ASU Electronic Theses and Dissertations
This collection includes most of the ASU Theses and Dissertations from 2011 to present. ASU Theses and Dissertations are available in downloadable PDF format; however, a small percentage of items are under embargo. Information about the dissertations/theses includes degree information, committee members, an abstract, supporting data or media.
In addition to the electronic theses found in the ASU Digital Repository, ASU Theses and Dissertations can be found in the ASU Library Catalog.
Dissertations and Theses granted by Arizona State University are archived and made available through a joint effort of the ASU Graduate College and the ASU Libraries. For more information or questions about this collection contact or visit the Digital Repository ETD Library Guide or contact the ASU Graduate College at gradformat@asu.edu.
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- Genre: Masters Thesis
Description
A new analytical method is proposed for measuring the deuterium to hydrogen ratio (D/H) of non-stoichiometric water in hydrous minerals via pyrolysis facilitated gas-chromatography - isotope ratio mass spectrometry (GC-IRMS). Previously published analytical methods have reported a poorly understood nonlinear dependence of D/H on sample size, for which any accurate correction is difficult. This sample size effect been variously attributed to kinetic isotope fractionation within the mass spectrometer and peripheral instruments, ion source linearity issues, and an unstable H_3^+-factor or incorrect H_3^+-factor calculations. The cause of the sample size effect is here identified by examinations of individual chromatograms as well as bulk data from chromatographic peaks. It is here determined that it is primarily an artifact of the calculations employed by the manufacturer's computer program, used to both monitor the functions of the mass spectrometer and to collect data. Ancillary causes of the sample size effect include a combination of persistent background interferences and chromatographic separation of the isotopologues of molecular hydrogen. Previously published methods are evaluated in light of these findings. A new method of H_3^+-factor and D/H calculation is proposed which makes portions of the Isodat software as well as other published calculation methods unnecessary. Using this new method, D/H is measured in non-stoichiometric water in chert from the Cretaceous Edwards Group, Texas, as well as the Precambrian Kromberg Formation, South Africa, to assess hydrological conditions as well as to estimate the maximum average surface temperature during precipitation of the chert. Data from Cretaceous chert are consistent with previously published data and interpretations, based upon conventional analyses of large samples. Data from Precambrian chert are consistent with maximum average surface temperatures approaching 65°C during the Archean, instead of the much lower temperatures derived from erroneous methods of sample preparation and analysis. D/H is likewise measured in non-stoichiometric water in silicified basalt from the Precambrian Hooggenoeg Complex, South Africa. Data are shown to be consistent with D/H of the Archean ocean similar to present day values.
ContributorsSheehan, Michael Robert (Author) / Knauth, Leroy P (Thesis advisor) / Anbar, Ariel (Committee member) / Farmer, Jack (Committee member) / Arizona State University (Publisher)
Created2011
Description
Dust devils have proven to be commonplace on Mars, although their occurrence is unevenly distributed across the surface. They were imaged or inferred by all six successful landed spacecraft: the Viking 1 and 2 Landers (VL-1 and VL-2), Mars Pathfinder Lander, the Mars Exploration Rovers Spirit and Opportunity, and the Phoenix Mars Lander. Comparisons of dust devil parameters were based on results from optical and meteorological (MET) detection campaigns. Spatial variations were determined based on comparisons of their frequency, morphology, and behavior. The Spirit data spanning three consecutive martian years is used as the basis of comparison because it is the most extensive on this topic. Average diameters were between 8 and 115 m for all observed or detected dust devils. The average horizontal speed for all of the studies was roughly 5 m/s. At each site dust devil densities peaked between 09:00 and 17:00 LTST during the spring and summer seasons supporting insolation-driven convection as the primary formation mechanism. Seasonal number frequency averaged ~1 dust devils/ km2/sol and spanned a total of three orders of magnitude. Extrapolated number frequencies determined for optical campaigns at the Pathfinder and Spirit sites accounted for temporal and spatial inconsistencies and averaged ~19 dust devils/km2/sol. Dust fluxes calculated from Pathfinder data (5x10-4 kg/m2/s and 7x10-5 kg/m2/s) were well with in the ranges calculated from Spirit data (4.0x10-9 to 4.6x10-4 kg/m2/s for Season One, 5.2x10-7 to 6.2x10-5 kg/m2/s during Season Two, and 1.5x10-7 to 1.6x10-4 kg/m2/s during Season Three). Based on the results a campaign is written for improvements in dust devil detection at the Mars Science Laboratory's (MSL) site. Of the four remaining candidate MSL sites, the dusty plains of Gale crater may potentially be the site with the highest probability of dust devil activity.
