Matching Items (53)
Description
Thermodynamic development and balance of plant study is completed for a 30 MW solar thermochemical water splitting process that generates hydrogen gas and electric power. The generalized thermodynamic model includes 23 components and 45 states. Quasi-steady state simulations are completed for design point system sizing, annual performance analysis and sensitivity analysis. Detailed consideration is given to water splitting reaction kinetics with governing equations generalized for use with any redox-active metal oxide material. Specific results for Ceria illustrate particle reduction in two solar receivers for target oxygen partial pressure of 10 Pa and particle temperature of 1773 K at a design point DNI of 900 W/m2. Sizes of the recuperator, steam generator and hydrogen separator are calculated at the design point DNI to achieve 100,000 kg of hydrogen production per day from the plant. The total system efficiency of 39.52% is comprised of 50.7% hydrogen fraction and 19.62% electrical fraction. Total plant capital costs and operating costs are estimated to equate a hydrogen production cost of $4.40 per kg for a 25-year plant life. Sensitivity analysis explores the effect of environmental parameters and design parameters on system performance and cost. Improving recuperator effectiveness from 0.7 to 0.8 is a high-value design modification resulting in a 12.1% decrease in hydrogen cost for a modest 2.0% increase in plant $2.85M. At the same time, system efficiency is relatively inelastic to recuperator effectiveness because 81% of excess heat is recovered from the system for electricity production 39 MWh/day and revenue is $0.04 per kWh. Increasing water inlet pressure up to 20 bar reduces the size and cost of super heaters but further pressure rises increasing pump at a rate that outweighs super heater cost savings.
ContributorsBudama, Vishnu Kumar (Author) / Johnson, Nathan (Thesis advisor) / Stechel, Ellen (Committee member) / Rykaczewski, Konrad (Committee member) / Phelan, Patrick (Committee member) / Wang, Robert (Committee member) / Arizona State University (Publisher)
Created2018
Description
Additive manufacturing (AM) describes an array of methods used to create a 3D object layer by layer. The increasing popularity of AM in the past decade has been due to its demonstrated potential to increase design flexibility, produce rapid prototypes, and decrease material waste. Temporary supports are an inconvenient necessity in many metal AM parts. These sacrificial structures are used to fabricate large overhangs, anchor the part to the build substrate, and provide a heat pathway to avoid warping. Polymers AM has addressed this issue by using support material that is soluble in an electrolyte that the base material is not. In contrast, metals AM has traditionally approached support removal using time consuming, costly methods such as electrical discharge machining or a dremel.
This work introduces dissolvable supports to single- and multi-material metals AM. The multi-material approach uses material choice to design a functionally graded material where corrosion is the functionality being varied. The single-material approach is the primary focus of this thesis, leveraging already common post-print heat treatments to locally alter the microstructure near the surface. By including a sensitizing agent in the ageing heat treatment, carbon is diffused into the part decreasing the corrosion resistance to a depth equal to at least half the support thickness. In a properly chosen electrolyte, this layer is easily chemically, or electrochemically removed. Stainless steel 316 (SS316) and Inconel 718 are both investigated to study this process using two popular alloys. The microstructure evolution and corrosion properties are investigated for both. For SS316, the effect of applied electrochemical potential is investigated to describe the varying corrosion phenomena induced, and the effect of potential choice on resultant roughness. In summary, a new approach to remove supports from metal AM parts is introduced to decrease costs and further the field of metals AM by expanding the design space.
This work introduces dissolvable supports to single- and multi-material metals AM. The multi-material approach uses material choice to design a functionally graded material where corrosion is the functionality being varied. The single-material approach is the primary focus of this thesis, leveraging already common post-print heat treatments to locally alter the microstructure near the surface. By including a sensitizing agent in the ageing heat treatment, carbon is diffused into the part decreasing the corrosion resistance to a depth equal to at least half the support thickness. In a properly chosen electrolyte, this layer is easily chemically, or electrochemically removed. Stainless steel 316 (SS316) and Inconel 718 are both investigated to study this process using two popular alloys. The microstructure evolution and corrosion properties are investigated for both. For SS316, the effect of applied electrochemical potential is investigated to describe the varying corrosion phenomena induced, and the effect of potential choice on resultant roughness. In summary, a new approach to remove supports from metal AM parts is introduced to decrease costs and further the field of metals AM by expanding the design space.
