ASU Electronic Theses and Dissertations
This collection includes most of the ASU Theses and Dissertations from 2011 to present. ASU Theses and Dissertations are available in downloadable PDF format; however, a small percentage of items are under embargo. Information about the dissertations/theses includes degree information, committee members, an abstract, supporting data or media.
In addition to the electronic theses found in the ASU Digital Repository, ASU Theses and Dissertations can be found in the ASU Library Catalog.
Dissertations and Theses granted by Arizona State University are archived and made available through a joint effort of the ASU Graduate College and the ASU Libraries. For more information or questions about this collection contact or visit the Digital Repository ETD Library Guide or contact the ASU Graduate College at gradformat@asu.edu.
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- All Subjects: Alkali activation
- All Subjects: Composite
- Creators: Mobasher, Barzin
Description
The alkali activation of aluminosilicate materials as binder systems derived from industrial byproducts have been extensively studied due to the advantages they offer in terms enhanced material properties, while increasing sustainability by the reuse of industrial waste and byproducts and reducing the adverse impacts of OPC production. Fly ash and ground granulated blast furnace slag are commonly used for their content of soluble silica and aluminate species that can undergo dissolution, polymerization with the alkali, condensation on particle surfaces and solidification. The following topics are the focus of this thesis: (i) the use of microwave assisted thermal processing, in addition to heat-curing as a means of alkali activation and (ii) the relative effects of alkali cations (K or Na) in the activator (powder activators) on the mechanical properties and chemical structure of these systems. Unsuitable curing conditions instigate carbonation, which in turn lowers the pH of the system causing significant reductions in the rate of fly ash activation and mechanical strength development. This study explores the effects of sealing the samples during the curing process, which effectively traps the free water in the system, and allows for increased aluminosilicate activation. The use of microwave-curing in lieu of thermal-curing is also studied in order to reduce energy consumption and for its ability to provide fast volumetric heating. Potassium-based powder activators dry blended into the slag binder system is shown to be effective in obtaining very high compressive strengths under moist curing conditions (greater than 70 MPa), whereas sodium-based powder activation is much weaker (around 25 MPa). Compressive strength decreases when fly ash is introduced into the system. Isothermal calorimetry is used to evaluate the early hydration process, and to understand the reaction kinetics of the alkali powder activated systems. A qualitative evidence of the alkali-hydroxide concentration of the paste pore solution through the use of electrical conductivity measurements is also presented, with the results indicating the ion concentration of alkali is more prevalent in the pore solution of potassium-based systems. The use of advanced spectroscopic and thermal analysis techniques to distinguish the influence of studied parameters is also discussed.
ContributorsChowdhury, Ussala (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramanium D. (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2013
Description
The main objective of this study is to investigate drying properties and plastic shrinkage cracking resistance of fresh cement-based pastes reinforced with fibers and textiles. Naturally occurring mineral wollastonite has been studied independently as well as in combination with AR-glass textile. A series of blended mixes with Portland cement and wollastonite nano-fibers were developed and tested under low vacuum conditions to simulate severe evaporation conditions and expedite the drying process causing plastic shrinkage cracks. Cumulative moisture loss, evaporation rates, and diffusivity were analyzed by means of a 2-stage diffusion simulation approach, developed previously in Arizona State University. Effect of fiber-matrix interaction on the transport properties of the composite were evaluated using the existing approach. Morphology of the cracked surface was investigated by the means of image analysis wherein length, width, area and density of the cracks were computed to help characterize the contribution of fiber and textile in the cracking phenomenon. Additionally, correlation between cumulative moisture loss and crack propagation was attempted. The testing procedures and associated analytical methods were applied to evaluate effectiveness of four wollastonite fiber sizes and also a hybrid reinforcement system with alkali-resistant glass (ARG) textile in improving shrinkage cracking related parameters. Furthermore, the experimental and analytical approach was extended to magnified version of the existing shrinkage testing set-up to study the size effect of these composites when subjected to matching drying conditions. Different restraining mechanisms were used to study the simulation of the cracking phenomena on a larger specimen. Paste and mortar formulations were developed to investigate size effect on shrinkage resistance of cementitious composites.
