Matching Items (119)
Description
Wide bandgap (WBG) semiconductors GaN (3.4 eV), Ga2O3 (4.8 eV) and AlN (6.2 eV), have gained considerable interests for energy-efficient optoelectronic and electronic applications in solid-state lighting, photovoltaics, power conversion, and so on. They can offer unique device performance compared with traditional semiconductors such as Si. Efficient GaN based light-emitting diodes (LEDs) have increasingly displaced incandescent and fluorescent bulbs as the new major light sources for lighting and display. In addition, due to their large bandgap and high critical electrical field, WBG semiconductors are also ideal candidates for efficient power conversion.
In this dissertation, two types of devices are demonstrated: optoelectronic and electronic devices. Commercial polar c-plane LEDs suffer from reduced efficiency with increasing current densities, knowns as “efficiency droop”, while nonpolar/semipolar LEDs exhibit a very low efficiency droop. A modified ABC model with weak phase space filling effects is proposed to explain the low droop performance, providing insights for designing droop-free LEDs. The other emerging optoelectronics is nonpolar/semipolar III-nitride intersubband transition (ISBT) based photodetectors in terahertz and far infrared regime due to the large optical phonon energy and band offset, and the potential of room-temperature operation. ISBT properties are systematically studied for devices with different structures parameters.
In terms of electronic devices, vertical GaN p-n diodes and Schottky barrier diodes (SBDs) with high breakdown voltages are homoepitaxially grown on GaN bulk substrates with much reduced defect densities and improved device performance. The advantages of the vertical structure over the lateral structure are multifold: smaller chip area, larger current, less sensitivity to surface states, better scalability, and smaller current dispersion. Three methods are proposed to boost the device performances: thick buffer layer design, hydrogen-plasma based edge termination technique, and multiple drift layer design. In addition, newly emerged Ga2O3 and AlN power electronics may outperform GaN devices. Because of the highly anisotropic crystal structure of Ga2O3, anisotropic electrical properties have been observed in Ga2O3 electronics. The first 1-kV-class AlN SBDs are demonstrated on cost-effective sapphire substrates. Several future topics are also proposed including selective-area doping in GaN power devices, vertical AlN power devices, and (Al,Ga,In)2O3 materials and devices.
In this dissertation, two types of devices are demonstrated: optoelectronic and electronic devices. Commercial polar c-plane LEDs suffer from reduced efficiency with increasing current densities, knowns as “efficiency droop”, while nonpolar/semipolar LEDs exhibit a very low efficiency droop. A modified ABC model with weak phase space filling effects is proposed to explain the low droop performance, providing insights for designing droop-free LEDs. The other emerging optoelectronics is nonpolar/semipolar III-nitride intersubband transition (ISBT) based photodetectors in terahertz and far infrared regime due to the large optical phonon energy and band offset, and the potential of room-temperature operation. ISBT properties are systematically studied for devices with different structures parameters.
In terms of electronic devices, vertical GaN p-n diodes and Schottky barrier diodes (SBDs) with high breakdown voltages are homoepitaxially grown on GaN bulk substrates with much reduced defect densities and improved device performance. The advantages of the vertical structure over the lateral structure are multifold: smaller chip area, larger current, less sensitivity to surface states, better scalability, and smaller current dispersion. Three methods are proposed to boost the device performances: thick buffer layer design, hydrogen-plasma based edge termination technique, and multiple drift layer design. In addition, newly emerged Ga2O3 and AlN power electronics may outperform GaN devices. Because of the highly anisotropic crystal structure of Ga2O3, anisotropic electrical properties have been observed in Ga2O3 electronics. The first 1-kV-class AlN SBDs are demonstrated on cost-effective sapphire substrates. Several future topics are also proposed including selective-area doping in GaN power devices, vertical AlN power devices, and (Al,Ga,In)2O3 materials and devices.
