Matching Items (20)
Description
The presence of huge amounts of waste heat and the constant demand for electric energy makes this an appreciable research topic, yet at present there is no commercially viable technology to harness the inherent energy resource provided by the temperature differential between the inside and outside of buildings. In a newly developed technology, electricity is generated from the temperature gradient between building walls through a Seebeck effect. A 3D-printed triply periodic minimal surface (TPMS) structure is sandwiched in copper electrodes with copper (I) sulphate (Cu2SO4) electrolyte to mimic a thermogalvanic cell. Previous studies mainly concentrated on mechanical properties and the electric power generation ability of these structures; however, the goal of this study is to estimate the thermal resistance of the 3D-printed TPMS experimentally. This investigation elucidates their thermal resistances which in turn helps to appreciate the power output associated in the thermogalvanic structure. Schwarz P, Gyroid, IWP, and Split P geometries were considered for the experiment with electrolyte in the thermogalvanic brick. Among these TPMS structures, Split P was found more thermally resistive than the others with a thermal resistance of 0.012 m2 K W-1. The thermal resistances of Schwarz D and Gyroid structures were also assessed experimentally without electrolyte and the results are compared to numerical predictions in a previous Mater's thesis.
ContributorsDasinor, Emmanuel (Author) / Phelan, Patrick (Thesis advisor) / Milcarek, Ryan (Committee member) / Bhate, Dhruv (Committee member) / Arizona State University (Publisher)
Created2020
Description
Buildings release an abundance of waste heat that is left unused. Thermogalvaniccells (TGCs) can take advantage of waste heat to generate electricity with a low
temperature gradient. In this dissertation, I simulated the thermal transport of TGCs
containing different triply periodic minimal surface (TPMS) structures, compared it
to measured values and conducted a mesh convergence study to examine the viability
of the computational fluid dynamics (CFD) solutions. Natural convection effects are
one of the driving forces in TGCs. Using the Bousinesq approximation, I was able to
capture those effects in the CFD simulations as it accounts for the density variations
of the fluid. Upon simulating the TGC using the Schwarz P TPMS geometry, the
cathode temperature converged as I refined the mesh and approached the measured
value. As for the IWP TPMS structure, the solution converged as I refined the mesh,
despite having a deviation to the measured values. This was due to the abundance of
sharp regions along the walls of the TPMS that ANSYS had difficulty to accurately
model.
Furthermore, I simulated the TGCs using different boundary condition (BC) approximations to observe the cathode and anode temperatures as well as their overall
∆T across the cell. For the TGC containing the Schwarz P geometry, Case C (constant anode temperature BC with TPMS conduction) was the most accurate while
Case D (convection BC at anode with TPMS conduction) deviated from the measured
values, had the most accurate ∆T and was well within the uncertainty bounds of the
measured values. Larger temperature fluctuations were seen closer to the cathode
while the effects steadily decrease as the fluid approaches the anode.
Moreover, the TGC containing the IWP structures presented interesting results.
The main deviation was from the cathode temperatures because a higher temperature
readings meant that more cells in the fluid domain were prone to diverging, thereby
resulting in a higher calculated cathode temperature. Simulating the TGC with the
Schwarz P geometry produced satisfactory results while the TGC using the IWP
geometry deviated due to the software limitations. Finally, the effects of natural
convection and TPMS on TGCs were studied and it was found that the absence of
natural convection lead to a higher ∆T while the absence of TPMS resulted in a more
uniform temperature distribution throughout the domain
Contributorsalweqayyan, yousef (Author) / Phelan, Patrick (Thesis advisor) / Rykaczewski, Konrad (Committee member) / Milcarek, Ryan (Committee member) / Arizona State University (Publisher)
Created2021
Description
Thermophotovoltaic energy conversion is seen as a viable option for efficiently converting heat to electricity. There are three key components to a thermophotovoltaic (TPV) system: a heat source, a heat emitter and a photovoltaic (PV) cell. A heat source heats up the emitter which causes the emitter to release thermal radiation. The photons are absorbed by a PV cell when they are acting above the bandgap energy. The PV cell then generates electricity from this thermal radiation. In theory, efficiency of a TPV system can be well above 50%. In order for TPV to reach large-scale adaptation, an efficiency at or above 20% is needed. In this project, a high-temperature heater capable of reaching 1000K was developed. The heater involved a copper block machined to hold two cartridge heaters, as well as two thermocouples. It has an accompanying copper lid that can be screwed tight to the main block, with an emitter in between. There is an aperture to allow radiation through the casing towards the PV cell. Preliminary thermal analysis showed that the heater provides uniform temperature distribution across the emitter, which is necessary for proper radiation. A mounting system was also designed to implement the heater into the overall TPV system. Current work is being done to lower the radiation loss from the heater and mounting system, as well as implementation of all auxiliary components to begin testing. The maximum temperature of the heater, radiation heat flux received by the cell, and overall power output and efficiency of the system will be tested.
