ASU Electronic Theses and Dissertations
This collection includes most of the ASU Theses and Dissertations from 2011 to present. ASU Theses and Dissertations are available in downloadable PDF format; however, a small percentage of items are under embargo. Information about the dissertations/theses includes degree information, committee members, an abstract, supporting data or media.
In addition to the electronic theses found in the ASU Digital Repository, ASU Theses and Dissertations can be found in the ASU Library Catalog.
Dissertations and Theses granted by Arizona State University are archived and made available through a joint effort of the ASU Graduate College and the ASU Libraries. For more information or questions about this collection contact or visit the Digital Repository ETD Library Guide or contact the ASU Graduate College at gradformat@asu.edu.
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Description
Ethylene vinyl acetate (EVA) is the most commonly used encapsulant in photovoltaic modules. However, EVA degrades over time and causes performance losses in PV system. Therefore, EVA degradation is a matter of concern from a durability point of view.
This work compares EVA encapsulant degradation in glass/backsheet and glass/glass field-aged PV modules. EVA was extracted from three field-aged modules (two glass/backsheet and one glass/glass modules) from three different manufacturers from various regions (cell edges, cell centers, and non-cell region) from each module based on their visual and UV Fluorescence images. Characterization techniques such as I-V measurements, Colorimetry, Different Scanning Calorimetry, Thermogravimetric Analysis, Raman spectroscopy, and Fourier Transform Infrared Spectroscopy were performed on EVA samples.
The intensity of EVA discoloration was quantified using colorimetric measurements. Module performance parameters like Isc and Pmax degradation rates were calculated from I-V measurements. Properties such as degree of crystallinity, vinyl acetate content and degree of crosslinking were calculated from DSC, TGA, and Raman measurements, respectively. Polyenes responsible for EVA browning were identified in FTIR spectra.
The results from the characterization techniques confirmed that when EVA undergoes degradation, crosslinking in EVA increases beyond 90% causing a decrease in the degree of crystallinity and an increase in vinyl acetate content of EVA. Presence of polyenes in FTIR spectra of degraded EVA confirmed the occurrence of Norrish II reaction. However, photobleaching occurred in glass/backsheet modules due to the breathable backsheet whereas no photobleaching occurred in glass/glass modules because they were hermetically sealed. Hence, the yellowness index along with the Isc and Pmax degradation rates of EVA in glass/glass module is higher than that in glass/backsheet modules.
The results implied that more acetic acid was produced in the non-cell region due to its double layer of EVA compared to the front EVA from cell region. But, since glass/glass module is hermetically sealed, acetic acid gets entrapped inside the module further accelerating EVA degradation whereas it diffuses out through backsheet in glass/backsheet modules. Hence, it can be said that EVA might be a good encapsulant for glass/backsheet modules, but the same cannot be said for glass/glass modules.
This work compares EVA encapsulant degradation in glass/backsheet and glass/glass field-aged PV modules. EVA was extracted from three field-aged modules (two glass/backsheet and one glass/glass modules) from three different manufacturers from various regions (cell edges, cell centers, and non-cell region) from each module based on their visual and UV Fluorescence images. Characterization techniques such as I-V measurements, Colorimetry, Different Scanning Calorimetry, Thermogravimetric Analysis, Raman spectroscopy, and Fourier Transform Infrared Spectroscopy were performed on EVA samples.
The intensity of EVA discoloration was quantified using colorimetric measurements. Module performance parameters like Isc and Pmax degradation rates were calculated from I-V measurements. Properties such as degree of crystallinity, vinyl acetate content and degree of crosslinking were calculated from DSC, TGA, and Raman measurements, respectively. Polyenes responsible for EVA browning were identified in FTIR spectra.