ContributorsLefky, Christopher (Author) / Hildreth, Owen (Thesis advisor) / Chawla, Nikhilesh (Committee member) / Azeredo, Bruno (Committee member) / Rykaczewski, Konrad (Committee member) / Nian, Qiong (Committee member) / Arizona State University (Publisher)
Created2018
Description
The objective of this dissertation is to study the use of metamaterials as narrow-band and broadband selective absorbers for opto-thermal and solar thermal energy conversion. Narrow-band selective absorbers have applications such as plasmonic sensing and cancer treatment, while one of the main applications of selective metamaterials with broadband absorption is efficiently converting solar energy into heat as solar absorbers.
This dissertation first discusses the use of gold nanowires as narrow-band selective metamaterial absorbers. An investigation into plasmonic localized heating indicated that film-coupled gold nanoparticles exhibit tunable selective absorption based on the size of the nanoparticles. By using anodized aluminum oxide templates, aluminum nanodisc narrow-band absorbers were fabricated. A metrology instrument to measure the reflectance and transmittance of micro-scale samples was also developed and used to measure the reflectance of the aluminum nanodisc absorbers (220 µm diameter area). Tuning of the resonance wavelengths of these absorbers can be achieved through changing their geometry. Broadband absorption can be achieved by using a combination of geometries for these metamaterials which would facilitate their use as solar absorbers.
Recently, solar energy harvesting has become a topic of considerable research investigation due to it being an environmentally conscious alternative to fossil fuels. The next section discusses the steady-state temperature measurement of a lab-scale multilayer solar absorber, named metafilm. A lab-scale experimental setup is developed to characterize the solar thermal performance of selective solar absorbers. Under a concentration factor of 20.3 suns, a steady-state temperature of ~500 degrees Celsius was achieved for the metafilm compared to 375 degrees Celsius for a commercial black absorber under the same conditions. Thermal durability testing showed that the metafilm could withstand up to 700 degrees Celsius in vacuum conditions and up to 400 degrees Celsius in atmospheric conditions with little degradation of its optical and radiative properties. Moreover, cost analysis of the metafilm found it to cost significantly less ($2.22 per square meter) than commercial solar coatings ($5.41-100 per square meter).
Finally, this dissertation concludes with recommendations for further studies like using these selective metamaterials and metafilms as absorbers and emitters and using the aluminum nanodiscs on glass as selective filters for photovoltaic cells to enhance solar thermophotovoltaic energy conversion.
This dissertation first discusses the use of gold nanowires as narrow-band selective metamaterial absorbers. An investigation into plasmonic localized heating indicated that film-coupled gold nanoparticles exhibit tunable selective absorption based on the size of the nanoparticles. By using anodized aluminum oxide templates, aluminum nanodisc narrow-band absorbers were fabricated. A metrology instrument to measure the reflectance and transmittance of micro-scale samples was also developed and used to measure the reflectance of the aluminum nanodisc absorbers (220 µm diameter area). Tuning of the resonance wavelengths of these absorbers can be achieved through changing their geometry. Broadband absorption can be achieved by using a combination of geometries for these metamaterials which would facilitate their use as solar absorbers.
Recently, solar energy harvesting has become a topic of considerable research investigation due to it being an environmentally conscious alternative to fossil fuels. The next section discusses the steady-state temperature measurement of a lab-scale multilayer solar absorber, named metafilm. A lab-scale experimental setup is developed to characterize the solar thermal performance of selective solar absorbers. Under a concentration factor of 20.3 suns, a steady-state temperature of ~500 degrees Celsius was achieved for the metafilm compared to 375 degrees Celsius for a commercial black absorber under the same conditions. Thermal durability testing showed that the metafilm could withstand up to 700 degrees Celsius in vacuum conditions and up to 400 degrees Celsius in atmospheric conditions with little degradation of its optical and radiative properties. Moreover, cost analysis of the metafilm found it to cost significantly less ($2.22 per square meter) than commercial solar coatings ($5.41-100 per square meter).
