Highly shocked L5/6 chondrites Acfer 040, Mbale, NWA 091 and Chico and LL6 chondrite NWA 757 were used to investigate a variety of shock pressures and post-shock annealing histories. NWA 757 is the only highly shocked LL chondrite that includes abundant HP minerals. The assemblage of ringwoodite and majoritic garnet indicates an equilibration shock pressure of ~20 GPa, similar to many strongly shocked L chondrites. Acfer 040 is one of the only two chondrite samples with bridgmanite (silicate perovskite), suggesting equilibration pressure >25 GPa. The bridgmanite, which is unstable at low-pressure, was mostly vitrified during post-shock cooling. Mbale demonstrates an example of elevated post-shock temperature resulting in back-transformation of ringwoodite to olivine. In contrast, majoritic garnet in Mbale survives as unambiguous evidence of strong shock. In these two samples, HP minerals are exclusively associated with shock melt, indicating that elevated shock temperatures are required for rapid mineral transformations during the transient shock pulse. However, elevated post-shock temperatures can destroy HP minerals: in temperature sequence from bridgmanite to ringwoodite then garnet. NWA 091 and Chico are impact melt breccias with pervasive melting, blackening of silicates, recrystallization of host rock but no HP minerals. These features indicate near whole-rock-melting conditions. However, the elevated post-shock temperatures of these samples has annealed out HP signatures. The observed shock features result from a complex P-T-t path and may not directly reflect the peak shock pressure. Although HP minerals provide robust evidence of high pressure, their occurrence also requires high shock temperatures and rapid cooling during the shock pulse. The most highly shocked samples lack HP signatures but have abundant high-temperature features formed after pressure release.
The Earth’s lowermost mantle large low velocity provinces are accompanied by small-scale ultralow velocity zones in localized regions on the core-mantle boundary. Large low velocity provinces are hypothesized to be caused by large-scale compositional heterogeneity (i.e., thermochemical piles). The origin of ultralow velocity zones, however, remains elusive. Here we perform three-dimensional geodynamical calculations to show that the current locations and shapes of ultralow velocity zones are related to their cause. We find that the hottest lowermost mantle regions are commonly located well within the interiors of thermochemical piles. In contrast, accumulations of ultradense compositionally distinct material occur as discontinuous patches along the margins of thermochemical piles and have asymmetrical cross-sectional shape. Furthermore, the lateral morphology of these patches provides insight into mantle flow directions and long-term stability. The global distribution and large variations of morphology of ultralow velocity zones validate a compositionally distinct origin for most ultralow velocity zones.