The results from the characterization techniques confirmed that when EVA undergoes degradation, crosslinking in EVA increases beyond 90% causing a decrease in the degree of crystallinity and an increase in vinyl acetate content of EVA. Presence of polyenes in FTIR spectra of degraded EVA confirmed the occurrence of Norrish II reaction. However, photobleaching occurred in glass/backsheet modules due to the breathable backsheet whereas no photobleaching occurred in glass/glass modules because they were hermetically sealed. Hence, the yellowness index along with the Isc and Pmax degradation rates of EVA in glass/glass module is higher than that in glass/backsheet modules.
The results implied that more acetic acid was produced in the non-cell region due to its double layer of EVA compared to the front EVA from cell region. But, since glass/glass module is hermetically sealed, acetic acid gets entrapped inside the module further accelerating EVA degradation whereas it diffuses out through backsheet in glass/backsheet modules. Hence, it can be said that EVA might be a good encapsulant for glass/backsheet modules, but the same cannot be said for glass/glass modules.
ContributorsPatel, Aesha Parimalbhai (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Green, Matthew (Committee member) / Mu, Bin (Committee member) / Arizona State University (Publisher)
Created2018
Description
Over the past decade, proton exchange membrane fuel cells have gained much momentum due to their environmental advantages and commutability over internal combustion engines. To carefully study the dynamic behavior of the fuel cells, a dynamic test stand to validate their performance is necessary. Much attention has been given to HiL (Hardware-in-loop) testing of the fuel cells, where the simulated FC model is replaced by a real hardware. This thesis presents an economical approach for closed loop HiL testing of PEM fuel cell. After evaluating the performance of the standalone fuel cell system, a fuel cell hybrid electric vehicle model was developed by incorporating a battery system. The FCHEV was tested with two different control strategies, viz. load following and thermostatic.
The study was done to determine the dynamic behavior of the FC when exposed to real-world drive cycles. Different parameters associated with the efficiency of the fuel cell were monitored. An electronic DC load was used to draw current from the FC. The DC load was controlled in real time with a NI PXIe-1071 controller chassis incorporated with NI PXI-6722 and NI PXIe-6341 controllers. The closed loop feedback was obtained with the temperatures from two surface mount thermocouples on the FC. The temperature of these thermocouples follows the curve of the FC core temperature, which is measured with a thermocouple located inside the fuel cell system. This indicates successful implementation of the closed loop feedback. The results show that the FC was able to satisfy the required power when continuous shifting load was present, but there was a discrepancy between the power requirements at times of peak acceleration and also at constant loads when ran for a longer time. It has also been found that further research is required to fully understand the transient behavior of the fuel cell temperature distribution in relation to their use in automotive industry. In the experimental runs involving the FCHEV model with different control strategies, it was noticed that the fuel cell response to transient loads improved and the hydrogen consumption of the fuel cell drastically decreased.
The study was done to determine the dynamic behavior of the FC when exposed to real-world drive cycles. Different parameters associated with the efficiency of the fuel cell were monitored. An electronic DC load was used to draw current from the FC. The DC load was controlled in real time with a NI PXIe-1071 controller chassis incorporated with NI PXI-6722 and NI PXIe-6341 controllers. The closed loop feedback was obtained with the temperatures from two surface mount thermocouples on the FC. The temperature of these thermocouples follows the curve of the FC core temperature, which is measured with a thermocouple located inside the fuel cell system. This indicates successful implementation of the closed loop feedback. The results show that the FC was able to satisfy the required power when continuous shifting load was present, but there was a discrepancy between the power requirements at times of peak acceleration and also at constant loads when ran for a longer time. It has also been found that further research is required to fully understand the transient behavior of the fuel cell temperature distribution in relation to their use in automotive industry. In the experimental runs involving the FCHEV model with different control strategies, it was noticed that the fuel cell response to transient loads improved and the hydrogen consumption of the fuel cell drastically decreased.
ContributorsGoyal, Govind (Author) / Ra'ouf Mayyas, Abdel (Thesis advisor) / Madakannan, Arunachalanadar (Committee member) / Dalrymple, Odesma (Committee member) / Arizona State University (Publisher)
Created2014