Finally, this dissertation concludes with recommendations for further studies like using these selective metamaterials and metafilms as absorbers and emitters and using the aluminum nanodiscs on glass as selective filters for photovoltaic cells to enhance solar thermophotovoltaic energy conversion.
ContributorsAlshehri, Hassan (Author) / Wang, Liping (Thesis advisor) / Phelan, Patrick (Committee member) / Rykaczewski, Konrad (Committee member) / Wang, Robert (Committee member) / Yu, Hongbin (Committee member) / Arizona State University (Publisher)
Created2018
Description
Reactive inkjet printing (RIJP) is a direct-write deposition technique that synthesizes and patterns functional materials simultaneously. It is a route to cheap fabrication of highly conductive features on a versatile range of substrates. Silver reactive inks have become a staple of conductive inkjet printing for application in printed and flexible electronics, photovoltaic metallization, and more. However, the high cost of silver makes these less effective for disposable and low-cost applications.
This work aimed to develop a particle-free formulation for a nickel reactive ink capable of metallizing highly pure nickel at temperatures under 100 °C to facilitate printing on substrates like paper or plastic. Nickel offers a significantly cheaper alternative to silver at slightly reduced bulk conductivity.
To meet these aims, three archetypes of inks were formulated. First were a set of glycerol-based inks temperature ink containing nickel acetate, hydrazine, and ammonia in a mixture of water and glycerol. This ink reduced between 115 – 200 °C to produce slightly oxidized deposits of nickel with carbon content around 10 wt %.
The high temperature was addressed in a second series, which replaced glycerol with lower boiling glycols and added sodium hydroxide as a strong base to enhance thermodynamics and kinetics of reduction. These inks reduced between 60 and 100 °C but sodium salts contaminated the final deposits.
In a third set of inks, sodium hydroxide was replaced with tetramethylammonium hydroxide (TMAH), a strong organic base, to address contamination. These inks also reduced between 60 and 100 °C. Pipetting or printing onto gold coated substrates produce metallic flakes coated in a clear, thick residue. EDS measured carbon and oxygen content up to 70 wt % of deposits. The residue was hypothesized to be a non-volatile byproduct of TMAH and acetate.
Recommendations are provided to address the residue. Ultimately the formulated reactive inks did not meet design targets. However, this thesis sets the framework to design an optimal nickel reactive ink in future work.
This work aimed to develop a particle-free formulation for a nickel reactive ink capable of metallizing highly pure nickel at temperatures under 100 °C to facilitate printing on substrates like paper or plastic. Nickel offers a significantly cheaper alternative to silver at slightly reduced bulk conductivity.
To meet these aims, three archetypes of inks were formulated. First were a set of glycerol-based inks temperature ink containing nickel acetate, hydrazine, and ammonia in a mixture of water and glycerol. This ink reduced between 115 – 200 °C to produce slightly oxidized deposits of nickel with carbon content around 10 wt %.
The high temperature was addressed in a second series, which replaced glycerol with lower boiling glycols and added sodium hydroxide as a strong base to enhance thermodynamics and kinetics of reduction. These inks reduced between 60 and 100 °C but sodium salts contaminated the final deposits.
In a third set of inks, sodium hydroxide was replaced with tetramethylammonium hydroxide (TMAH), a strong organic base, to address contamination. These inks also reduced between 60 and 100 °C. Pipetting or printing onto gold coated substrates produce metallic flakes coated in a clear, thick residue. EDS measured carbon and oxygen content up to 70 wt % of deposits. The residue was hypothesized to be a non-volatile byproduct of TMAH and acetate.
Recommendations are provided to address the residue. Ultimately the formulated reactive inks did not meet design targets. However, this thesis sets the framework to design an optimal nickel reactive ink in future work.
ContributorsDebruin, Dylan Jerome (Author) / Torres, Cesar (Thesis advisor) / Rykaczewski, Konrad (Thesis advisor) / Hildreth, Owen (Committee member) / Arizona State University (Publisher)
Created2019
Description
Soft polymer composites with improved thermal conductivity are needed for the thermal management of electronics. Interfacial thermal boundary resistance, however, prevents the efficient use of many high thermal conductivity fill materials. Magnetic alignment of ferrous fill material enforces percolation of the high thermal conductivity fill, thereby shifting the governing boundary resistance to the particle- particle interfaces and increasing the directional thermal conductivity of the polymer composite. Magnetic alignment maximizes the thermal conductivity while minimizing composite stiffening at a fill fraction of half the maximum packing factor. The directional thermal conductivity of the composite is improved by more than 2-fold. Particle-particle contact engineering is then introduced to decrease the particle- particle boundary resistance and further improve the thermal conductivity of the composite.
