SHCC laminates such as angles, channels, hat sections, closed sections with optimized cross sections. Sandwich composites with stress skin-cellular core concept were also developed to utilize strength and ductility of fabric reinforced skin in addition to thickness, ductility, and thermal benefits of cellular core materials. The proposed structurally efficient and durable sections promise to compete with wood and light gage steel based sections for lightweight construction and panel application
ContributorsDey, Vikram (Author) / Mobasher, Barzin (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Neithalath, Narayanan (Committee member) / Underwood, Benjamin (Committee member) / Liu, Yongming (Committee member) / Arizona State University (Publisher)
Created2016