This collection includes most of the ASU Theses and Dissertations from 2011 to present. ASU Theses and Dissertations are available in downloadable PDF format; however, a small percentage of items are under embargo. Information about the dissertations/theses includes degree information, committee members, an abstract, supporting data or media.

In addition to the electronic theses found in the ASU Digital Repository, ASU Theses and Dissertations can be found in the ASU Library Catalog.

Dissertations and Theses granted by Arizona State University are archived and made available through a joint effort of the ASU Graduate College and the ASU Libraries. For more information or questions about this collection contact or visit the Digital Repository ETD Library Guide or contact the ASU Graduate College at gradformat@asu.edu.

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In these times of increasing industrialization, there arises a need for effective and energy efficient heat transfer/heat exchange devices. The focus nowadays is on identifying various methods and techniques which can aid the process of developing energy efficient devices. One of the most common heat transfer devices is a heat

In these times of increasing industrialization, there arises a need for effective and energy efficient heat transfer/heat exchange devices. The focus nowadays is on identifying various methods and techniques which can aid the process of developing energy efficient devices. One of the most common heat transfer devices is a heat exchanger. Heat exchangers are an essential commodity to any industry and their efficiency can play an important role in making industries energy efficient and reduce the energy losses in the devices, in turn decreasing energy inputs to run the industry.

One of the ways in which we can improve the efficiency of heat exchangers is by applying ultrasonic energy to a heat exchanger. This research explores the possibility of introducing the external input of ultrasonic energy to increase the efficiency of the heat exchanger. This increase in efficiency can be estimated by calculating the parameters important for the characterization of a heat exchanger, which are effectiveness (ε) and overall heat transfer coefficient (U). These parameters are calculated for both the non-ultrasound and ultrasound conditions in the heat exchanger.

This a preliminary study of ultrasound and its effect on a conventional shell-and-coil heat exchanger. From the data obtained it can be inferred that the increase in effectiveness and overall heat transfer coefficient upon the application of ultrasound is 1% and 6.22% respectively.
ContributorsAnnam, Roshan Sameer (Author) / Phelan, Patrick (Thesis advisor) / Rykaczewski, Konrad (Committee member) / Milcarek, Ryan (Committee member) / Arizona State University (Publisher)
Created2019
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Description
Advanced fibrous composite materials exhibit outstanding thermomechanical performance under extreme environments, which make them ideal for structural components that are used in a wide range of aerospace, nuclear, and defense applications. The integrity and residual useful life of these components, however, are strongly influenced by their inherent material flaws and

Advanced fibrous composite materials exhibit outstanding thermomechanical performance under extreme environments, which make them ideal for structural components that are used in a wide range of aerospace, nuclear, and defense applications. The integrity and residual useful life of these components, however, are strongly influenced by their inherent material flaws and defects resulting from the complex fabrication processes. These defects exist across multiple length scales and govern several scale-dependent inelastic deformation mechanisms of each of the constituents as well as their composite damage anisotropy. Tailoring structural components for optimal performance requires addressing the knowledge gap regarding the microstructural material morphology that governs the structural scale damage and failure response. Therefore, there is a need for a high-fidelity multiscale modeling framework and scale-specific in-situ experimental characterization that can capture complex inelastic mechanisms, including damage initiation and propagation across multiple length scales. This dissertation presents a novel multiscale computational framework that accounts for experimental information pertinent to microstructure morphology and architectural variabilities to investigate the response of ceramic matrix composites (CMCs) with manufacturing-induced defects. First, a three-dimensional orthotropic viscoplasticity creep formulation is developed to capture the complex temperature- and time-dependent constituent load transfer mechanisms in different CMC material systems. The framework also accounts for a reformulated fracture mechanics-informed matrix damage model and the Curtin progressive fiber damage model to capture the complex scale-dependent damage and failure mechanisms through crack kinetics and porosity growth. Next, in-situ experiments using digital image correlation (DIC) are performed to capture the damage and failure mechanisms in CMCs and to validate the high-fidelity modeling results. The dissertation also presents an exhaustive experimental investigation into the effects of temperature and manufacturing-induced defects on toughened epoxy adhesives and hybrid composite-metallic bonded joints. Nondestructive evaluation techniques are utilized to characterize the inherent defects morphology of the bulk adhesives and bonded interface. This is followed by quasi-static tensile tests conducted at extreme hot and cold temperature conditions. The damage mechanisms and failure modes are investigated using in-situ DIC and a high-resolution camera. The information from the morphology characterization studies is used to reconstruct high-fidelity geometries of the test specimens for finite element analysis.
ContributorsKhafagy, Khaled Hassan Abdo (Author) / Chattopadhyay, Aditi (Thesis advisor) / Fard, Masoud Y. (Committee member) / Milcarek, Ryan (Committee member) / Stoumbos, Tom (Committee member) / Borkowski, Luke (Committee member) / Arizona State University (Publisher)
Created2022
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Description
Solid Oxide Fuel Cells (SOFCs) generate electricity using only hydrogen and oxygen and they form H2O as the only byproduct, giving them the potential to significantly reduce carbon emissions and the impacts of global warming. In order to meet the global power demands today, SOFCs need to significantly increase their