The interface between rigid fill particles is a point contact with very little interfacial area connecting them. Silver and gallium-based liquid metal (LM) coatings provide soft interfaces that, under pressure, increase the interfacial area between particles and decrease the particle-particle boundary resistance. These engineered contacts are investigated both in and out of the polymer matrix and with and without magnetic alignment of the fill. Magnetically aligned in the polymer matrix, 350nm- thick silver coatings on nickel particles produce a 1.8-fold increase in composite thermal conductivity over the aligned bare-nickel composites. The LM coatings provide similar enhancements, but require higher volumes of LM to do so. This is due to the rapid formation of gallium oxide, which introduces additional thermal boundaries and decreases the benefit of the LM coatings.
The oxide shell of LM droplets (LMDs) can be ruptured using pressure. The pressure needed to rupture LMDs matches closely to thin-walled pressure vessel theory. Furthermore, the addition of tungsten particles stabilizes the mixture for use at higher pressures. Finally, thiols and hydrochloric acid weaken the oxide shell and boost the thermal performance of the beds of LMDs by 50% at pressures much lower than 1 megapascal (MPa) to make them more suitable for use in TIMs.
The interface between rigid fill particles is a point contact with very little interfacial area connecting them. Silver and gallium-based liquid metal (LM) coatings provide soft interfaces that, under pressure, increase the interfacial area between particles and decrease the particle-particle boundary resistance. These engineered contacts are investigated both in and out of the polymer matrix and with and without magnetic alignment of the fill. Magnetically aligned in the polymer matrix, 350nm- thick silver coatings on nickel particles produce a 1.8-fold increase in composite thermal conductivity over the aligned bare-nickel composites. The LM coatings provide similar enhancements, but require higher volumes of LM to do so. This is due to the rapid formation of gallium oxide, which introduces additional thermal boundaries and decreases the benefit of the LM coatings.
The oxide shell of LM droplets (LMDs) can be ruptured using pressure. The pressure needed to rupture LMDs matches closely to thin-walled pressure vessel theory. Furthermore, the addition of tungsten particles stabilizes the mixture for use at higher pressures. Finally, thiols and hydrochloric acid weaken the oxide shell and boost the thermal performance of the beds of LMDs by 50% at pressures much lower than 1 megapascal (MPa) to make them more suitable for use in TIMs.
ContributorsRalphs, Matthew (Author) / Rykaczewski, Konrad (Thesis advisor) / Wang, Robert Y (Thesis advisor) / Phelan, Patrick (Committee member) / Wang, Liping (Committee member) / Devasenathipathy, Shankar (Committee member) / Arizona State University (Publisher)
Created2019
Description
The wettability of powders is an important characteristic for both industry and academia and is often described by the powder’s contact angle with a certain liquid. While there exist many ways to measure contact angle, it is a portion of the powder technology field that is not fully understood and requires more investigation and research. This study investigates two methods for measuring contact angle, the sessile drop method and the Washburn method, and looks to compare results to determine which method offers the most reliable data in terms of accuracy and repeatability. Two powders - microcrystalline cellulose and aluminum oxide - and three liquids - water, 50 cSt silicone oil, and 350 cSt silicone oil - were used to study the differences between the two measurement techniques as well as the effects of varying fluid viscosity on the measurements. It was found that the sessile drop method proved to be an ineffective method for measuring contact angle when liquid penetration into the powder occurred, as the contact angle changed while the drop penetrated. Initial results showed the contact angle for silicone oil on the powders to be greater than 90°, indicating nonwetting of the surface which was inconsistent with observations. The results from the Washburn method align better with other values in similar studies, but more study is needed to confirm the results gathered in this research.