ContributorsDeffigos, Nikolas (Author) / Wang, Liping (Thesis director) / Milcarek, Ryan (Committee member) / Ni, Qing (Committee member) / Barrett, The Honors College (Contributor) / Mechanical and Aerospace Engineering Program (Contributor)
Created2021-12
Description
In this study, the viability of doped ceria for SOFC electrolyte application is investigated through calculation of the oxygen anion diffusion through undoped, Zr-doped, Pr-doped, and Gd-doped ceria. DFT calculations are performed to determine the oxygen vacancy formation and activation energy to vacancy migration barriers for each material. All dopants were found to increase the activation energy to vacancy migration and decrease the oxygen vacancy formation energy. These energy barriers are then integrated into a kinetic Monte Carlo simulation that models the oxygen vacancy diffusion over time. From the simulation results, the diffusivity of oxygen anion through each material is calculated as a function of dopant concentration and temperature. It was discovered that diffusivity increased with temperature and decreased with dopant concentration in all dopant cases. Gd-doped ceria exhibited the highest overall oxygen diffusion rates, making it the most effective choice for SOFC electrolyte application, while Zr-doped ceria would be the least effective choice with the lowest diffusion rates.
ContributorsMandal, Bennett (Author) / Muhich, Christopher (Thesis director) / Milcarek, Ryan (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2019-12
Description
As the need for environmentally friendly and renewable fuel sources rises, many are considering alternative fuel sources, such as solar power. The device explored in this report uses solar power, in theory, to heat a metal oxide, cerium oxide, to a desired temperature. At specific temperatures and pressures, a reaction between an input gas, carbon dioxide or water vapor, and the metal oxide may produce fuel in the form of hydrogen or carbon monoxide. In order to reach the temperatures required by the reaction, a filament inside a high-temperature radiant heater must be heated to the desired temperature. In addition, the system’s pressure range must be satisfied. A pressure and temperature measurement device, as well as a voltage control, must be connected to an interface with a computer in order to monitor the pressure and temperature of different parts of the system. The cerium oxide element must also be constructed and placed inside the system. The desired shape of the cerium oxide material is a tube, to allow the flow of gas through the tubes and system and to provide mechanical strength. To construct the metal oxide tubes, they need to be extruded, dried, and sintered correctly. All the manufactured elements described serve an essential purpose in the system and are discussed further in this document.
This report focuses on the manufacturing of ceria tubes, the construction of a high-temperature radiant heater filament, and the implementation of a pressure measurement device. The manufacturing of ceria tubes includes the extrusion, the drying, and the sintering of the tubes. In addition, heating element filament construction consists of spot-welding certain metals together to create a device similar to that of a light bulb filament. Different methods were considered in each of these areas, and they are described in this report. All of the explorations in this document move towards the final device, a thermochemical reactor for the production of hydrogen (H2) and carbon monoxide (CO) from water (H2O) and carbon dioxide (CO2).
The results of this report indicate that there are several important manufacturing steps to create the most desirable results, in terms of tube manufacturing and heating element design. For the correct tube construction, they must be dried in a drying rack, and they must be sintered in V-groove plates. In addition, the results of the heating element manufacturing indicate that the ideal heating element filament needs to be simple in design (easily fixed), cost-effective, require little construction time, attach to the ends of the system easily, provide mechanical flexibility, and prevent the coil from touching the walls of the tube it lies in. Each aspect of the ideal elements, whether they are tubes or heating elements, is explored in this report.
