ASU Electronic Theses and Dissertations
This collection includes most of the ASU Theses and Dissertations from 2011 to present. ASU Theses and Dissertations are available in downloadable PDF format; however, a small percentage of items are under embargo. Information about the dissertations/theses includes degree information, committee members, an abstract, supporting data or media.
In addition to the electronic theses found in the ASU Digital Repository, ASU Theses and Dissertations can be found in the ASU Library Catalog.
Dissertations and Theses granted by Arizona State University are archived and made available through a joint effort of the ASU Graduate College and the ASU Libraries. For more information or questions about this collection contact or visit the Digital Repository ETD Library Guide or contact the ASU Graduate College at gradformat@asu.edu.
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Description
In this thesis the performance of a Hybrid AC System (HACS) is modeled and optimized. The HACS utilizes solar photovoltaic (PV) panels to help reduce the demand from the utility during peak hours. The system also includes an ice Thermal Energy Storage (TES) tank to accumulate cooling energy during off-peak hours. The AC runs continuously on grid power during off-peak hours to generate cooling for the house and to store thermal energy in the TES. During peak hours, the AC runs on the power supplied from the PV, and cools the house along with the energy stored in the TES. A higher initial cost is expected due to the additional components of the HACS (PV and TES), but a lower operational cost due to higher energy efficiency, energy storage and renewable energy utilization. A house cooled by the HACS will require a smaller size AC unit (about 48% less in the rated capacity), compared to a conventional AC system. To compare the cost effectiveness of the HACS with a regular AC system, time-of-use (TOU) utility rates are considered, as well as the cost of the system components and the annual maintenance. The model shows that the HACS pays back its initial cost of $28k in about 6 years with an 8% APR, and saves about $45k in total cost when compared to a regular AC system that cools the same house for the same period of 6 years.
ContributorsJubran, Sadiq (Author) / Phelan, Patrick (Thesis advisor) / Calhoun, Ronald (Committee member) / Trimble, Steve (Committee member) / Arizona State University (Publisher)
Created2011
Description
As world energy demands increase, research into more efficient energy production methods has become imperative. Heterogeneous catalysis and nanoscience are used to promote chemical transformations important for energy production. These concepts are important in solid oxide fuel cells (SOFCs) which have attracted attention because of their potential to provide an efficient and environmentally favorable power generation system. The SOFC is also fuel-flexible with the ability to run directly on many fuels other than hydrogen. Internal fuel reforming directly in the anode of the SOFC would greatly reduce the cost and complexity of the device. Methane is the simplest hydrocarbon and a main component in natural gas, making it useful when testing catalysts on the laboratory scale. Nickel (Ni) and gadolinium (Gd) doped ceria (CeO2) catalysts for potential use in the SOFC anode were synthesized with a spray drying method and tested for catalytic performance using partial oxidation of methane and steam reforming. The relationships between catalytic performance and structure were then investigated using X-ray diffraction, transmission electron microscopy, and environmental transmission electron microscopy. The possibility of solid solutions, segregated phases, and surface layers of Ni were explored. Results for a 10 at.% Ni in CeO2 catalyst reveal a poor catalytic behavior while a 20 at.% Ni in CeO2 catalyst is shown to have superior activity. The inclusion of both 10 at.% Gd and 10 at.% Ni in CeO2 enhances the catalytic performance. Analysis of the presence of Ni in all 3 samples reveals Ni heterogeneity and little evidence for extensive solid solution doping. Ni is found in small domains throughout CeO2 particles. In the 20 at.% Ni sample a segregated, catalytically active NiO phase is observed. Overall, it is found that significant interaction between Ni and CeO2 occurs that could affect the synthesis and functionality of the SOFC anode.
ContributorsCavendish, Rio (Author) / Crozier, Peter (Thesis advisor) / Adams, James (Committee member) / Smith, David (Committee member) / Arizona State University (Publisher)
Created2012
Description
Interdigitated back contact (IBC) solar cells have achieved the highest single junction silicon wafer-based solar cell power conversion efficiencies reported to date. This thesis is about the fabrication of a high-efficiency silicon heterojunction IBC solar cell for potential use as the bottom cell for a 3-terminal lattice-matched dilute-nitride Ga (In)NP(As)/Si monolithic tandem solar cell. An effective fabrication process has been developed and the process challenges related to open circuit voltage (Voc), series resistance (Rs), and fill factor (FF) are experimentally analyzed. While wet etching, the sample lost the initial passivation, and by changing the etchant solution and passivation process, the voltage at maximum power recovered to an initial value of over 710 mV before metallization. The factors reducing the series resistance loss in IBC cells were also studied. One of these factors was the Indium Tin Oxide (ITO) sputtering parameters, which impact the conductivity of the ITO layer and transport across the a-Si:H/ITO interface. For the standard recipe, the chamber pressure was 3.5 mTorr with no oxygen partial pressure, and the thickness of the ITO layer in contact with the a-Si:H layers, was optimized to 150 nm. The patterning method for the metal contacts and final annealing also change the contact resistance of the base and emitter stack layers. The final annealing step is necessary to recover the sputtering damage; however, the higher the annealing time the higher the final IBC series resistance. The best efficiency achieved was 19.3% (Jsc = 37 mA/cm2, Voc = 691 mV, FF = 71.7%) on 200 µm thick 1-15 Ω-cm n-type CZ C-Si with a designated area of 4 cm2.