ContributorsSmith, Bryan Alexander (Author) / Emady, Heather (Thesis director) / Rykaczewski, Konrad (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
Description
3D printing has recently become a popular manufacturing process and the goal of the project was to take that process to the kitchen. This was done by utilizing existing knowledge of the culinary process of "spherification", by which a liquid is encapsulated in an edible shell, and combining it with the hydrogel research advancements in tissue engineering to make robust fibers. A co-flow nozzle was constructed and the two fluids needed for spherification were flowed in various configurations to create different fibers. By outlining a stability regime and measuring the outer diameters for both regular and reverse spherification, the optimal method of production and fibers that would be suitable for 3D printing were discovered. The results of the experiments can be used to begin 3D printing edible 2D patterns and eventually 3D structures.
ContributorsSchott, Christopher David (Author) / Rykaczewski, Konrad (Thesis director) / Herrmann, Marcus (Committee member) / Barrett, The Honors College (Contributor) / Mechanical and Aerospace Engineering Program (Contributor)
Created2015-05
Description
The energy crisis in the past decades has greatly boosted the search for alternatives to traditional fossil foils, and solar energy stands out as an important candidate due to its cleanness and abundance. However, the relatively low conversion efficiency and energy density strongly hinder the utilization of solar energy in wider applications. This thesis focuses on employing metamaterials and metafilms to enhance the conversion efficiency of solar thermal, solar thermophotovoltaic (STPV) and photovoltaic systems.
A selective metamaterial solar absorber is designed in this thesis to maximize the absorbed solar energy and minimize heat dissipation through thermal radiation. The theoretically designed metamaterial solar absorber exhibits absorptance higher than 95% in the solar spectrum but shows emittance less than 4% in the IR regime. This metamaterial solar absorber is further experimentally fabricated and optically characterized. Moreover, a metafilm selective absorber with stability up to 600oC is introduced, which exhibits solar absorptance higher than 90% and IR emittance less than 10%.
Solar thermophotovoltaic energy conversion enhanced by metamaterial absorbers and emitters is theoretically investigated in this thesis. The STPV system employing selective metamaterial absorber and emitter is investigated in this work, showing its conversion efficiency between 8% and 10% with concentration factor varying between 20 and 200. This conversion efficiency is remarkably enhanced compared with the conversion efficiency for STPV system employing black surfaces (<2.5%).
Moreover, plasmonic light trapping in ultra-thin solar cells employing concave grating nanostructures is discussed in this thesis. The plasmonic light trapping inside an ultrathin GaAs layer in the film-coupled metamaterial structure is numerically demonstrated. By exciting plasmonic resonances inside this structure, the short-circuit current density for the film-coupled metamaterial solar cell is three times the short-circuit current for a free-standing GaAs layer.
The dissertation is concluded by discussing about the future work on selective solar thermal absorbers, STPV/TPV systems and light trapping structures. Possibilities to design and fabricate solar thermal absorber with better thermal stability will be discussed, the experimental work of TPV system will be conducted, and the light trapping in organic and perovskite solar cells will be looked into.
A selective metamaterial solar absorber is designed in this thesis to maximize the absorbed solar energy and minimize heat dissipation through thermal radiation. The theoretically designed metamaterial solar absorber exhibits absorptance higher than 95% in the solar spectrum but shows emittance less than 4% in the IR regime. This metamaterial solar absorber is further experimentally fabricated and optically characterized. Moreover, a metafilm selective absorber with stability up to 600oC is introduced, which exhibits solar absorptance higher than 90% and IR emittance less than 10%.
Solar thermophotovoltaic energy conversion enhanced by metamaterial absorbers and emitters is theoretically investigated in this thesis. The STPV system employing selective metamaterial absorber and emitter is investigated in this work, showing its conversion efficiency between 8% and 10% with concentration factor varying between 20 and 200. This conversion efficiency is remarkably enhanced compared with the conversion efficiency for STPV system employing black surfaces (<2.5%).
Moreover, plasmonic light trapping in ultra-thin solar cells employing concave grating nanostructures is discussed in this thesis. The plasmonic light trapping inside an ultrathin GaAs layer in the film-coupled metamaterial structure is numerically demonstrated. By exciting plasmonic resonances inside this structure, the short-circuit current density for the film-coupled metamaterial solar cell is three times the short-circuit current for a free-standing GaAs layer.
