This collection includes most of the ASU Theses and Dissertations from 2011 to present. ASU Theses and Dissertations are available in downloadable PDF format; however, a small percentage of items are under embargo. Information about the dissertations/theses includes degree information, committee members, an abstract, supporting data or media.

In addition to the electronic theses found in the ASU Digital Repository, ASU Theses and Dissertations can be found in the ASU Library Catalog.

Dissertations and Theses granted by Arizona State University are archived and made available through a joint effort of the ASU Graduate College and the ASU Libraries. For more information or questions about this collection contact or visit the Digital Repository ETD Library Guide or contact the ASU Graduate College at gradformat@asu.edu.

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Description
The demand for portland cement concrete is expected to increase over time. There is a need to develop a more sustainable cementitious systems in order to reduce the negative environmental impacts associated with ordinary portland cement (OPC) production. An attempt is made to investigate sustainable binder solutions through the use

The demand for portland cement concrete is expected to increase over time. There is a need to develop a more sustainable cementitious systems in order to reduce the negative environmental impacts associated with ordinary portland cement (OPC) production. An attempt is made to investigate sustainable binder solutions through the use of alternative cementitious materials at high levels of volume replacement. Limestone, an abundant material is used as a filler in low water-to-powder concretes where a substantial fraction of the portland cement remains unhydrated. At high volume OPC replacement, 20% and 35%, the combination of limestone and an alumina source has been shown to improve mechanical and durability performance. At 20% OPC replacement levels the migration coefficient which is an indication of chloride penetration in concrete is lower than the OPC control mixture at 28 and 56 days of hydration. The use of limestone with a similar particle size distribution to that of the OPC is used in each of these blended systems. A 20% binary limestone blend provide similar strength to an OPC mortar at all ages and comparable transport properties to that of the OPC concrete. Fly ash and metakaolin are the two alumina sources for the ternary blended mixes with concrete. The metakaolin shows the highest increase in the amount of hydration products formed out of all the mixes, including calcium-silicate-hydrate and carboaluminate phases in combination with limestone powder. At both levels of replacement the metakaolin blends show a substantially lower migration coefficient which is contributed to the smaller pore sizes found in the metakaolin blends. The fracture response of these systems show that at all replacement levels the ductility of the systems increase indicated by the large critical crack tip opening displacement. The fracture toughness is the highest for the blend containing metakaolin indicative of the smaller pore sizes allowing more dissipation of energy. An attempt is made to relate all mechanical and durability parameters to the reaction products and pore-structure developing at later ages.
ContributorsAguayo, Matthew (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2014
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Description
Concrete is the most widely used infrastructure material worldwide. Production of portland cement, the main binding component in concrete, has been shown to require significant energy and account for approximately 5-7% of global carbon dioxide production. The expected continued increased use of concrete over the coming decades indicates this is

Concrete is the most widely used infrastructure material worldwide. Production of portland cement, the main binding component in concrete, has been shown to require significant energy and account for approximately 5-7% of global carbon dioxide production. The expected continued increased use of concrete over the coming decades indicates this is an ideal time to implement sustainable binder technologies. The current work aims to explore enhanced sustainability concretes, primarily in the context of limestone and flow. Aspects such as hydration kinetics, hydration product formation and pore structure add to the understanding of the strength development and potential durability characteristics of these binder systems. Two main strategies for enhancing this sustainability are explored in this work: (i) the use of high volume limestone in combination with other alternative cementitious materials to decrease the portland cement quantity in concrete and (ii) the use of geopolymers as the binder phase in concrete. The first phase of the work investigates the use of fine limestone as cement replacement from the perspective of hydration, strength development, and pore structure. The nature of the potential synergistic benefit of limestone and alumina will be explored. The second phase will focus on the rheological characterization of these materials in the fresh state, as well as a more general investigation of the rheological characterization of suspensions. The results of this work indicate several key ideas. (i) There is a potential synergistic benefit for strength, hydration, and pore structure by using alumina and in portland limestone cements, (ii) the limestone in these systems is shown to react to some extent, and fine limestone is shown to accelerate hydration, (iii) rheological characteristics of cementitious suspensions are complex, and strongly dependent on several key parameters including: the solid loading, interparticle forces, surface area of the particles present, particle size distribution of the particles, and rheological nature of the media in which the particles are suspended, and (iv) stress plateau method is proposed for the determination of rheological properties of concentrated suspensions, as it more accurately predicts apparent yield stress and is shown to correlate well with other viscoelastic properties of the suspensions.
ContributorsVance, Kirk (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Mobasher, Barzin (Committee member) / Chawla, Nikhilesh (Committee member) / Marzke, Robert (Committee member) / Arizona State University (Publisher)
Created2014
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Description
The concept of Creep is a term used to define the tendency of stressed materials to develop an increasing strain through time under a sustained load, thus having an increase in deflection or having an elongation with time in relation to the short term strain. While the subject of compression

The concept of Creep is a term used to define the tendency of stressed materials to develop an increasing strain through time under a sustained load, thus having an increase in deflection or having an elongation with time in relation to the short term strain. While the subject of compression creep of concrete is well developed, use of concrete under tension loads has been limited at best due to brittleness of concrete. However with the advent of using fiber reinforced concrete, more and more applications where concrete is expected to carry tensile loads due to incorporation of fibers is gaining popularity. While the creep behavior of concrete in tension is important, the main case of the study is what happened when the concrete that is cracked in service is subjected to sustained loads causing creep. The relationship of opening cracks under these conditions are of utmost importance especially when the serviceability criteria is addressed. Little work has been reported in literature on the long-term behavior of FRC under sustained flexural loadings. The main objective of this study is to investigate the Long Term Flexural Behavior of Pre-Cracked Fiber Reinforced Beams under Sustained Loads. The experimental reports document the effect of loading and temperature on the creep characteristics of concrete. A variety of study has been carried out for the different responses generated by the creep tests based on factors like effect of temperature and humidity, effect of fiber content, effect of fiber type, and effect of different loading levels.

The Creep Testing Experimental Methodology is divided into three main parts which includes: (1) The Pre-cracking Partial Fracture Test; (2) Creep Test; (3) Post Creep Full Fracture Test. The magnitude of load applied to a specific specimen during creep testing was based on the results of average residual strength (ARS) tests, determined using EN14651. Specimens of the synthetic FRC mixture were creep tested at loads nominally equivalent to 30% and 50% of the FR1 value. The creep tests are usually continued until a steady Time versus CMOD response was obtained for the specimen signifying its presence in the secondary stage of creep. The creep recovery response is generated after unloading the specimen from the creep set up and later a full fracture test is carried out to obtain the complete post creep response of the beam under flexure.

The behavior of the Creep Coefficient versus Time response has been studied using various existing models like the ACI 209-R 92 Model and the CEB-FIP Model. Basic and hybrid rheological viscoelastic models have also been used in order to generate the material behavior response. A study has been developed in order to understand the applicability of various viscoelastic models for obtaining the material response of real materials. An analytical model for predicting the Flexural Behavior of FRC under sustained creep loads is presented at the end. This model helps generate the stress strain and Moment Curvature response of FRC beams when subjected to creep loads post initial cracking
ContributorsGohel, Megha Rajendrakumar (Author) / Mobasher, Barzin (Thesis advisor) / Dharmarajan, Subramaniam (Committee member) / Neithalath, Narayanan (Committee member) / Arizona State University (Publisher)
Created2017