ContributorsMoeini Rizi, Mansoure (Author) / Goodnick, Stephen (Thesis advisor) / Honsberg, Christina (Committee member) / Goryll, Michael (Committee member) / Smith, David (Committee member) / Bowden, Stuart (Committee member) / Arizona State University (Publisher)
Created2022
Description
According to Our World in Data, the industry sector contributes approximately 5.2 percent of the world's greenhouse gas emissions in 2016 [1]. Of that percentage, the cement industry contributes approximately 3 percent, thus accounting for more than 57 percent of all greenhouse gas emissions within the industry sector. Industrial-scale heating that is powered by renewable energy sources has the potential to combat this issue. This paper aims to analyze and model the Reverse Brayton Cycle to be used as a heat pump in a novel cement production system. The Simple Reverse Brayton Cycle and its potential concerning performance indicators such as coefficient of performance and scalability are determined. A Regenerative Brayton cycle is modeled in MATLAB® programming in order to be optimized and compared to conventional processes that require higher temperatures. Traditional manufacturing methods are discussed. Furthermore, possible methods of improvement are explored to view its effect on performance and temperatures between stages within the cycle.
ContributorsRivera, Daniel E (Author) / Phelan, Patrick (Thesis advisor) / Milcarek, Ryan (Committee member) / Calhoun, Ronald (Committee member) / Arizona State University (Publisher)
Created2024
Optimization of the implementation of renewable resources in a municipal electric utility in Arizona
Description
A municipal electric utility in Mesa, Arizona with a peak load of approximately 85 megawatts (MW) was analyzed to determine how the implementation of renewable resources (both wind and solar) would affect the overall cost of energy purchased by the utility. The utility currently purchases all of its energy through long term energy supply contracts and does not own any generation assets and so optimization was achieved by minimizing the overall cost of energy while adhering to specific constraints on how much energy the utility could purchase from the short term energy market. Scenarios were analyzed for a five percent and a ten percent penetration of renewable energy in the years 2015 and 2025. Demand Side Management measures (through thermal storage in the City's district cooling system, electric vehicles, and customers' air conditioning improvements) were evaluated to determine if they would mitigate some of the cost increases that resulted from the addition of renewable resources.
In the 2015 simulation, wind energy was less expensive than solar to integrate to the supply mix. When five percent of the utility's energy requirements in 2015 are met by wind, this caused a 3.59% increase in the overall cost of energy. When that five percent is met by solar in 2015, it is estimated to cause a 3.62% increase in the overall cost of energy. A mix of wind and solar in 2015 caused a lower increase in the overall cost of energy of 3.57%. At the ten percent implementation level in 2015, solar, wind, and a mix of solar and wind caused increases of 7.28%, 7.51% and 7.27% respectively in the overall cost of energy.
In 2025, at the five percent implementation level, wind and solar caused increases in the overall cost of energy of 3.07% and 2.22% respectively. In 2025, at the ten percent implementation level, wind and solar caused increases in the overall cost of energy of 6.23% and 4.67% respectively.
Demand Side Management reduced the overall cost of energy by approximately 0.6%, mitigating some of the cost increase from adding renewable resources.
In the 2015 simulation, wind energy was less expensive than solar to integrate to the supply mix. When five percent of the utility's energy requirements in 2015 are met by wind, this caused a 3.59% increase in the overall cost of energy. When that five percent is met by solar in 2015, it is estimated to cause a 3.62% increase in the overall cost of energy. A mix of wind and solar in 2015 caused a lower increase in the overall cost of energy of 3.57%. At the ten percent implementation level in 2015, solar, wind, and a mix of solar and wind caused increases of 7.28%, 7.51% and 7.27% respectively in the overall cost of energy.
In 2025, at the five percent implementation level, wind and solar caused increases in the overall cost of energy of 3.07% and 2.22% respectively. In 2025, at the ten percent implementation level, wind and solar caused increases in the overall cost of energy of 6.23% and 4.67% respectively.
Demand Side Management reduced the overall cost of energy by approximately 0.6%, mitigating some of the cost increase from adding renewable resources.
ContributorsCadorin, Anthony (Author) / Phelan, Patrick (Thesis advisor) / Calhoun, Ronald (Committee member) / Trimble, Steve (Committee member) / Arizona State University (Publisher)
Created2014
Description
Desorption processes are an important part of all processes which involve utilization of solid adsorbents such as adsorption cooling, sorption thermal energy storage, and drying and dehumidification processes and are inherently energy-intensive. Here, how those energy requirements can be reduced through the application of ultrasound for three widely used adsorbents namely zeolite 13X, activated alumina and silica gel is investigated. To determine and justify the effectiveness of incorporating ultrasound from an energy-savings point of view, an approach of constant overall input power of 20 and 25 W was adopted. To measure the extent of the effectiveness of using ultrasound, the ultrasonic-power-to-total power ratios of 0.2, 0.25, 0.4 and 0.5 were investigated and the results compared with those of no-ultrasound (heat only) at the same total power. Duplicate experiments were performed at three nominal frequencies of 28, 40 and 80 kHz to observe the influence of frequency on regeneration dynamics. Regarding moisture removal, application of ultrasound results in higher desorption rate compared to a non-ultrasound process. A nonlinear inverse proportionality was observed between the effectiveness of ultrasound and the frequency at which it is applied. Based on the variation of desorption dynamics with ultrasonic power and frequency, three mechanisms of reduced adsorbate adsorption potential, increased adsorbate surface energy and enhanced mass diffusion are proposed. Two analytical models that describe the desorption process were developed based on the experimental data from which novel efficiency metrics were proposed, which can be employed to justify incorporating ultrasound in regeneration and drying processes.
ContributorsDaghooghi Mobarakeh, Hooman (Author) / Phelan, Patrick (Thesis advisor) / Wang, Liping (Committee member) / Wang, Robert (Committee member) / Calhoun, Ronald (Committee member) / Deng, Shuguang (Committee member) / Arizona State University (Publisher)
Created2021