This report focuses on the manufacturing of ceria tubes, the construction of a high-temperature radiant heater filament, and the implementation of a pressure measurement device. The manufacturing of ceria tubes includes the extrusion, the drying, and the sintering of the tubes. In addition, heating element filament construction consists of spot-welding certain metals together to create a device similar to that of a light bulb filament. Different methods were considered in each of these areas, and they are described in this report. All of the explorations in this document move towards the final device, a thermochemical reactor for the production of hydrogen (H2) and carbon monoxide (CO) from water (H2O) and carbon dioxide (CO2).
The results of this report indicate that there are several important manufacturing steps to create the most desirable results, in terms of tube manufacturing and heating element design. For the correct tube construction, they must be dried in a drying rack, and they must be sintered in V-groove plates. In addition, the results of the heating element manufacturing indicate that the ideal heating element filament needs to be simple in design (easily fixed), cost-effective, require little construction time, attach to the ends of the system easily, provide mechanical flexibility, and prevent the coil from touching the walls of the tube it lies in. Each aspect of the ideal elements, whether they are tubes or heating elements, is explored in this report.
ContributorsCaron, Danielle (Author) / Milcarek, Ryan (Thesis director) / Ermanoski, Ivan (Committee member) / Stechel, Ellen (Committee member) / Mechanical and Aerospace Engineering Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
Description
The paper analyzes the growing desire to use waste-to-energy strategies on municipal solid waste (MSW) to generate power. The two waste-to-energy technologies that will be explored are incineration and gasification. The background of these two technologies will be explained because incineration, which has been the pioneering technology for the past century, has come to be rivaled by gasification with its unique purification feature. Following this section, gasification and incineration power generation are studied to conclude which technology is sounder. This study will be conducted via an analysis to find the thermal and exergetic efficiencies and emissions of each. After analyzing the two technologies, both utilizing a vapor cogeneration power system, their efficiencies were found. For the gasification process, the thermal efficiency was 26% and the exergetic efficiency was 59%. The incineration process had a thermal efficiency of 25% and an exergetic efficiency of 55%. Lastly, the emission from the power generation of each method was explored to see which system had a greater impact on the environment. It was found that the primary emissions of these technologies were carbon dioxide and water.
ContributorsJackson, Cole Alan (Author) / Deng, Shuguang (Thesis director) / Milcarek, Ryan (Committee member) / Mechanical and Aerospace Engineering Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2020-05
Description
Wastewater treatment plant (WWTP) utilization of combined heat and power (CHP) systems allows for the efficient use of on-site biogas production, as well as increased annual savings in utility costs. In this thesis, a literature review of six CHP prime mover technologies is presented. Even though there are different prime mover technologies, the main ones currently being implemented in WWTPs are micro turbines, fuel cells and reciprocating engines. These prime mover technologies offer varying efficiencies, installation costs and maintenance requirements. The prime movers are also all in different stages of development, leading some to be more currently-in-use than others in WWTPs. Currently reciprocating engines and micro turbines occupy the largest shares of the CHP in WWTP sector.
This thesis will also go in detail into equations and calculations created for a techno-economic assessment for installation and maintenance of a CHP system at a WWTP. The equations and calculations created here were then utilized with data from a typical WWTP in the Southwestern United States to create an accurate case study. In this case study, a payback of 5.7 years and a net present value of $709,000 can be achieved when the WWTP generates over 2,000,000 m3 of biogas per year and utilizes over 36,000 GJ of natural gas per year.
This thesis will also go in detail into equations and calculations created for a techno-economic assessment for installation and maintenance of a CHP system at a WWTP. The equations and calculations created here were then utilized with data from a typical WWTP in the Southwestern United States to create an accurate case study. In this case study, a payback of 5.7 years and a net present value of $709,000 can be achieved when the WWTP generates over 2,000,000 m3 of biogas per year and utilizes over 36,000 GJ of natural gas per year.
ContributorsRiley, Derall (Author) / Milcarek, Ryan (Thesis director) / Villalobos, Rene (Committee member) / Mechanical and Aerospace Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2020-12
Description
One of the most promising technologies for creating power without emissions is Solid Oxide Fuel Cells (SOFC) because it uses oxygen and hydrogen to create electricity with the only byproduct being water. To figure out the optimal design of the fuel cell, a literature review was conducted to determine the effects of adding both internal and external current collectors as well as the difference length has on the performance. To learn more about the kinetics of the reaction, hydrogen and carbon monoxide disappearance rates were measured to compare the rate at which each species disappears.