Solid Oxide Fuel Cells (SOFCs) generate electricity using only hydrogen and oxygen and they form H2O as the only byproduct, giving them the potential to significantly reduce carbon emissions and the impacts of global warming. In order to meet the global power demands today, SOFCs need to significantly increase their power density and improve robustness in startup and cycling operations. This study explores the impact of decreasing the anode thickness to improve the mass transport of the fuel through the anode of a micro-tubular (mT) SOFC because few studies have reported the correlation between the two. Decreasing the thickness decreases the chance for concentration overpotential which is caused by not enough of the reactants being able to reach the reaction site while products are not able to be removed quickly enough. Experiments were performed in a split tube furnace heated to 750°C with nickel-yttria stabilized zirconia (Ni-YSZ) supported cells. Pure hydrogen was supplied to the cell at rates of 10, 20, 30, and 40 mL/min while the cathode was supplied air from the environment. The cell's performance was studied using the current-voltage method to generate polarization curves and electrochemical impedance spectroscopy to create Bode and Nyquist plots. The results from the electrochemical impedance spectroscopy show a lower impedance for the frequencies pertaining to the gas diffusion in the anode for the thinner cells. This suggests that decreasing the anode thickness increases the mass transport of the gas. Additionally, through a distribution of relaxation times (DRT) analysis, the peaks vary between the two cell thicknesses at the frequencies pertaining to gas diffusion in anode-supported cells, implicating the decreased resistance created by thinning the anode layer.
ContributorsPhillips, Kristina (Author) / Milcarek, Ryan (Thesis advisor) / Wang, Robert (Committee member) / Phelan, Patrick (Committee member) / Arizona State University (Publisher)
Created2023
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Description
Solar energy as a limitless source of energy all around the globe has been difficult to harness. This is due to the low direct solar-electric conversion efficiency which has an upper limit set to the Shockley-Queisser limit. Solar thermophotovoltaics (STPV) is a much more efficient solar energy harvesting technology as

Solar energy as a limitless source of energy all around the globe has been difficult to harness. This is due to the low direct solar-electric conversion efficiency which has an upper limit set to the Shockley-Queisser limit. Solar thermophotovoltaics (STPV) is a much more efficient solar energy harvesting technology as it has the potential to overcome the Shockley-Queisser limit, by converting the broad-spectrum solar irradiation into narrowband infrared spectrum radiation matched to the PV cell. Despite the potential to surpass the Shockley-Queisser limit, very few experimental results have reported high system-level efficiency.

The objective of the thesis is to study the STPV conversion performance with selective metafilm absorber and emitter paired with a commercial GaSb cell at different solar concentrations. Absorber and Emitter metafilm thickness was optimized and fabricated. The optical properties of fabricated metafilms showed good agreement with the theoretically determined properties. The experimental setup was completed and validated by measuring the heat transfer rate across the test setup and comparing it with theoretical calculations. A novel method for maintaining the gap between the emitter and PV cell was developed using glass microspheres. Theoretical calculations show that the use of the glass of microspheres introduces negligible conduction loss across the gap compared to the radiation heat transfer, which is confirmed by experimental heat transfer measurement. This research work will help enhance the fundamental understanding and the development of the high-efficiency solar thermophotovoltaic system.
ContributorsNayal, Avinash (Author) / Wang, Liping (Thesis advisor) / Wang, Robert (Committee member) / Milcarek, Ryan (Committee member) / Arizona State University (Publisher)
Created2020
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Description
The presence of huge amounts of waste heat and the constant demand for electric energy makes this an appreciable research topic, yet at present there is no commercially viable technology to harness the inherent energy resource provided by the temperature differential between the inside and outside of buildings. In a

