ASU Electronic Theses and Dissertations
This collection includes most of the ASU Theses and Dissertations from 2011 to present. ASU Theses and Dissertations are available in downloadable PDF format; however, a small percentage of items are under embargo. Information about the dissertations/theses includes degree information, committee members, an abstract, supporting data or media.
In addition to the electronic theses found in the ASU Digital Repository, ASU Theses and Dissertations can be found in the ASU Library Catalog.
Dissertations and Theses granted by Arizona State University are archived and made available through a joint effort of the ASU Graduate College and the ASU Libraries. For more information or questions about this collection contact or visit the Digital Repository ETD Library Guide or contact the ASU Graduate College at gradformat@asu.edu.
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- All Subjects: Alternative Energy
Description
Organic optoelectronic devices have remained a research topic of great interest over the past two decades, particularly in the development of efficient organic photovoltaics (OPV) and organic light emitting diodes (OLED). In order to improve the efficiency, stability, and materials variety for organic optoelectronic devices a number of emitting materials, absorbing materials, and charge transport materials were developed and employed in a device setting. Optical, electrical, and photophysical studies of the organic materials and their corresponding devices were thoroughly carried out. Two major approaches were taken to enhance the efficiency of small molecule based OPVs: developing material with higher open circuit voltages or improved device structures which increased short circuit current. To explore the factors affecting the open circuit voltage (VOC) in OPVs, molecular structures were modified to bring VOC closer to the effective bandgap, ∆EDA, which allowed the achievement of 1V VOC for a heterojunction of a select Ir complex with estimated exciton energy of only 1.55eV. Furthermore, the development of anode interfacial layer for exciton blocking and molecular templating provide a general approach for enhancing the short circuit current. Ultimately, a 5.8% PCE was achieved in a single heterojunction of C60 and a ZnPc material prepared in a simple, one step, solvent free, synthesis. OLEDs employing newly developed deep blue emitters based on cyclometalated complexes were demonstrated. Ultimately, a peak EQE of 24.8% and nearly perfect blue emission of (0.148,0.079) was achieved from PtON7dtb, which approaches the maximum attainable performance from a blue OLED. Furthermore, utilizing the excimer formation properties of square-planar Pt complexes, highly efficient and stable white devices employing a single emissive material were demonstrated. A peak EQE of over 20% for pure white color (0.33,0.33) and 80 CRI was achieved with the tridentate Pt complex, Pt-16. Furthermore, the development of a series of tetradentate Pt complexes yielded highly efficient and stable single doped white devices due to their halogen free tetradentate design. In addition to these benchmark achievements, the systematic molecular modification of both emissive and absorbing materials provides valuable structure-property relationship information that should help guide further developments in the field.
ContributorsFleetham, Tyler Blain (Author) / Li, Jian (Thesis advisor) / Alford, Terry (Committee member) / Adams, James (Committee member) / Arizona State University (Publisher)
Created2014
Description
This dissertation develops advanced controls for distributed energy systems and evaluates performance on technical and economic benefits. Microgrids and thermal systems are of primary focus with applications shown for residential, commercial, and military applications that have differing equipment, rate structures, and objectives. Controls development for residential energy heating and cooling systems implement adaptive precooling strategies and thermal energy storage, with comparisons made of each approach separately and then together with precooling and thermal energy storage. Case studies show on-peak demand and annual energy related expenses can be reduced by up to 75.6% and 23.5%, respectively, for a Building America B10 Benchmark home in Phoenix Arizona, Los Angeles California, and Kona Hawaii. Microgrids for commercial applications follow after with increased complexity. Three control methods are developed and compared including a baseline logic-based control, model predictive control, and model predictive control with ancillary service control algorithms. Case studies show that a microgrid consisting of 326 kW solar PV, 634 kW/ 634 kWh battery, and a 350 kW diesel generator can reduce on-peak demand and annual energy related expenses by 82.2% and 44.1%, respectively. Findings also show that employing a model predictive control algorithm with ancillary services can reduce operating expenses by 23.5% when compared to a logic-based algorithm. Microgrid evaluation continues with an investigation of off-grid operation and resilience for military applications. A statistical model is developed to evaluate the survivability (i.e. probability to meet critical load during an islanding event) to serve critical load out to 7 days of grid outage. Case studies compare the resilience of a generator-only microgrid consisting of 5,250 kW in generators and hybrid microgrid consisting of 2,250 kW generators, 3,450 kW / 13,800 kWh storage, and 16,479 kW solar photovoltaics. Findings show that the hybrid microgrid improves survivability by 10.0% and decreases fuel consumption by 47.8% over a 168-hour islanding event when compared to a generator-only microgrid under nominal conditions. Findings in this dissertation can increase the adoption of reliable, low cost, and low carbon distributed energy systems by improving the operational capabilities and economic benefits to a variety of customers and utilities.
ContributorsNelson, James Robert (Author) / Johnson, Nathan (Thesis advisor) / Stadler, Michael (Committee member) / Zhang, Wenlong (Committee member) / Arizona State University (Publisher)
Created2019