Matching Items (10)
Description
Solar system orbital dynamics can offer unique challenges. Impacts of interplanetary dust particles can significantly alter the surfaces of icy satellites and minor planets. Impact heating from these particles can anneal away radiation damage to the crystalline structure of surface water ice. This effect is enhanced by gravitational focusing for giant planet satellites. In addition, impacts of interplanetary dust particles on the small satellites of the Pluto system can eject into the system significant amounts of secondary intra-satellite dust. This dust is primarily swept up by Pluto and Charon, and could explain the observed albedo features on Pluto's surface. In addition to Pluto, a large fraction of trans-neptunian objects (TNOs) are binary or multiple systems. The mutual orbits of these TNO binaries can range from very wide (periods of several years) to near-contact systems (less than a day period). No single formation mechanism can explain this distribution. However, if the systems generally formed wide, a combination of solar and body tides (commonly called Kozai Cycles-Tidal Friction, KCTF) can cause most systems to tighten sufficiently to explain the observed distributions. This KCTF process can also be used to describe the orbital evolution of a terrestrial-class exoplanet after being captured as a satellite of a habitable-zone giant exoplanet. The resulting exomoon would be both potentially habitable and potenially detectable in the full Kepler data set.
ContributorsPorter, Simon Bernard (Author) / Desch, Steven (Thesis advisor) / Zolotov, Mikhail (Committee member) / Timmes, Francis (Committee member) / Scannapieco, Evan (Committee member) / Robinson, Mark (Committee member) / Arizona State University (Publisher)
Created2013
Description
Earthquake faulting and the dynamics of subducting lithosphere are among the frontiers of geophysics. Exploring the nature, cause, and implications of geophysical phenomena requires multidisciplinary investigations focused at a range of spatial scales. Within this dissertation, I present studies of micro-scale processes using observational seismology and experimental mineral physics to provide important constraints on models for a range of large-scale geophysical phenomena within the crust and mantle.
The Great Basin (GB) in the western U.S. is part of the diffuse North American-Pacific plate boundary. The interior of the GB occasionally produces large earthquakes, yet the current distribution of regional seismic networks poorly samples it. The EarthScope USArray Transportable Array provides unprecedented station density and data quality for the central GB. I use this dataset to develop an earthquake catalog for the region that is complete to M 1.5. The catalog contains small-magnitude seismicity throughout the interior of the GB. The spatial distribution of earthquakes is consistent with recent regional geodetic studies, confirming that the interior of the GB is actively deforming everywhere and all the time. Additionally, improved event detection thresholds reveal that swarms of temporally-clustered repeating earthquakes occur throughout the GB. The swarms are not associated with active volcanism or other swarm triggering mechanisms, and therefore, may represent a common fault behavior.
Enstatite (Mg,Fe)SiO3 is the second most abundant mineral within subducting lithosphere. Previous studies suggest that metastable enstatite within subducting slabs may persist to the base of the mantle transition zone (MTZ) before transforming to high-pressure polymorphs. The metastable persistence of enstatite has been proposed as a potential cause for both deep-focus earthquakes and the stagnation of slabs at the base of the MTZ. I show that natural Al- and Fe-bearing enstatite reacts more readily than previous studies and by multiple transformation mechanisms at conditions as low as 1200°C and 18 GPa. Metastable enstatite is thus unlikely to survive to the base of the MTZ. Additionally, coherent growth of akimotoite and other high-pressure phases along polysynthetic twin boundaries provides a mechanism for the inheritance of crystallographic preferred orientation from previously deformed enstatite-bearing rocks within subducting slabs.
The Great Basin (GB) in the western U.S. is part of the diffuse North American-Pacific plate boundary. The interior of the GB occasionally produces large earthquakes, yet the current distribution of regional seismic networks poorly samples it. The EarthScope USArray Transportable Array provides unprecedented station density and data quality for the central GB. I use this dataset to develop an earthquake catalog for the region that is complete to M 1.5. The catalog contains small-magnitude seismicity throughout the interior of the GB. The spatial distribution of earthquakes is consistent with recent regional geodetic studies, confirming that the interior of the GB is actively deforming everywhere and all the time. Additionally, improved event detection thresholds reveal that swarms of temporally-clustered repeating earthquakes occur throughout the GB. The swarms are not associated with active volcanism or other swarm triggering mechanisms, and therefore, may represent a common fault behavior.