The presence of huge amounts of waste heat and the constant demand for electric energy makes this an appreciable research topic, yet at present there is no commercially viable technology to harness the inherent energy resource provided by the temperature differential between the inside and outside of buildings. In a newly developed technology, electricity is generated from the temperature gradient between building walls through a Seebeck effect. A 3D-printed triply periodic minimal surface (TPMS) structure is sandwiched in copper electrodes with copper (I) sulphate (Cu2SO4) electrolyte to mimic a thermogalvanic cell. Previous studies mainly concentrated on mechanical properties and the electric power generation ability of these structures; however, the goal of this study is to estimate the thermal resistance of the 3D-printed TPMS experimentally. This investigation elucidates their thermal resistances which in turn helps to appreciate the power output associated in the thermogalvanic structure. Schwarz P, Gyroid, IWP, and Split P geometries were considered for the experiment with electrolyte in the thermogalvanic brick. Among these TPMS structures, Split P was found more thermally resistive than the others with a thermal resistance of 0.012 m2 K W-1. The thermal resistances of Schwarz D and Gyroid structures were also assessed experimentally without electrolyte and the results are compared to numerical predictions in a previous Mater's thesis.
ContributorsDasinor, Emmanuel (Author) / Phelan, Patrick (Thesis advisor) / Milcarek, Ryan (Committee member) / Bhate, Dhruv (Committee member) / Arizona State University (Publisher)
Created2020
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Description
Energy storage technologies are essential to overcome the temporal variability in renewable energy. The primary aim of this thesis is to develop reactor solutions to better analyze the potential of thermochemical energy storage (TCES) using non-stoichiometric metal oxides, for the multi-day energy storage application. A TCES system consists of a

Energy storage technologies are essential to overcome the temporal variability in renewable energy. The primary aim of this thesis is to develop reactor solutions to better analyze the potential of thermochemical energy storage (TCES) using non-stoichiometric metal oxides, for the multi-day energy storage application. A TCES system consists of a reduction reactor and an insulated MOx storage bin. The reduction reactor heats (to ~ 1100 °C) and partially reduces the MOx, thereby adding sensible and chemical energy (i.e., charging it) under reduced pO2 environments (~10 Pa). Inert gas removes the oxygen generated during reduction. The storage bin holds the hot and partially reduced MOx (typically particles) until it is used in an energy recovery device (i.e., discharge). Irrespective of the reactor heat source (here electrical), or the particle-inert gas flows (here countercurrent), the thermal reduction temperature and inert gas (here N2) flow minimize when the process approaches reversibility, i.e., operates near equilibrium. This study specifically focuses on developing a reduction reactor based on the theoretical considerations for approaching reversibility along the reaction path. The proposed Zigzag flow reactor (ZFR) is capable of thermally reducing CAM28 particles at temperatures ~ 1000 °C under an O2 partial pressure ~ 10 Pa. The associated analytical and numerical models analyze the reaction equilibrium under a real (discrete) reaction path and the mass transfer kinetic conditions necessary to approach equilibrium. The discrete equilibrium model minimizes the exergy destroyed in a practical reactor and identifies methods of maximizing the energy storage density () and the exergetic efficiency. The mass transfer model analyzes the O2 N2 concentration boundary layers to recommend sizing considerations to maximize the reactor power density. Two functional ZFR prototypes, the -ZFR and the -ZFR, establish the proof of concept and achieved a reduction extent, Δδ = 0.071 with CAM28 at T~950 °C and pO2 = 10 Pa, 7x higher than a previous attempt in the literature. The -ZFR consistently achieved  > 100 Wh/kg during >10 h. runtime and the -ZFR displayed an improved  = 130 Wh/kg during >5 h. operation with CAM28. A techno-economic model of a grid-scale ZFR with an associated storage bin analyzes the cost of scaling the ZFR for grid energy storage requirements. The scaled ZFR capital costs contribute < 1% to the levelized cost of thermochemical energy storage, which ranges from 5-20 ¢/kWh depending on the storage temperature and storage duration.
ContributorsGhotkar, Rhushikesh (Author) / Milcarek, Ryan (Thesis advisor) / Ermanoski, Ivan (Committee member) / Phelan, Patrick (Committee member) / Wang, Liping (Committee member) / Wang, Robert (Committee member) / Arizona State University (Publisher)
Created2023
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Description
Ethylene is one of the most widely used organic compounds worldwide with ever increasing demand. Almost all the industries currently producing ethylene globally use the method of steam cracking, which, though highly selective and cost effective, is energy intensive along with having a high carbon footprint. This study aims to

