ASU Electronic Theses and Dissertations
This collection includes most of the ASU Theses and Dissertations from 2011 to present. ASU Theses and Dissertations are available in downloadable PDF format; however, a small percentage of items are under embargo. Information about the dissertations/theses includes degree information, committee members, an abstract, supporting data or media.
In addition to the electronic theses found in the ASU Digital Repository, ASU Theses and Dissertations can be found in the ASU Library Catalog.
Dissertations and Theses granted by Arizona State University are archived and made available through a joint effort of the ASU Graduate College and the ASU Libraries. For more information or questions about this collection contact or visit the Digital Repository ETD Library Guide or contact the ASU Graduate College at gradformat@asu.edu.
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- Creators: Mobasher, Barzin
The current study focuses on the fundamental understanding of such functional composites, from their microstructural design to macro-scale application. More specifically, this study investigates three different categories of functional cementitious composites. First, it discusses the differences between cementitious systems containing interground and blended limestone with and without alumina. The interground systems are found to outperform the blended systems due to differential grinding of limestone. A novel approach to deduce the particle size distribution of limestone and cement in the interground systems is proposed. Secondly, the study delves into the realm of ultra-high performance concrete, a novel material which possesses extremely high compressive-, tensile- and flexural-strength and service life as compared to regular concrete. The study presents a novel first principles-based paradigm to design economical ultra-high performance concretes using locally available materials. In the final part, the study addresses the thermal benefits of a novel type of concrete containing phase change materials. A software package was designed to perform numerical simulations to analyze temperature profiles and thermal stresses in concrete structures containing PCMs.
The design of these materials is accompanied by material characterization of cementitious binders. This has been accomplished using techniques that involve measurement of heat evolution (isothermal calorimetry), determination and quantification of reaction products (thermo-gravimetric analysis, x-ray diffraction, micro-indentation, scanning electron microscopy, energy-dispersive x-ray spectroscopy) and evaluation of pore-size distribution (mercury intrusion porosimetry). In addition, macro-scale testing has been carried out to determine compression, flexure and durability response. Numerical simulations have been carried out to understand hydration of cementitious composites, determine optimum particle packing and determine the thermal performance of these composites.
The use of reinforcing fibers in asphalt concrete (AC) has been documented in many studies. Published studies generally demonstrate positive benefits from using mechanically fiber reinforced asphalt concrete (M-FRAC); however, improvements generally vary with respect to the particular study. The widespread acceptance of fibers use in the asphalt industry is hindered by these inconsistencies. This study seeks to fulfill a critical knowledge gap by advancing knowledge of M-FRAC in order to better understand, interpret, and predict the behavior of these materials. The specific objectives of this dissertation are to; (a) evaluate the state of aramid fiber in AC and examine their impacts on the mechanical performance of asphalt mixtures; (b) evaluate the interaction of the reinforcement efficiency of fibers with compositions of asphalt mixtures; (c) evaluate tensile and fracture properties of M-FRAC; (d) evaluate the interfacial shear bond strength and critical fiber length in M-FRAC; and (e) propose micromechanical models for prediction of the tensile strength of M-FRAC. The research approach to achieve these objectives included experimental measurements and theoretical considerations. Throughout the study, the mechanical response of specimens with and without fibers are scrutinized using standard test methods including flow number (AASHTO T 378) and uniaxial fatigue (AASHTO TP 107), and non-standard test methods for fiber extraction, direct tension, semi-circular bending, and single fiber pull-out tests. Then, the fiber reinforcement mechanism is further examined by using the basic theories of viscoelasticity as well as micromechanical models.
The findings of this study suggest that fibers do serve as a reinforcement element in AC; however, their reinforcing effectiveness depends on the state of fibers in the mix, temperature/ loading rate, properties of fiber (i.e. dosage, length), properties of mix type (gradation and binder content), and mechanical test type to characterize M-FRAC. The outcome of every single aforementioned elements identifies key reasons attributed to the fiber reinforcement efficiency in AC, which provides insights to justify the discrepancies in the literature and further recommends solutions to overcome the knowledge gaps. This improved insight will translate into the better deployment of existing fiber-based technologies; the development of new, and more effective fiber-based technologies in asphalt mixtures.