Enstatite (Mg,Fe)SiO3 is the second most abundant mineral within subducting lithosphere. Previous studies suggest that metastable enstatite within subducting slabs may persist to the base of the mantle transition zone (MTZ) before transforming to high-pressure polymorphs. The metastable persistence of enstatite has been proposed as a potential cause for both deep-focus earthquakes and the stagnation of slabs at the base of the MTZ. I show that natural Al- and Fe-bearing enstatite reacts more readily than previous studies and by multiple transformation mechanisms at conditions as low as 1200°C and 18 GPa. Metastable enstatite is thus unlikely to survive to the base of the MTZ. Additionally, coherent growth of akimotoite and other high-pressure phases along polysynthetic twin boundaries provides a mechanism for the inheritance of crystallographic preferred orientation from previously deformed enstatite-bearing rocks within subducting slabs.
ContributorsLockridge, Jeffrey Steven (Author) / Sharp, Thomas (Thesis advisor) / Arrowsmith, Ramon (Thesis advisor) / Shim, Sang-Heon (Committee member) / Garnero, Edward (Committee member) / Leinenweber, Kurt (Committee member) / Arizona State University (Publisher)
Created2015
Description
Shock metamorphism in meteorites constrains the impact histories of asteroids and planets. Shock-induced high-pressure (HP) minerals can provide more precise estimates of shock conditions than shock-induced deformation effects. In this research, I use shock features, particularly HP minerals, in ordinary-chondrite samples to constrain not only shock pressures but also the pressure-temperature-time (P-T-t) paths they experienced.
Highly shocked L5/6 chondrites Acfer 040, Mbale, NWA 091 and Chico and LL6 chondrite NWA 757 were used to investigate a variety of shock pressures and post-shock annealing histories. NWA 757 is the only highly shocked LL chondrite that includes abundant HP minerals. The assemblage of ringwoodite and majoritic garnet indicates an equilibration shock pressure of ~20 GPa, similar to many strongly shocked L chondrites. Acfer 040 is one of the only two chondrite samples with bridgmanite (silicate perovskite), suggesting equilibration pressure >25 GPa. The bridgmanite, which is unstable at low-pressure, was mostly vitrified during post-shock cooling. Mbale demonstrates an example of elevated post-shock temperature resulting in back-transformation of ringwoodite to olivine. In contrast, majoritic garnet in Mbale survives as unambiguous evidence of strong shock. In these two samples, HP minerals are exclusively associated with shock melt, indicating that elevated shock temperatures are required for rapid mineral transformations during the transient shock pulse. However, elevated post-shock temperatures can destroy HP minerals: in temperature sequence from bridgmanite to ringwoodite then garnet. NWA 091 and Chico are impact melt breccias with pervasive melting, blackening of silicates, recrystallization of host rock but no HP minerals. These features indicate near whole-rock-melting conditions. However, the elevated post-shock temperatures of these samples has annealed out HP signatures. The observed shock features result from a complex P-T-t path and may not directly reflect the peak shock pressure. Although HP minerals provide robust evidence of high pressure, their occurrence also requires high shock temperatures and rapid cooling during the shock pulse. The most highly shocked samples lack HP signatures but have abundant high-temperature features formed after pressure release.
Highly shocked L5/6 chondrites Acfer 040, Mbale, NWA 091 and Chico and LL6 chondrite NWA 757 were used to investigate a variety of shock pressures and post-shock annealing histories. NWA 757 is the only highly shocked LL chondrite that includes abundant HP minerals. The assemblage of ringwoodite and majoritic garnet indicates an equilibration shock pressure of ~20 GPa, similar to many strongly shocked L chondrites. Acfer 040 is one of the only two chondrite samples with bridgmanite (silicate perovskite), suggesting equilibration pressure >25 GPa. The bridgmanite, which is unstable at low-pressure, was mostly vitrified during post-shock cooling. Mbale demonstrates an example of elevated post-shock temperature resulting in back-transformation of ringwoodite to olivine. In contrast, majoritic garnet in Mbale survives as unambiguous evidence of strong shock. In these two samples, HP minerals are exclusively associated with shock melt, indicating that elevated shock temperatures are required for rapid mineral transformations during the transient shock pulse. However, elevated post-shock temperatures can destroy HP minerals: in temperature sequence from bridgmanite to ringwoodite then garnet. NWA 091 and Chico are impact melt breccias with pervasive melting, blackening of silicates, recrystallization of host rock but no HP minerals. These features indicate near whole-rock-melting conditions. However, the elevated post-shock temperatures of these samples has annealed out HP signatures. The observed shock features result from a complex P-T-t path and may not directly reflect the peak shock pressure. Although HP minerals provide robust evidence of high pressure, their occurrence also requires high shock temperatures and rapid cooling during the shock pulse. The most highly shocked samples lack HP signatures but have abundant high-temperature features formed after pressure release.