The dissertation is concluded by discussing about the future work on selective solar thermal absorbers, STPV/TPV systems and light trapping structures. Possibilities to design and fabricate solar thermal absorber with better thermal stability will be discussed, the experimental work of TPV system will be conducted, and the light trapping in organic and perovskite solar cells will be looked into.
ContributorsWang, Hao (Author) / Wang, Liping (Thesis advisor) / Phelan, Patrick (Committee member) / Wang, Robert (Committee member) / Dai, Lenore (Committee member) / Rykaczewski, Konrad (Committee member) / Arizona State University (Publisher)
Created2016
Description
“Smart” materials are used for a broad range of application including electronics, bio-medical devices, and smart clothing. This work focuses on development of smart self-sealing and breathable protective gear for soldiers against Chemical Weapon Agents (CWA). Specifically, the response of chemo-mechanical swelling polymer modified meshes to contact with stimuli droplets was studied. Theoretical discussion of the mechanism of smart materials is followed by development and experimental analysis of different modified mesh designs. A multi-physics model is proposed based on experimental data and the prototype of the fabric is tested in aerosol impingement conditions to confirm the barrier formed by rapid-self-sealing feature of the design.
ContributorsUppal, Aastha (Author) / Rykaczewski, Konrad (Thesis advisor) / Hildreth, Owen (Committee member) / Marvi, Hamidreza (Committee member) / Arizona State University (Publisher)
Created2016
Description
It is well known that the geckos can cling to almost any surface using highly dense micro
ano fibrils found on the feet that rely on Van Der Waals forces to adhere. A few experimental and theoretical approaches have been taken to understand the adhesion mechanism of gecko feet. This work explains the building procedure of custom experimental setup to test the adhesion force over a temperature range and extends its application in space environment, potentially unsafe working condition.
This study demonstrates that these adhesive capable of switching adhesive properties not only at room environment but also over a temperature range of -160 degC to 120 degC in vacuum conditions. These conditions are similar to the condition experienced by a satellite in a space orbiting around the earth. Also, this study demonstrated various detachment and specimen patch preparation methods. The custom-made experimental setup for adhesion test can measure adhesion force in temperature and pressure controlled environment over specimen size of 1 sq. inch. A cryogenic cooling system with liquid nitrogen is used to achieve -160 degC and an electric resistive heating system are used to achieve 120 degC in controlled volume. Thermal electrodes, infrared thermopile detectors are used to record temperature at sample and pressure indicator to record vacuum condition in controlled volume. Reversibility of the switching behaviour of the specimen in controlled environment confirms its application in space and very high or very low-temperature conditions.
The experimental setup was developed using SolidWorks as a design tool, Ansys as simulation tool and the data acquisition utilizes LabVIEW available in the market today.
ano fibrils found on the feet that rely on Van Der Waals forces to adhere. A few experimental and theoretical approaches have been taken to understand the adhesion mechanism of gecko feet. This work explains the building procedure of custom experimental setup to test the adhesion force over a temperature range and extends its application in space environment, potentially unsafe working condition.
This study demonstrates that these adhesive capable of switching adhesive properties not only at room environment but also over a temperature range of -160 degC to 120 degC in vacuum conditions. These conditions are similar to the condition experienced by a satellite in a space orbiting around the earth. Also, this study demonstrated various detachment and specimen patch preparation methods. The custom-made experimental setup for adhesion test can measure adhesion force in temperature and pressure controlled environment over specimen size of 1 sq. inch. A cryogenic cooling system with liquid nitrogen is used to achieve -160 degC and an electric resistive heating system are used to achieve 120 degC in controlled volume. Thermal electrodes, infrared thermopile detectors are used to record temperature at sample and pressure indicator to record vacuum condition in controlled volume. Reversibility of the switching behaviour of the specimen in controlled environment confirms its application in space and very high or very low-temperature conditions.
The experimental setup was developed using SolidWorks as a design tool, Ansys as simulation tool and the data acquisition utilizes LabVIEW available in the market today.
ContributorsMate, Sunil (Author) / Marvi, Hamidreza (Thesis advisor) / Rykaczewski, Konrad (Committee member) / Lee, Hyunglae (Committee member) / Arizona State University (Publisher)
Created2016