ContributorsKachala, Robert (Author) / Mobasher, Barzin (Thesis advisor) / Dharmarajan, Subramaniam (Committee member) / Neithalath, Narayanan (Committee member) / Arizona State University (Publisher)
Created2014
Description
Composite materials are finally providing uses hitherto reserved for metals in structural systems applications – airframes and engine containment systems, wraps for repair and rehabilitation, and ballistic/blast mitigation systems. They have high strength-to-weight ratios, are durable and resistant to environmental effects, have high impact strength, and can be manufactured in a variety of shapes. Generalized constitutive models are being developed to accurately model composite systems so they can be used in implicit and explicit finite element analysis. These models require extensive characterization of the composite material as input. The particular constitutive model of interest for this research is a three-dimensional orthotropic elasto-plastic composite material model that requires a total of 12 experimental stress-strain curves, yield stresses, and Young’s Modulus and Poisson’s ratio in the material directions as input. Sometimes it is not possible to carry out reliable experimental tests needed to characterize the composite material. One solution is using virtual testing to fill the gaps in available experimental data. A Virtual Testing Software System (VTSS) has been developed to address the need for a less restrictive method to characterize a three-dimensional orthotropic composite material. The system takes in the material properties of the constituents and completes all 12 of the necessary characterization tests using finite element (FE) models. Verification and validation test cases demonstrate the capabilities of the VTSS.
ContributorsHarrington, Joseph (Author) / Rajan, Subramaniam D. (Thesis advisor) / Neithalath, Narayanan (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2015
Description
Pultrusion manufacturing technique stands at the forefront for efficient production of continuous, uniform concrete composites for use in large scale structural applications. High volume and low labor, among other benefits such as improved impregnation and better sample consistency, stand as some of the crucial advances found in automated pultrusion. These advantages introduce textile reinforced concrete (TRC) composites as a potential surrogate for wood, light gauge steel, and other common structural materials into an ever changing and broadening market of industrial grade structural sections. With the potential modifications of textile geometry, textile type, section geometry, and connection type, the options presented by TRC sections seem nearly boundless. Automated pultrusion presents the ability to manufacture many different TRC composite types in at a quickened rate opening up a new field of study of structural materials.
The objective of this study centered on two studies including the development of an automated pultrusion system for the manufacturing of TRC composites and ultimately the assessment of composites created with the pultrusion technique and their viability as a relevant structural construction material. Upon planning, fabrication, and continued use of an automated pultrusion system in Arizona State University’s Structures Lab, an initial, comparative study of polypropylene microfiber composites was conducted to assess fiber reinforced concrete composites, manufactured with Filament Winding Technique, and textile reinforced concrete composites, manufactured with Automated Pultrusion Technique, in tensile and flexural mechanical response at similar reinforcement dosages. A secondary study was then conducted to measure the mechanical behavior of carbon, polypropylene, and alkali-resistant glass TRC composites and explore the response of full scale TRC structural shapes, including angle and channel sections. Finally, a study was conducted on the connection type for large scale TRC composite structural sections in tension and compression testing.
The objective of this study centered on two studies including the development of an automated pultrusion system for the manufacturing of TRC composites and ultimately the assessment of composites created with the pultrusion technique and their viability as a relevant structural construction material. Upon planning, fabrication, and continued use of an automated pultrusion system in Arizona State University’s Structures Lab, an initial, comparative study of polypropylene microfiber composites was conducted to assess fiber reinforced concrete composites, manufactured with Filament Winding Technique, and textile reinforced concrete composites, manufactured with Automated Pultrusion Technique, in tensile and flexural mechanical response at similar reinforcement dosages. A secondary study was then conducted to measure the mechanical behavior of carbon, polypropylene, and alkali-resistant glass TRC composites and explore the response of full scale TRC structural shapes, including angle and channel sections. Finally, a study was conducted on the connection type for large scale TRC composite structural sections in tension and compression testing.