ContributorsHu, Jinping (Author) / Sharp, Thomas G. (Thesis advisor) / Tyburczy, James A. (Committee member) / Leinenweber, Kurt (Committee member) / Wadhwa, Meenakshi (Committee member) / Zolotov, Mikhail (Committee member) / Arizona State University (Publisher)
Created2016
Description
The Jovian moon Europa's putative subsurface ocean offers one of the closest astrobiological targets for future exploration. It’s geologically young surface with a wide array of surface features aligned with distinct surface composition suggests past/present geophysical activity with implications for habitability. In this body of work, I propose a hypothesis for material transport from the ocean towards the surface via a convecting ice-shell. Geodynamical modeling is used to perform numerical experiments on a two-phase water-ice system to test the hypotheses. From these models, I conclude that it is possible for trace oceanic chemistry, entrapped into the newly forming ice at the ice-ocean phase interface, to reach near-surface. This new ice is advected across the ice-shell and towards the surface affirming a dynamical possibility for material transport across the ice-ocean system, of significance to astrobiological prospecting. Next, I use these self-consistent ice-ocean models to study the thickening of ice-shell over time. Europa is subject to the immense gravity field of Jupiter that generates tidal heating within the moon. Analysis of cases with uniform and localized internal tidal heating reveal that as the ice-shell grows from a warm initial ocean, there is an increase in the size of convection cells which causes a dramatic increase in the growth rate of the ice-shell. Addition of sufficient amount of heat also results in an ice-shell at an equilibrium thickness. Localization of tidal heating as a function of viscosity controls the equilibrium thickness. These models are then used to understand how compositional heterogeneity can be created in a growing ice-shell. Impurities (e.g. salts on the surface) that enter the ice-shell get trapped in the thickening ice-shell by freezing. I show the distribution pattern of heterogeneities that can form within the ice-shell at different times. This may be of potential application in identifying the longevity and mobility of brine pockets in Europa's ice-shell which are thought to be potential habitable niches.
ContributorsAllu Peddinti, Divya (Author) / McNamara, Allen Keith (Thesis advisor) / Garnero, Edward (Committee member) / Desch, Steven (Committee member) / Zolotov, Mikhail (Committee member) / Clarke, Amanda (Committee member) / Arizona State University (Publisher)
Created2017
Description
We model the self-compression of homogeneous, undifferentiated, Ceres-like bodies composed of various minerals and mineral-composites: antigorite, brucite, dolomite, lizardite and magnesite, plus mixtures which were the above minerals mixed with ice Ih. All of the modeled clay/ice bodies had a final radius within 1% of RCeres, an average final density of ~2083 kg m-3 and central pressures of ~133 MPa. The smallest radius was from magnesite, which had a final compressed radius of ~0.88 RCeres, central pressure of ~212 MPa and final density of ~2955 kg m-3. The most significant change in radius was due to the zero-pressure density as the highest densities created the highest force of gravity and produced the smallest radii, yet zero-pressure densities that matched Ceres produced 0.99 RCeres bodies. It was found that the addition of ice, anywhere from 9.1-19.1%, did not affect the body a measurable amount as the inclusion of ice resulted in a lower density creating a lower force of gravity, decreased central pressure and less overall compression. Models that closely resembled Ceres had internal pressures of 133 MPa, which is not enough pressure to induce pore collapse or produce drastic changes due to K and K'. Porosity and the addition of ice in Ceres-like bodies is possible and cannot be ignored when using more complicated modeling techniques. Each mineral and mineral-composite produced unique overall results which allowed us to compare each mineral to Ceres, understand how it has compressed over time and how objects of such a size are affected by compression. Due to the small size, low force of gravity and high bulk moduli of the given minerals, Ceres-like bodies do not compress a considerable amount if they are in fact composed of hydrated silicates.