ContributorsFu, Houqiang (Author) / Zhao, Yuji (Thesis advisor) / Vasileska, Dragica (Committee member) / Goodnick, Stephen (Committee member) / Yu, Hongbin (Committee member) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2019
Description
Soft polymer composites with improved thermal conductivity are needed for the thermal management of electronics. Interfacial thermal boundary resistance, however, prevents the efficient use of many high thermal conductivity fill materials. Magnetic alignment of ferrous fill material enforces percolation of the high thermal conductivity fill, thereby shifting the governing boundary resistance to the particle- particle interfaces and increasing the directional thermal conductivity of the polymer composite. Magnetic alignment maximizes the thermal conductivity while minimizing composite stiffening at a fill fraction of half the maximum packing factor. The directional thermal conductivity of the composite is improved by more than 2-fold. Particle-particle contact engineering is then introduced to decrease the particle- particle boundary resistance and further improve the thermal conductivity of the composite.
The interface between rigid fill particles is a point contact with very little interfacial area connecting them. Silver and gallium-based liquid metal (LM) coatings provide soft interfaces that, under pressure, increase the interfacial area between particles and decrease the particle-particle boundary resistance. These engineered contacts are investigated both in and out of the polymer matrix and with and without magnetic alignment of the fill. Magnetically aligned in the polymer matrix, 350nm- thick silver coatings on nickel particles produce a 1.8-fold increase in composite thermal conductivity over the aligned bare-nickel composites. The LM coatings provide similar enhancements, but require higher volumes of LM to do so. This is due to the rapid formation of gallium oxide, which introduces additional thermal boundaries and decreases the benefit of the LM coatings.
The oxide shell of LM droplets (LMDs) can be ruptured using pressure. The pressure needed to rupture LMDs matches closely to thin-walled pressure vessel theory. Furthermore, the addition of tungsten particles stabilizes the mixture for use at higher pressures. Finally, thiols and hydrochloric acid weaken the oxide shell and boost the thermal performance of the beds of LMDs by 50% at pressures much lower than 1 megapascal (MPa) to make them more suitable for use in TIMs.
The interface between rigid fill particles is a point contact with very little interfacial area connecting them. Silver and gallium-based liquid metal (LM) coatings provide soft interfaces that, under pressure, increase the interfacial area between particles and decrease the particle-particle boundary resistance. These engineered contacts are investigated both in and out of the polymer matrix and with and without magnetic alignment of the fill. Magnetically aligned in the polymer matrix, 350nm- thick silver coatings on nickel particles produce a 1.8-fold increase in composite thermal conductivity over the aligned bare-nickel composites. The LM coatings provide similar enhancements, but require higher volumes of LM to do so. This is due to the rapid formation of gallium oxide, which introduces additional thermal boundaries and decreases the benefit of the LM coatings.
The oxide shell of LM droplets (LMDs) can be ruptured using pressure. The pressure needed to rupture LMDs matches closely to thin-walled pressure vessel theory. Furthermore, the addition of tungsten particles stabilizes the mixture for use at higher pressures. Finally, thiols and hydrochloric acid weaken the oxide shell and boost the thermal performance of the beds of LMDs by 50% at pressures much lower than 1 megapascal (MPa) to make them more suitable for use in TIMs.
ContributorsRalphs, Matthew (Author) / Rykaczewski, Konrad (Thesis advisor) / Wang, Robert Y (Thesis advisor) / Phelan, Patrick (Committee member) / Wang, Liping (Committee member) / Devasenathipathy, Shankar (Committee member) / Arizona State University (Publisher)
Created2019
Description
Demand for green energy alternatives to provide stable and reliable energy
solutions has increased over the years which has led to the rapid expansion of global
markets in renewable energy sources such as solar photovoltaic (PV) technology. Newest
amongst these technologies is the Bifacial PV modules, which harvests incident radiation
from both sides of the module. The overall power generation can be significantly increased
by using these bifacial modules. The purpose of this research is to investigate and maximize
the effect of back reflectors, designed to increase the efficiency of the module by utilizing
the intercell light passing through the module to increase the incident irradiance, on the
energy output using different profiles placed at varied distances from the plane of the array
(POA). The optimum reflector profile and displacement of the reflector from the module
are determined experimentally.