ContributorsWaller, Devin (Author) / Greeley, Ronald (Thesis advisor) / Christensen, Philip R. (Philip Russel) (Committee member) / Cerveny, Randall (Committee member) / Arizona State University (Publisher)
Created2011
Description
The Santa Gertrudis Mining District of Sonora, Mexico contains more than a dozen purported Carlin-like, sedimentary-hosted, disseminated-gold deposits. A series of near-surface, mostly oxidized gold deposits were open-pit mined from the calcareous and clastic units of the Cretaceous Bisbee Group. Gold occurs as finely disseminated, sub-micron coatings on sulfides, associated with argillization and silicification of calcareous, carbonaceous, and siliciclastic sedimentary rocks in structural settings. Gold occurs with elevated levels of As, Hg, Sb, Pb, and Zn. Downhole drill data within distal disseminated gold zones reveal a 5:1 ratio of Ag:Au and strong correlations of Au to Pb and Zn. This study explores the timing and structural control of mineralization utilizing field mapping, geochemical studies, drilling, core logging, and structural analysis. Most field evidence indicates that mineralization is related to a single pulse of moderately differentiated, Eocene intrusives described as Mo-Cu-Au skarn with structurally controlled distal disseminated As-Ag-Au.
ContributorsGeier, John Jeffrey (Author) / Reynolds, Stephen J. (Thesis advisor) / Burt, Donald (Committee member) / Stump, Edmund (Committee member) / Arizona State University (Publisher)
Created2011
Description
The Byrd Glacier region of Antarctica is important for understanding the tectonic development and landscape evolution of the Transantarctic Mountains (TAM). This outlet glacier crossing the TAM marks a major discontinuity in the Neoproterozoic-early Paleozoic Ross orogen. The region has not been geologically mapped in detail, but previous studies have inferred a fault to exist beneath and parallel to the direction of flow of Byrd Glacier. Thermochronologic analysis has never been undertaken across Byrd Glacier, and little is known of the exhumation history of the region. The objectives of this study are to assess possible differential movement across the inferred Byrd Glacier fault, to measure the timing of exhumation, and to gain a better overall understanding of the structural architecture of the TAM. Apatites and zircons separated from rock samples collected from various locations north and south of Byrd Glacier were dated using single-crystal (U- Th)/He analysis. Similar cooling histories were revealed with comparable exhumation rates of 0.03 ± 0.003 and 0.04 ± 0.03 mm/yr north and south of Byrd Glacier from apatite data and somewhat similar rates of 0.06 ± 0.008 and 0.04 ± 0.01 mm/yr north and south of Byrd Glacier from zircon data. Age vs. elevation regressions indicate a vertical offset of 1379 ± 159 m and 4000 ± 3466 m from apatite and zircon data. To assess differential movement, the Kukri Peneplain (a regional unconformity) was utilized as a datum. On-site photographs, Landsat imagery, and Aster Global DEM data were combined to map Kukri Peneplain elevation points north and south of Byrd Glacier. The difference in elevation of the peneplain as projected across Byrd Glacier shows an offset of 1122 ± 4.7 m. This study suggests a model of relatively uniform exhumation followed by fault displacement that uplifted the south side of Byrd Glacier relative to the north side. Combining apatite and zircon (U-Th)/He analysis along with remote geomorphologic analysis has provided an understanding of the differential movement and exhumation history of crustal blocks in the Byrd Glacier region. The results complement thermochronologic and geomorphologic studies elsewhere within the TAM providing more information and a new approach.
ContributorsFoley, Daniel Joseph (Author) / Stump, Edmund (Thesis advisor) / Whipple, Kelin X (Committee member) / Hodges, Kip (Committee member) / Arizona State University (Publisher)
Created2011
Description
Meter-resolution topography gathered by LiDAR (Light Detection and Ranging) has become an indispensable tool for better understanding of many surface processes including those sculpting landscapes that record information about earthquake hazards for example. For this reason, and because of the spectacular representation of the phenomena that these data provide, it is appropriate to integrate these data into Earth science educational materials. I seek to answer the following research question: "will using the LiDAR topography data instead of, or alongside, traditional visualizations and teaching methods enhance a student's ability to understand geologic concepts such as plate tectonics, the earthquake cycle, strike-slip faults, and geomorphology?" In order to answer this question, a ten-minute introductory video on LiDAR and its uses for the study of earthquakes entitled "LiDAR: Illuminating Earthquake Hazards" was produced. Additionally, LiDAR topography was integrated into the development of an undergraduate-level educational activity, the San Andreas fault (SAF) earthquake cycle activity, designed to teach introductory Earth science students about the earthquake cycle. Both the LiDAR video and the SAF activity were tested in undergraduate classrooms in order to determine their effectiveness. A pretest and posttest were administered to introductory geology lab students. The results of these tests show a notable increase in understanding LiDAR topography and its uses for studying earthquakes from pretest to posttest after watching the video on LiDAR, and a notable increase in understanding the earthquake cycle from pretest to posttest using the San Andreas Fault earthquake cycle exercise. These results suggest that the use of LiDAR topography within these educational tools is beneficial for students when learning about the earthquake cycle and earthquake hazards.