ContributorsMastrean, Alex Travis (Author) / Desch, Steven (Thesis director) / Zolotov, Mikhail (Committee member) / Shim, Sang-Heon Dan (Committee member) / School of Earth and Space Exploration (Contributor) / Barrett, The Honors College (Contributor)
Created2015-12
Description
The transport of hydrogen to the Earth’s deep interior remains uncertain. The upper mantle minerals have very low hydrogen solubilities (hundreds of ppm). The hydrogen storage capability in the transition zone minerals (2 wt%) is high compared to those of the upper mantle. The hydrogen storage in the lower mantle is not well known. The main minerals in the lower mantle bridgmanite and ferropericlase have very low hydrogen storage capacities (less than 20 ppm). In order to further understand the hydrogen storage in the lower mantle, a series of experiments had been conducted to simulate the environment similar to the Earth’s mantle. The experiments with hydrous Mg2SiO4 ringwoodite (Rw) show that it converts to crystalline dense hydrous silica, stishovite (Stv) or CaCl2-type SiO2(mStv), containing ∼1 wt% H2O together with bridgmanite (Brd) and MgO at the pressure-temperature conditions expected for lower mantle depths between approximately 660 to 1600 km. Brd would break down partially to dense hydrous silica (6–25 mol%) and(Mg,Fe)O in mid-mantle regions with 0.05–0.27 wt% H2O. The hydrous stishovite has a CaCl2 structure, which is common among hydrous minerals in the lower mantle. Based on this observation, I hypothesize the existence of hydrous phases in the lower mantle. The experiments found a new hexagonal iron hydroxide (η-Fe12O18+x/2Hx) between the stability fields of the epsilon and pyrite-type FeOOH at 60–80 GPa and high temperature. The new phase contains less H2O, limiting the H2O transport from the shallow to the deep mantle in the Fe–O–H system. Possible hydrogen storage in Ca-perovskite was studied. CaPv could contain 0.5–1 wt% water and the water in CaPv could distort the crystal structure of CaPv from cubic to tetragonal structure. In conclusion, hydrogen can be stored in hydrous stishovite in the shallower depth of the lower mantle. At greater depth, the new η phase and pyrite-type phase would take over the hydrogen storage. The role of CaPv in deep water storage needs to be considered in future studies.
ContributorsChen, Huawei (Author) / Shim, Sang-Heon (Thesis advisor) / Garnero, Edward (Committee member) / Bose, Maitrayee (Committee member) / Li, Mingming (Committee member) / Leinenweber, Kurt (Committee member) / Arizona State University (Publisher)
Created2019
Description
Part I – I analyze a database of Smoothed Particle Hydrodynamics (SPH) simulations of collisions between planetary bodies and use the data to define semi-empirical models that reproduce remant masses. These models may be leveraged when detailed, time-dependent aspects of the collision are not paramount, but analytical intuition or a rapid solution is required, e.g. in ‘N-body simulations’. I find that the stratification of the planet is a non-negligible control on accretion efficiency. I also show that the absolute scale (total mass) of the collision may affect the accretion efficiency, with larger bodies more efficiently disrupting, as a function of gravitational binding energy. This is potentially due to impact velocities above the sound speed. The interplay of these dependencies implies that planet formation, depending on the dynamical environment, may be separated into stages marked by differentiation and the growth of planets more massive than the Moon.
Part II – I examine time-resolved neutron data from the Dynamic Albedo of Neutrons (DAN) instrument on the Mars Science Laboratory (MSL) Curiosity rover. I personally and independently developed a data analysis routine (described in the supplementary material in Chapter 2) that utilizes spectra from Monte Carlo N-Particle Transport models of the experiment and the Markov-chain Monte Carlo method to estimate bulk soil/rock properties. The method also identifies cross-correlation and degeneracies. I use data from two measurement campaigns that I targeted during remote operations at ASU. I find that alteration zones of a sandstone unit in Gale crater are markedly elevated in H content from the parent rock, consistent with the presence of amorphous silica. I posit that these deposits were formed by the most recent aqueous alteration events in the crater, since subsequent events would have produced matured forms of silica that were not observed. I also find that active dunes in Gale crater contain minimal water and I developed a Monte Carlo phase analysis routine to understand the amorphous materials in the dunes.