Ethylene is one of the most widely used organic compounds worldwide with ever increasing demand. Almost all the industries currently producing ethylene globally use the method of steam cracking, which, though highly selective and cost effective, is energy intensive along with having a high carbon footprint. This study aims to analyze micro-scale partial oxidation of propane as a novel approach towards ethylene generation which is simpler, less energy consuming, operates at lower temperatures and causes minimum CO2 emission. The experimental study endeavors to maximize the ethylene production by investigating the effect of variables such as temperature, flow rate, equivalence ratio and reactor diameter. The micro-scale partial oxidation of propane is studied inside quartz tube reactors of 1 mm and 3 mm diameter at a temperature range of 800 to 900 oC, at varying flow rates of 10 to 100 sccm and equivalence ratios of 1 to 6. The study reveals ethylene yield has a strong dependence on all the above factors. However, the factors are not completely independent of each other. Adjusting certain factors and levels results in greater ethylene yields as high as 10%, but propane to ethylene conversion efficiency is approximately constant for most conditions. Low CO2 concentrations are also recorded for most of the factor and level combinations, indicating the potential to achieve lower CO2 yields compared to conventional approaches. The investigation indicates promise for application in the field of ethylene generation.
ContributorsMAHALKAR, PAWAN MUKUND (Author) / Milcarek, Ryan (Thesis advisor) / Kwon, Beomjin (Committee member) / Phelan, Patrick (Committee member) / Arizona State University (Publisher)
Created2023
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Description
This study investigates the energy saving potential of high albedo roof coatings which are designed to reflect a large proportion of solar radiation compared to traditional roofing materials. Using EnergyPlus simulations, the efficacy of silicone, acrylic, and aluminum roof coatings is assessed across two prototype commercial buildings—a standalone retail (2,294

This study investigates the energy saving potential of high albedo roof coatings which are designed to reflect a large proportion of solar radiation compared to traditional roofing materials. Using EnergyPlus simulations, the efficacy of silicone, acrylic, and aluminum roof coatings is assessed across two prototype commercial buildings—a standalone retail (2,294 m2 or 24,692 ft2) and a strip-mall (2,090 m2 or 22,500 ft2)—located in four cities: Phoenix, Houston, Los Angeles, and Miami. The performance of reflective coatings was compared with respect to a black roof having a solar reflectance of 5% and a thermal emittance of 90%. A sensitivity analysis was done to assess the impact of solar reflectance and thermal emittance on the ability of roof coatings to reduce surface temperatures, a key factor behind energy savings. This factor plays a crucial role in all three heat transfer mechanisms: conduction, convection, and radiation. The rooftop surface temperature exhibits considerable variation depending on the solar reflectance and thermal emittance attributes of the roof. A contour plot between these properties reveals that high values of both result in reduced cooling needs and a heating penalty which is insignificant when compared with cooling savings for cooling-dominant climates like Phoenix where the cooling demand significantly outweighs the heating demand, yielding significant energy savings. Furthermore, the study also investigates the effects of reflective coatings on buildings that have photovoltaic solar panels installed on them. This includes exploring their impact on building HVAC loads, as well as the performance improvement due to the reduced temperatures beneath them.
ContributorsSharma, Ajay Kumar (Author) / Phelan, Patrick (Thesis advisor) / Neithalath, Narayanan (Committee member) / Milcarek, Ryan (Committee member) / Arizona State University (Publisher)
Created2024
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Description
According to Our World in Data, the industry sector contributes approximately 5.2 percent of the world's greenhouse gas emissions in 2016 [1]. Of that percentage, the cement industry contributes approximately 3 percent, thus accounting for more than 57 percent of all greenhouse gas emissions within the industry sector. Industrial-scale heating

According to Our World in Data, the industry sector contributes approximately 5.2 percent of the world's greenhouse gas emissions in 2016 [1]. Of that percentage, the cement industry contributes approximately 3 percent, thus accounting for more than 57 percent of all greenhouse gas emissions within the industry sector. Industrial-scale heating that is powered by renewable energy sources has the potential to combat this issue. This paper aims to analyze and model the Reverse Brayton Cycle to be used as a heat pump in a novel cement production system. The Simple Reverse Brayton Cycle and its potential concerning performance indicators such as coefficient of performance and scalability are determined. A Regenerative Brayton cycle is modeled in MATLAB® programming in order to be optimized and compared to conventional processes that require higher temperatures. Traditional manufacturing methods are discussed. Furthermore, possible methods of improvement are explored to view its effect on performance and temperatures between stages within the cycle.
ContributorsRivera, Daniel E (Author) / Phelan, Patrick (Thesis advisor) / Milcarek, Ryan (Committee member) / Calhoun, Ronald (Committee member) / Arizona State University (Publisher)
Created2024