Theoretically, a 60-cell bifacial module can produce 26% additional energy in
comparison to a 48-cell bifacial module due to the 12 excess cells found in the 60-cell
module. It was determined that bifacial modules have the capacity to produce additional
energy when optimized back reflectors are utilized. The inverted U reflector produced
higher energy gain when placed at farther distances from the module, indicating direct
dependent proportionality between the placement distance of the reflector from the module
and the output energy gain. It performed the best out of all current construction geometries
with reflective coatings, generating more than half of the additional energy produced by a
densely-spaced 60-cell benchmark module compared to a sparsely-spaced 48-cell reference
module.ii
A gain of 11 and 14% was recorded on cloudy and sunny days respectively for the
inverted U reflector. This implies a reduction in the additional cells of the 60-cell module
by 50% can produce the same amount of energy of the 60-cell module by a 48-cell module
with an inverted U reflector. The use of the back reflectors does not only affect the
additional energy gain but structural and land costs. Row to row spacing for bifacial
systems(arrays) is reduced nearly by half as the ground height clearance is largely
minimized, thus almost 50% of height constraints for mounting bifacial modules, using
back reflectors resulting in reduced structural costs for mounting of bifacial modules
solutions has increased over the years which has led to the rapid expansion of global
markets in renewable energy sources such as solar photovoltaic (PV) technology. Newest
amongst these technologies is the Bifacial PV modules, which harvests incident radiation
from both sides of the module. The overall power generation can be significantly increased
by using these bifacial modules. The purpose of this research is to investigate and maximize
the effect of back reflectors, designed to increase the efficiency of the module by utilizing
the intercell light passing through the module to increase the incident irradiance, on the
energy output using different profiles placed at varied distances from the plane of the array
(POA). The optimum reflector profile and displacement of the reflector from the module
are determined experimentally.
Theoretically, a 60-cell bifacial module can produce 26% additional energy in
comparison to a 48-cell bifacial module due to the 12 excess cells found in the 60-cell
module. It was determined that bifacial modules have the capacity to produce additional
energy when optimized back reflectors are utilized. The inverted U reflector produced
higher energy gain when placed at farther distances from the module, indicating direct
dependent proportionality between the placement distance of the reflector from the module
and the output energy gain. It performed the best out of all current construction geometries
with reflective coatings, generating more than half of the additional energy produced by a
densely-spaced 60-cell benchmark module compared to a sparsely-spaced 48-cell reference
module.ii
A gain of 11 and 14% was recorded on cloudy and sunny days respectively for the
inverted U reflector. This implies a reduction in the additional cells of the 60-cell module
by 50% can produce the same amount of energy of the 60-cell module by a 48-cell module
with an inverted U reflector. The use of the back reflectors does not only affect the
additional energy gain but structural and land costs. Row to row spacing for bifacial
systems(arrays) is reduced nearly by half as the ground height clearance is largely
minimized, thus almost 50% of height constraints for mounting bifacial modules, using
back reflectors resulting in reduced structural costs for mounting of bifacial modules
ContributorsMARTIN, PEDRO JESSE (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Phelan, Patrick (Committee member) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2019
Optical simulation and optimization of light extraction efficiency for organic light emitting diodes
Description
Current organic light emitting diodes (OLEDs) suffer from the low light extraction efficiency. In this thesis, novel OLED structures including photonic crystal, Fabry-Perot resonance cavity and hyperbolic metamaterials were numerically simulated and theoretically investigated. Finite-difference time-domain (FDTD) method was employed to numerically simulate the light extraction efficiency of various 3D OLED structures. With photonic crystal structures, a maximum of 30% extraction efficiency is achieved. A higher external quantum efficiency of 35% is derived after applying Fabry-Perot resonance cavity into OLEDs. Furthermore, different factors such as material properties, layer thicknesses and dipole polarizations and locations have been studied. Moreover, an upper limit for the light extraction efficiency of 80% is reached theoretically with perfect reflector and single dipole polarization and location. To elucidate the physical mechanism, transfer matrix method is introduced to calculate the spectral-hemispherical reflectance of the multilayer OLED structures. In addition, an attempt of using hyperbolic metamaterial in OLED has been made and resulted in 27% external quantum efficiency, due to the similar mechanism of wave interference as Fabry-Perot structure. The simulation and optimization methods and findings would facilitate the design of next generation, high-efficiency OLED devices.