Part II – I examine time-resolved neutron data from the Dynamic Albedo of Neutrons (DAN) instrument on the Mars Science Laboratory (MSL) Curiosity rover. I personally and independently developed a data analysis routine (described in the supplementary material in Chapter 2) that utilizes spectra from Monte Carlo N-Particle Transport models of the experiment and the Markov-chain Monte Carlo method to estimate bulk soil/rock properties. The method also identifies cross-correlation and degeneracies. I use data from two measurement campaigns that I targeted during remote operations at ASU. I find that alteration zones of a sandstone unit in Gale crater are markedly elevated in H content from the parent rock, consistent with the presence of amorphous silica. I posit that these deposits were formed by the most recent aqueous alteration events in the crater, since subsequent events would have produced matured forms of silica that were not observed. I also find that active dunes in Gale crater contain minimal water and I developed a Monte Carlo phase analysis routine to understand the amorphous materials in the dunes.
ContributorsGabriel, Travis Saint James (Author) / Asphaug, Erik I (Thesis advisor) / Hardgrove, Craig (Thesis advisor) / Sharp, Thomas (Committee member) / Zolotov, Mikhail (Committee member) / Young, Patrick (Committee member) / Arizona State University (Publisher)
Created2019
Description
The redox conditions of Earth have been changing since proto-Earth’s accretion from the solar nebula. These changes have influenced the distribution and partitioning of volatile elements between the atmosphere and the mantle (Righter et al., 2020; Stagno and Fei, 2020. Though oxygen fugacity fO2 is arguably not the main factor for phase stability at certain pressure-temperature conditions (McCammon, 2005), it can influence which phases are stable, especially within a closed system such as the ones presented in this study. Despite the importance of controlling fO2 for interpreting the history of planetary bodies, there have been no methods to control the redox conditions in the laser-heated diamond anvil cell (LHDAC). This thesis has examined the feasibility for controlling redox conditions in the LHDAC using a mixture of Ar and H2 for insulation media. The experiments of this study were carried out at the GSECARS sector of the Advanced Photon Source at Argonne National Laboratory. In this study, α-Fe2O3 (hematite), ε-FeOOH (CaCl2-type), and Fe3O4 (magnetite) starting materials were used for probing changes of redox conditions. Experiments were also conducted with a pure Ar-medium for ε-FeOOH at the same pressure-temperature conditions of the hydrogen-bearing medium in order to provide a reference point for data which has uncontrolled redox conditions for an initially Fe(2+)-free material. The results for the ε-FeOOH starting material in Ar show transformation to ι-Fe2O3 (Rh2O3(II)-type) at 30.0 GPa and 1900 K, while in Ar + H2 it transformed to Fe5O7 with minor FeH (dhcp) at 30.0 GPa and 1850 K. For α-Fe2O3 in Ar + H2, it was found to convert to ε-FeOOH, Fe5O7, Fe5O6, and FeH (dhcp) at 36.5 GPa and 1800 K. For Fe3O4 in Ar + H2, it was found to convert to Fe4O5 (CaFe3O5-type), Fe5O6, and minor FeH (fcc) at 26.0 GPa and 1800 K. These results demonstrate that H in an Ar medium can promote the conversion of some Fe(3+) to Fe(2+) and Fe(0). However, the formation of ε-FeOOH in the α-Fe2O3 starting material suggests that H may participate in the chemical reaction of iron oxides.
ContributorsKulka, Britany Lynn (Author) / Shim, Sang-Heon (Thesis advisor) / Sharp, Thomas (Committee member) / Leinenweber, Kurt (Committee member) / Hervig, Richard (Committee member) / Arizona State University (Publisher)
Created2021
Description
The mineralogy of the deep mantle is one of the key factors for the chemical evolution of the Earth. The constituent minerals of the mantle rock control the physical properties of the mantle, which have significant impacts on the large-scale processes occurring in the Earth's interior. In my PhD research, I adopted experimental approaches to investigate the mineralogy and the physical properties of the Earth's materials in the deep mantle by using the diamond anvil cells (DACs) combined with in-situ X-ray diffraction techniques.