ContributorsPhillips, Kristina (Author) / Milcarek, Ryan (Thesis director) / Wang, Robert (Committee member) / Barrett, The Honors College (Contributor) / Mechanical and Aerospace Engineering Program (Contributor)
Created2022-05
Description
Energy storage technologies are essential to overcome the temporal variability in renewable energy. The primary aim of this thesis is to develop reactor solutions to better analyze the potential of thermochemical energy storage (TCES) using non-stoichiometric metal oxides, for the multi-day energy storage application. A TCES system consists of a reduction reactor and an insulated MOx storage bin. The reduction reactor heats (to ~ 1100 °C) and partially reduces the MOx, thereby adding sensible and chemical energy (i.e., charging it) under reduced pO2 environments (~10 Pa). Inert gas removes the oxygen generated during reduction. The storage bin holds the hot and partially reduced MOx (typically particles) until it is used in an energy recovery device (i.e., discharge). Irrespective of the reactor heat source (here electrical), or the particle-inert gas flows (here countercurrent), the thermal reduction temperature and inert gas (here N2) flow minimize when the process approaches reversibility, i.e., operates near equilibrium. This study specifically focuses on developing a reduction reactor based on the theoretical considerations for approaching reversibility along the reaction path. The proposed Zigzag flow reactor (ZFR) is capable of thermally reducing CAM28 particles at temperatures ~ 1000 °C under an O2 partial pressure ~ 10 Pa. The associated analytical and numerical models analyze the reaction equilibrium under a real (discrete) reaction path and the mass transfer kinetic conditions necessary to approach equilibrium. The discrete equilibrium model minimizes the exergy destroyed in a practical reactor and identifies methods of maximizing the energy storage density () and the exergetic efficiency. The mass transfer model analyzes the O2 N2 concentration boundary layers to recommend sizing considerations to maximize the reactor power density. Two functional ZFR prototypes, the -ZFR and the -ZFR, establish the proof of concept and achieved a reduction extent, Δδ = 0.071 with CAM28 at T~950 °C and pO2 = 10 Pa, 7x higher than a previous attempt in the literature. The -ZFR consistently achieved > 100 Wh/kg during >10 h. runtime and the -ZFR displayed an improved = 130 Wh/kg during >5 h. operation with CAM28. A techno-economic model of a grid-scale ZFR with an associated storage bin analyzes the cost of scaling the ZFR for grid energy storage requirements. The scaled ZFR capital costs contribute < 1% to the levelized cost of thermochemical energy storage, which ranges from 5-20 ¢/kWh depending on the storage temperature and storage duration.
ContributorsGhotkar, Rhushikesh (Author) / Milcarek, Ryan (Thesis advisor) / Ermanoski, Ivan (Committee member) / Phelan, Patrick (Committee member) / Wang, Liping (Committee member) / Wang, Robert (Committee member) / Arizona State University (Publisher)
Created2023
Description
Ethylene is one of the most widely used organic compounds worldwide with ever increasing demand. Almost all the industries currently producing ethylene globally use the method of steam cracking, which, though highly selective and cost effective, is energy intensive along with having a high carbon footprint. This study aims to analyze micro-scale partial oxidation of propane as a novel approach towards ethylene generation which is simpler, less energy consuming, operates at lower temperatures and causes minimum CO2 emission. The experimental study endeavors to maximize the ethylene production by investigating the effect of variables such as temperature, flow rate, equivalence ratio and reactor diameter. The micro-scale partial oxidation of propane is studied inside quartz tube reactors of 1 mm and 3 mm diameter at a temperature range of 800 to 900 oC, at varying flow rates of 10 to 100 sccm and equivalence ratios of 1 to 6. The study reveals ethylene yield has a strong dependence on all the above factors. However, the factors are not completely independent of each other. Adjusting certain factors and levels results in greater ethylene yields as high as 10%, but propane to ethylene conversion efficiency is approximately constant for most conditions. Low CO2 concentrations are also recorded for most of the factor and level combinations, indicating the potential to achieve lower CO2 yields compared to conventional approaches. The investigation indicates promise for application in the field of ethylene generation.
ContributorsMAHALKAR, PAWAN MUKUND (Author) / Milcarek, Ryan (Thesis advisor) / Kwon, Beomjin (Committee member) / Phelan, Patrick (Committee member) / Arizona State University (Publisher)
Created2023