ContributorsRobinson, Sarah Elizabeth (Author) / Arrowsmith, Ramon (Thesis advisor) / Reynolds, Stephen J. (Committee member) / Semken, Steven (Committee member) / Arizona State University (Publisher)
Created2011
Description
The spectacular geological panoramas of Grand Canyon National Park (GCNP) motivate the curiosity of visitors about geology. However, there is little research on how well these visitors understand the basic geologic principles on display in the Canyon walls. The new Trail of Time (ToT) interpretative exhibit along the South Rim uses Grand Canyon vistas to teach these principles. Now being visited by thousands daily, the ToT is a uniquely valuable setting for research on informal learning of geologic time and other basic geologic concepts. At the ToT, visitors are not only asked to comprehend a linear timeline, but to associate it with the strata exposed in the walls of the Canyon. The research addressed two primary questions: (1) how do visitors of the National Park use elements of the geologic landscape of the Grand Canyon to explain fundamental principles of relative geologic time? and (2) how do visitors reconcile the relationship between the horizontal ToT timeline and the vertical encoding of time in the strata exposed in the Canyon walls? Semi-structured interviews tracked participants' understanding of the ToT exhibit and of basic principles of geologic time. Administering the verbal analysis method of Chi (1997) to the interview transcripts, the researcher identified emergent themes related to how the respondents utilized the landscape to answer interview questions. Results indicate that a majority of respondents are able to understand principles of relative geologic time by utilizing both the observed and inferred landscape of Grand Canyon. Results also show that by applying the same integrated approach to the landscape, a majority of respondents are able to reconcile stratigraphic time with the horizontal ToT timeline. To gain deeper insight into the cognitive skills activated to correctly understand geologic principles the researcher used Dodick and Orion's application of Montangero's (1996) diachronic thinking model to code responses into three schemes: (1) transformation, (2) temporal organization, and (3) interstage linkage. Results show that correct responses required activation of the temporal organization scheme or the more advanced interstage linkage scheme. Appropriate application of these results can help inform the development of future outdoor interpretive geoscience exhibits.
ContributorsFrus, Rebecca (Author) / Semken, Steven (Thesis advisor) / Baker, Dale (Committee member) / Farmer, Jack (Committee member) / Arizona State University (Publisher)
Created2011
Description
The goal of this study is to gain a better understanding of earthquake distribution and regional tectonic structure across Arizona. To achieve this objective, I utilized seismic data from EarthScope's USArray Transportable Array (TA), which was deployed in Arizona from April 2006 to March 2009. With station spacing of approximately 70 km and ~3 years of continuous three-component broadband seismic data, the TA provided an unprecedented opportunity to develop the first seismicity catalog for Arizona without spatial sampling bias. In this study I developed a new data analysis workflow to detect smaller scale seismicity across a regional study area, which serves as a template for future regional analyses of TA data and similar datasets. The final event catalog produced for this study increased the total number of earthquakes documented in Arizona by more than 50% compared to the historical catalog, despite being generated from less than three years of continuous waveform data. I combined this new TA catalog with existing earthquake catalogs to construct a comprehensive historical earthquake catalog for Arizona. These results enabled the identification of several previously unidentified areas of seismic activity within the state, as well as two regions characterized by seismicity in the deeper (>20 km) crust. The catalog also includes 16 event clusters, 10 of which exhibited clear temporal clustering and swarm-like behavior. These swarms were distributed throughout all three physiographic provinces, suggesting that earthquake swarms occur regardless of tectonic or physiographic setting. I also conducted a case study for an earthquake swarm in June of 2007 near Theodore Roosevelt Lake, approximately 80 miles northeast of Phoenix. Families of events showed very similar character, suggesting a nearly identical source location and focal mechanism. We obtained focal mechanisms for the largest of these events, and found that they are consistent with normal faulting, expected in this area of the Arizona Transition Zone. Further, I observed no notable correlation between reservoir water level and seismicity. The occurrence of multiple historical earthquakes in the areas surrounding the reservoir indicates that this swarm was likely the result of tectonic strain release, and not reservoir induced seismicity.