ContributorsBauchmoyer, Jacob Macgregor (Author) / Mobasher, Barzin (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Neithalath, Narayanan (Committee member) / Arizona State University (Publisher)
Created2017
Description
Alkali activated mine tailing-slag blends and mine tailing-cement blends containing mine tailings as the major binder constituent are evaluated for their setting time behavior,
reactivity properties, flow characteristics, and compressive strengths. Liquid sodium
silicate and sodium hydroxide are used as the activator solution. The effects of varying
alkali oxide-to-powder ratio (n value) and silicon oxide-to-alkali oxide ratio (Ms value) is
explored. The reactivity of all blends prepared in this study is studied using an isothermal
calorimeter. Mine tailing-cement blends show a higher initial heat release peak than mine
tailing-slag blends, whereas their cumulative heat release is comparable for higher n values
of 0.050 to 0.100. Compressive strength tests and rheological studies were done for the
refined blends selected based on setting time criterion. Setting times and compressive
strengths are found to depend significantly on the activator parameters and binder
compositions, allowing fine-tuning of the mix proportion parameters based on the intended
end applications. The compressive strength of the selected mine tailing-slag blends and
mine tailing-cement blends are in the range of 7-40 MPa and 4-11 MPa, respectively.
Higher compressive strength is generally achieved at lower Ms and higher n values for mine
tailing-slag blends, while a higher Ms yields better compressive strength in the case of mine
tailing-cement blends. Rheological studies indicate a decrease in yield stress and viscosity
with increase in the replacement ratio, while a higher activator concentration increase both.
Oscillatory shear studies were used to evaluate the storage modulus and loss modulus of
the mine tailing binders. The paste is seen to exhibit a more elastic behavior at n values of
0.05 and 0.075, however the viscous behavior is seen to dominate at higher n value of 0.1
at similar replacement ratios and Ms value. A higher Ms value is also seen to increase the
onset point of the drop in both the storage and loss modulus of the pastes. The studied also
investigated the potential use of mine tailing blends for coating applications. The pastes
with higher alkalinity showed a lesser crack percentage, with a 10% slag replacement ratio
having a better performance compared to 20% and 30% slag replacement ratios. Overall,
the study showed that the activation parameters and mine tailings replacement level have
a significant influence on the properties of both mine tailing-slag binders and mine tailing-cement binders, thereby allowing selection of suitable mix design for the desired end
application, allowing a sustainable approach to dispose the mine tailings waste
ContributorsRamasamy Jeyaprakash, Rijul Kanth (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramaniam (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2023
Description
Alkali-activated aluminosilicates, commonly known as "geopolymers", are being increasingly studied as a potential replacement for Portland cement. These binders use an alkaline activator, typically alkali silicates, alkali hydroxides or a combination of both along with a silica-and-alumina rich material, such as fly ash or slag, to form a final product with properties comparable to or better than those of ordinary Portland cement. The kinetics of alkali activation is highly dependent on the chemical composition of the binder material and the activator concentration. The influence of binder composition (slag, fly ash or both), different levels of alkalinity, expressed using the ratios of Na2O-to-binders (n) and activator SiO2-to-Na2O ratios (Ms), on the early age behavior in sodium silicate solution (waterglass) activated fly ash-slag blended systems is discussed in this thesis. Optimal binder composition and the n values are selected based on the setting times. Higher activator alkalinity (n value) is required when the amount of slag in the fly ash-slag blended mixtures is reduced. Isothermal calorimetry is performed to evaluate the early age hydration process and to understand the reaction kinetics of the alkali activated systems. The differences in the calorimetric signatures between waterglass activated slag and fly ash-slag blends facilitate an understanding of the impact of the binder composition on the reaction rates. Kinetic modeling is used to quantify the differences in reaction kinetics using the Exponential as well as the Knudsen method. The influence of temperature on the reaction kinetics of activated slag and fly ash-slag blends based on the hydration parameters are discussed. Very high compressive strengths can be obtained both at early ages as well as later ages (more than 70 MPa) with waterglass activated slag mortars. Compressive strength decreases with the increase in the fly ash content. A qualitative evidence of leaching is presented through the electrical conductivity changes in the saturating solution. The impact of leaching and the strength loss is found to be generally higher for the mixtures made using a higher activator Ms and a higher n value. Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR) is used to obtain information about the reaction products.
ContributorsChithiraputhiran, Sundara Raman (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, Subramaniyam D (Committee member) / Mobasher, Barzin (Committee member) / Arizona State University (Publisher)
Created2012