ETDs

This collection includes most of the ASU Theses and Dissertations from 2011 to present. ASU Theses and Dissertations are available in downloadable PDF format; however, a small percentage of items are under embargo. Information about the dissertations/theses includes degree information, committee members, an abstract, supporting data or media.

In addition to the electronic theses found in the ASU Digital Repository, ASU Theses and Dissertations can be found in the ASU Library Catalog.

Dissertations and Theses granted by Arizona State University are archived and made available through a joint effort of the ASU Graduate College and the ASU Libraries. For more information or questions about this collection contact or visit the Digital Repository ETD Library Guide or contact the ASU Graduate College at gradformat@asu.edu.

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Synthesis, characterization and mechanical behavior of a novel sustainable structural binder utilizing the chemistry of iron carbonation

Description
Increased priority on the minimization of environmental impacts of conventional construction materials in recent years has motivated increased use of waste materials or bi-products such as fly ash, blast furnace slag with a view to reduce or eliminate the manufacturing/consumption of ordinary portland cement (OPC) which accounts for approximately 5-7%…

Increased priority on the minimization of environmental impacts of conventional construction materials in recent years has motivated increased use of waste materials or bi-products such as fly ash, blast furnace slag with a view to reduce or eliminate the manufacturing/consumption of ordinary portland cement (OPC) which accounts for approximately 5-7% of global carbon dioxide emission. The current study explores, for the first time, the possibility of carbonating waste metallic iron powder to develop carbon-negative sustainable binder systems for concrete. The fundamental premise of this work is that metallic iron will react with aqueous CO2 under controlled conditions to form complex iron carbonates which have binding capabilities. The compressive and flexural strengths of the chosen iron-based binder systems increase with carbonation duration and the specimens carbonated for 4 days exhibit mechanical properties that are comparable to those of companion ordinary portland cement systems. The optimal mixture proportion and carbonation regime for this non-conventional sustainable binder is established based on the study of carbonation efficiency of a series of mixtures using thermogravimetric analysis. The pore- and micro-structural features of this novel binding material are also evaluated. The fracture response of this novel binder is evaluated using strain energy release rate and measurement of fracture process zone using digital image correlation (DIC). The iron-based binder system exhibits significantly higher strain energy release rates when compared to those of the OPC systems in both the unreinforced and glass fiber reinforced states. The iron-based binder also exhibits higher amount of area of fracture process zone due to its ability to undergo inelastic deformation facilitated by unreacted metallic iron particle inclusions in the microstructure that helps crack bridging /deflection. The intrinsic nano-mechanical properties of carbonate reaction product are explored using statistical nanoindentation technique coupled with a stochastic deconvolution algorithm. Effect of exposure to high temperature (up to 800°C) is also studied. Iron-based binder shows significantly higher residual flexural strength after exposure to high temperatures. Results of this comprehensive study establish the viability of this binder type for concrete as an environment-friendly and economical alternative to OPC.
ContributorsDas, Sumanta (Author) / Neithalath, Narayanan (Thesis advisor) / Rajan, S.D. (Committee member) / Mobasher, Barzin (Committee member) / Marzke, Robert (Committee member) / Chawla, Nikhilesh (Committee member) / Stone, David (Committee member) / Arizona State University (Publisher)
Created2015
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Analytical load-deflection equations for beam and 2-D panel with a bilinear moment-curvature model

Description
A simplified bilinear moment-curvature model are derived based on the moment-curvature response generated from a parameterized stress-strain response of strain softening and or strain-hardening material by Dr. Barzin Mobasher and Dr. Chote Soranakom. Closed form solutions are developed for deflection calculations of determinate beams subjected to usual loading patterns at…

A simplified bilinear moment-curvature model are derived based on the moment-curvature response generated from a parameterized stress-strain response of strain softening and or strain-hardening material by Dr. Barzin Mobasher and Dr. Chote Soranakom. Closed form solutions are developed for deflection calculations of determinate beams subjected to usual loading patterns at any load stage. The solutions are based on a bilinear moment curvature response characterized by the flexural crack initiation and ultimate capacity based on a deflection hardening behavior. Closed form equations for deflection calculation are presented for simply supported beams under three point bending, four point bending, uniform load, concentrated moment at the middle, pure bending, and for cantilever beam under a point load at the end, a point load with an arbitrary distance from the fixed end, and uniform load. These expressions are derived for pre-cracked and post cracked regions. A parametric study is conducted to examine the effects of moment and curvature at the ultimate stage to moment and curvature at the first crack ratios on the deflection. The effectiveness of the simplified closed form solution is demonstrated by comparing the analytical load deflection response and the experimental results for three point and four point bending. The simplified bilinear moment-curvature model is modified by imposing the deflection softening behavior so that it can be widely implemented in the analysis of 2-D panels. The derivations of elastic solutions and yield line approach of 2-D panels are presented. Effectiveness of the proposed moment-curvature model with various types of panels is verified by comparing the simulated data with the experimental data of panel test.
ContributorsWang, Xinmeng (Author) / Mobasher, Barzin (Thesis advisor) / Rajan, Subramaniam D. (Committee member) / Neithalath, Narayanan (Committee member) / Arizona State University (Publisher)
Created2015