ETDs

This collection includes most of the ASU Theses and Dissertations from 2011 to present. ASU Theses and Dissertations are available in downloadable PDF format; however, a small percentage of items are under embargo. Information about the dissertations/theses includes degree information, committee members, an abstract, supporting data or media.

In addition to the electronic theses found in the ASU Digital Repository, ASU Theses and Dissertations can be found in the ASU Library Catalog.

Dissertations and Theses granted by Arizona State University are archived and made available through a joint effort of the ASU Graduate College and the ASU Libraries. For more information or questions about this collection contact or visit the Digital Repository ETD Library Guide or contact the ASU Graduate College at gradformat@asu.edu.

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Synthesis, characterization and mechanical behavior of a novel sustainable structural binder utilizing the chemistry of iron carbonation

Description
Increased priority on the minimization of environmental impacts of conventional construction materials in recent years has motivated increased use of waste materials or bi-products such as fly ash, blast furnace slag with a view to reduce or eliminate the manufacturing/consumption of ordinary portland cement (OPC) which accounts for approximately 5-7%…

Increased priority on the minimization of environmental impacts of conventional construction materials in recent years has motivated increased use of waste materials or bi-products such as fly ash, blast furnace slag with a view to reduce or eliminate the manufacturing/consumption of ordinary portland cement (OPC) which accounts for approximately 5-7% of global carbon dioxide emission. The current study explores, for the first time, the possibility of carbonating waste metallic iron powder to develop carbon-negative sustainable binder systems for concrete. The fundamental premise of this work is that metallic iron will react with aqueous CO2 under controlled conditions to form complex iron carbonates which have binding capabilities. The compressive and flexural strengths of the chosen iron-based binder systems increase with carbonation duration and the specimens carbonated for 4 days exhibit mechanical properties that are comparable to those of companion ordinary portland cement systems. The optimal mixture proportion and carbonation regime for this non-conventional sustainable binder is established based on the study of carbonation efficiency of a series of mixtures using thermogravimetric analysis. The pore- and micro-structural features of this novel binding material are also evaluated. The fracture response of this novel binder is evaluated using strain energy release rate and measurement of fracture process zone using digital image correlation (DIC). The iron-based binder system exhibits significantly higher strain energy release rates when compared to those of the OPC systems in both the unreinforced and glass fiber reinforced states. The iron-based binder also exhibits higher amount of area of fracture process zone due to its ability to undergo inelastic deformation facilitated by unreacted metallic iron particle inclusions in the microstructure that helps crack bridging /deflection. The intrinsic nano-mechanical properties of carbonate reaction product are explored using statistical nanoindentation technique coupled with a stochastic deconvolution algorithm. Effect of exposure to high temperature (up to 800°C) is also studied. Iron-based binder shows significantly higher residual flexural strength after exposure to high temperatures. Results of this comprehensive study establish the viability of this binder type for concrete as an environment-friendly and economical alternative to OPC.
ContributorsDas, Sumanta (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, S.D. (Committee member) / Mobasher, Barzin (Committee member) / Marzke, Robert (Committee member) / Chawla, Nikhilesh (Committee member) / Stone, David (Committee member) / Arizona State University (Publisher)
Created2015
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Advancing Knowledge of Mechanically-Fiber Reinforced Asphalt Concrete

Description

The use of reinforcing fibers in asphalt concrete (AC) has been documented in many studies. Published studies generally demonstrate positive benefits from using mechanically fiber reinforced asphalt concrete (M-FRAC); however, improvements generally vary with respect to the particular study. The widespread acceptance of fibers use in the asphalt industry is…

The use of reinforcing fibers in asphalt concrete (AC) has been documented in many studies. Published studies generally demonstrate positive benefits from using mechanically fiber reinforced asphalt concrete (M-FRAC); however, improvements generally vary with respect to the particular study. The widespread acceptance of fibers use in the asphalt industry is hindered by these inconsistencies. This study seeks to fulfill a critical knowledge gap by advancing knowledge of M-FRAC in order to better understand, interpret, and predict the behavior of these materials. The specific objectives of this dissertation are to; (a) evaluate the state of aramid fiber in AC and examine their impacts on the mechanical performance of asphalt mixtures; (b) evaluate the interaction of the reinforcement efficiency of fibers with compositions of asphalt mixtures; (c) evaluate tensile and fracture properties of M-FRAC; (d) evaluate the interfacial shear bond strength and critical fiber length in M-FRAC; and (e) propose micromechanical models for prediction of the tensile strength of M-FRAC. The research approach to achieve these objectives included experimental measurements and theoretical considerations. Throughout the study, the mechanical response of specimens with and without fibers are scrutinized using standard test methods including flow number (AASHTO T 378) and uniaxial fatigue (AASHTO TP 107), and non-standard test methods for fiber extraction, direct tension, semi-circular bending, and single fiber pull-out tests. Then, the fiber reinforcement mechanism is further examined by using the basic theories of viscoelasticity as well as micromechanical models.

The findings of this study suggest that fibers do serve as a reinforcement element in AC; however, their reinforcing effectiveness depends on the state of fibers in the mix, temperature/ loading rate, properties of fiber (i.e. dosage, length), properties of mix type (gradation and binder content), and mechanical test type to characterize M-FRAC. The outcome of every single aforementioned elements identifies key reasons attributed to the fiber reinforcement efficiency in AC, which provides insights to justify the discrepancies in the literature and further recommends solutions to overcome the knowledge gaps. This improved insight will translate into the better deployment of existing fiber-based technologies; the development of new, and more effective fiber-based technologies in asphalt mixtures.
ContributorsNoorvand, Hossein (Author) / Kaloush, Kamil (Thesis advisor) / Underwood, Shane B (Thesis advisor) / Mamlouk, Michael (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2020