ContributorsLockridge, Jeffrey Steven (Author) / Fouch, Matthew J (Thesis advisor) / Arrowsmith, Ramon (Thesis advisor) / Reynolds, Stephen J. (Committee member) / Arizona State University (Publisher)
Created2011
Description
The temperature of a planet's surface depends on numerous physical factors, including thermal inertia, albedo and the degree of insolation. Mars is a good target for thermal measurements because the low atmospheric pressure combined with the extreme dryness results in a surface dominated by large differences in thermal inertia, minimizing the effect of other physical properties. Since heat is propagated into the surface during the day and re-radiated at night, surface temperatures are affected by sub-surface properties down to several thermal skin depths. Because of this, orbital surface temperature measurements combined with a computational thermal model can be used to determine sub-surface structure. This technique has previously been applied to estimate the thickness and thermal inertia of soil layers on Mars on a regional scale, but the Mars Odyssey Thermal Emission Imaging System "THEMIS" instrument allows much higher-resolution thermal imagery to be obtained. Using archived THEMIS data and the KRC thermal model, a process has been developed for creating high-resolution maps of Martian soil layer thickness and thermal inertia, allowing investigation of the distribution of dust and sand at a scale of 100 m/pixel.
ContributorsHeath, Simon (Author) / Christensen, Philip R. (Philip Russel) (Thesis advisor) / Bel, James (Thesis advisor) / Hervig, Richard (Committee member) / Arizona State University (Publisher)
Created2013
Description
ABSTRACT The accretion of juvenile island-arc lithosphere by convergent tectonism during the Paleoproterozoic, in conjunction with felsic volcanism, resulted in the assembly, ductile to partial brittle deformation, uplift, and northwest-directed thrusting of rocks in the McDowell Mountains region and adjacent areas in the Mazatzal Orogenic belt. Utilizing lithologic characteristics and petrographic analysis of the Proterozoic bedrock, a correlation to the Alder series was established, revising the stratigraphic sequences described by earlier works. The central fold belt, composed of an open, asymmetric syncline and an overturned, isoclinal anticline, is cut by an axial-plane parallel reactivated thrust zone that is intruded by a deformed Paleoproterozoic mafic dike. Finite strain analyses of fold geometries, shear fabrics, foliations, fold vergence, and strained clasts point to Paleoproterozoic northwest-directed thrusting associated with the Mazatzal orogen at approximately 1650 million years ago. Previous studies constrained the regional P-T conditions to at least the upper andalusite-kyanite boundary at peak metamorphic conditions, which ranged from 4-6 kilobars and 350-450⁰ Celsius, although the plasticity of deformation in a large anticlinal core suggests that this represents the low end of the P-T conditions. Subsequent to deformation, the rocks were intruded by several granitoid plutons, likely of Mesoproterozoic age (1300-1400 Ma). A detailed analysis of Proterozoic strain solidly places the structure of the McDowell Mountains within the confines of the Mazatzal Orogeny, pending any contradictory geochronological data.
ContributorsVance, Brad (Author) / Reynolds, Stephen J. (Thesis advisor) / Semken, Steven (Committee member) / Stump, Edmund (Committee member) / Arizona State University (Publisher)
Created2012
Description
Tempe Terra, Mars, has a complex history marked by volcanism and tectonism. Investigation results presented here build on previous work to better determine the volcanic history of the Tempe volcanic province by identifying and mapping previously undetected vents, characterizing all vents, identifying spatial and temporal trends in eruptive styles, comparing vent density to similar provinces such as the Snake River Plains of Idaho and Syria Planum and determining absolute age relationships among the volcanic features. Crater size-frequency distribution model ages of 120 Ma to 2.4 Ga indicate the province has been active for over half of the planet's history. During that time, age decreases from southwest to northeast, a trend that parallels the dominant orientation of faulting in the region, providing further evidence that volcanic activity in the region is tectonically controlled (or the tectonics is magmatically controlled). Morphological variation with age hints at an evolving magma source (increasing viscosity) or changing eruption conditions (decreasing eruption rate or eruption through thicker lithosphere).
ContributorsManfredi, Leon (Author) / Clarke, Amanda B (Thesis advisor) / Williams, David A. (Thesis advisor) / Reynolds, Stephen J. (Committee member) / Arizona State University (Publisher)
Created2012