First, I found that Ca-bearing bridgmanite can be stable in the deeper part of the Earth's lower mantle where temperature is sufficiently high. The dissolution of calcium into bridgmanite can change the physical properties of the mantle, such as compressibility and viscosity. This study suggests a new mineralogical model for the lower mantle, which is composed of the two layers depending on whether calcium dissolves in bridgmanite or forms CaSiO3 perovskite as a separate phase.
Second, I investigated the mineralogy and density of the subducting materials in the Archean at the P-T conditions near 670 km-depth. The experiments suggest that the major phases of Archean volcanic crust is majoritic garnet and ringwoodite in the P-T conditions of the deep transition zone, which become bridgmanite with increasing pressure. The density model showed that Archean volcanic crust would have been denser than the surrounding mantle, promoting sinking into the lower mantle regardless of the style of the transportation in the Archean.
Lastly, I further investigated the mineralogies and densities of the ancient volcanic crusts for the Archean and Proterozoic at the P-T conditions of the lower mantle. The experiments suggest that the mineralogy of the ancient volcanic crusts is composed mostly of bridgmanite, which is systemically denser than the surrounding lower mantle. This implies that the ancient volcanic crusts would have accumulated at the base of the mantle because of their large density and thickness. Therefore, the distinctive chemistry of the ancient volcanic crusts from the surrounding mantle would have given a rise to the chemical heterogeneities in the region for billions of years.
First, I found that Ca-bearing bridgmanite can be stable in the deeper part of the Earth's lower mantle where temperature is sufficiently high. The dissolution of calcium into bridgmanite can change the physical properties of the mantle, such as compressibility and viscosity. This study suggests a new mineralogical model for the lower mantle, which is composed of the two layers depending on whether calcium dissolves in bridgmanite or forms CaSiO3 perovskite as a separate phase.
Second, I investigated the mineralogy and density of the subducting materials in the Archean at the P-T conditions near 670 km-depth. The experiments suggest that the major phases of Archean volcanic crust is majoritic garnet and ringwoodite in the P-T conditions of the deep transition zone, which become bridgmanite with increasing pressure. The density model showed that Archean volcanic crust would have been denser than the surrounding mantle, promoting sinking into the lower mantle regardless of the style of the transportation in the Archean.
Lastly, I further investigated the mineralogies and densities of the ancient volcanic crusts for the Archean and Proterozoic at the P-T conditions of the lower mantle. The experiments suggest that the mineralogy of the ancient volcanic crusts is composed mostly of bridgmanite, which is systemically denser than the surrounding lower mantle. This implies that the ancient volcanic crusts would have accumulated at the base of the mantle because of their large density and thickness. Therefore, the distinctive chemistry of the ancient volcanic crusts from the surrounding mantle would have given a rise to the chemical heterogeneities in the region for billions of years.
ContributorsKo, Byeongkwan (Author) / Shim, Sang-Heon (Thesis advisor) / Garnero, Edward (Committee member) / Leinenweber, Kurt (Committee member) / Li, Mingming (Committee member) / Desch, Steven (Committee member) / Arizona State University (Publisher)
Created2020
Description
Cubic (space group: Fmm) iridium phosphide, Ir2P, has been synthesized at high pressure and high temperature. Angle-dispersive synchrotron X-ray diffraction measurements on Ir2P powder using a diamond-anvil cell at room temperature and high pressures (up to 40.6 GPa) yielded a bulk modulus of B[subscript 0] = 306(6) GPa and its pressure derivative B0′ = 6.4(5). Such a high bulk modulus attributed to the short and strongly covalent Ir-P bonds as revealed by first – principles calculations and three-dimensionally distributed [IrP4] tetrahedron network. Indentation testing on a well–sintered polycrystalline sample yielded the hardness of 11.8(4) GPa. Relatively low shear modulus of ~64 GPa from theoretical calculations suggests a complicated overall bonding in Ir2P with metallic, ionic, and covalent characteristics. In addition, a spin glass behavior is indicated by magnetic susceptibility measurements.
ContributorsWang, Pei (Author) / Wang, Yonggang (Author) / Wang, Liping (Author) / Zhang, Xinyu (Author) / Yu, Xiaohui (Author) / Zhu, Jinlong (Author) / Wang, Shanmin (Author) / Qin, Jiaqian (Author) / Leinenweber, Kurt (Author) / Chen, Haihua (Author) / He, Duanwei (Author) / Zhao, Yusheng (Author) / Department of Chemistry and Biochemistry (Contributor)
Created2016-02-24