ContributorsSu, Hang (Author) / Wang, Liping (Thesis advisor) / Li, Jian (Committee member) / Huang, Huei-Ping (Committee member) / Arizona State University (Publisher)
Created2016
Description
Solar energy is leading in renewable energy sources and the aspects surrounding the efforts to harvest light are gaining importance. One such aspect is increasing the light absorption, where heliotropism comes into play. Heliotropism, the ability to track the sun across the sky, can be integrated with solar cells for more efficient photon collection and other optoelectronic systems. Inspired by plants, which optimize incident sunlight in nature, several researchers have made artificial heliotropic and phototropic systems. This project aims to design, synthesize and characterize a material system and evaluate its application in a phototropic system. A gold nanoparticle (Au NP) incorporated poly(N-isopropylacrylamide) (PNIPAAm) hydrogel was synthesized as a photo-thermo-responsive material in our phototropic system. The Au NPs generate heat from the incident via plasmonic resonance to induce a volume phase change of the thermo-responsive hydrogel PNIPAAm. PNIPAAm shrinks or swells at temperature above or below 32°C. Upon irradiation, the Au NP-PNIPAAm micropillar actuates, specifically bending toward the incident light and precisely following the varying incident angle.
Swelling ratio tests, bending angle tests with a static incident light and bending tests with varying angles were carried out on hydrogel samples with varying Au NP concentrations. Swelling ratios ranging from 1.45 to 2.9 were recorded for pure hydrogel samples and samples with very low Au NP concentrations. Swelling ratios of 2.41 and 3.37 were calculated for samples with low and high concentrations of Au NPs, respectively. A bending of up to 88° was observed in Au NP-hydrogel pillars with a low Au NP concentration with a 90° incident angle. The light tracking performance was assessed by the slope of the pillar Bending angle (response angle) vs. Incident light angle plot. A slope of 1 indicates ideal tracking with top of the pillar being normal to the incident light, maximizing the photon absorption. Slopes of 0.82 and 0.56 were observed for the low and high Au NP concentration samples. The rapid and precise incident light tracking of our system has shown the promise in phototropic applications.
Swelling ratio tests, bending angle tests with a static incident light and bending tests with varying angles were carried out on hydrogel samples with varying Au NP concentrations. Swelling ratios ranging from 1.45 to 2.9 were recorded for pure hydrogel samples and samples with very low Au NP concentrations. Swelling ratios of 2.41 and 3.37 were calculated for samples with low and high concentrations of Au NPs, respectively. A bending of up to 88° was observed in Au NP-hydrogel pillars with a low Au NP concentration with a 90° incident angle. The light tracking performance was assessed by the slope of the pillar Bending angle (response angle) vs. Incident light angle plot. A slope of 1 indicates ideal tracking with top of the pillar being normal to the incident light, maximizing the photon absorption. Slopes of 0.82 and 0.56 were observed for the low and high Au NP concentration samples. The rapid and precise incident light tracking of our system has shown the promise in phototropic applications.
ContributorsGopalakrishna, Hamsini (Author) / He, Ximin (Thesis advisor) / Holman, Zachary C (Committee member) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2016
Description
Mechanical behavior of metallic thin films at room temperature (RT) is relatively well characterized. However, measuring the high temperature mechanical properties of thin films poses several challenges. These include ensuring uniformity in sample temperature and minimizing temporal fluctuations due to ambient heat loss, in addition to difficulties involved in mechanical testing of microscale samples. To address these issues, we designed and analyzed a MEMS-based high temperature tensile testing stage made from single crystal silicon. The freestanding thin film specimens were co-fabricated with the stage to ensure uniaxial loading. Multi-physics simulations of Joule heating, incorporating both radiation and convection heat transfer, were carried out using COMSOL to map the temperature distribution across the stage and the specimen. The simulations were validated using temperature measurements from a thermoreflectance microscope.
ContributorsEswarappa Prameela, Suhas (Author) / Rajagopalan, Jagannathan (Thesis advisor) / Wang, Liping (Committee member) / Jiao, Yang (Committee member) / Arizona State University (Publisher)
Created2016
Description
In recent years, solar photovoltaic (PV) industry has seen lots of improvements in technology and of growth in market with crystalline silicon PV modules being the most widely used technology. Plant inspections are gaining much importance to identify and quantitatively determine the impacts of various visual defects on performance. There are about 86 different types of defects found in the PV modules installed in various climates and most of them can be visually observed. However, a quantitative determination of impact or risk of each of identified defect on performance is challenging. Thus, it is utmost important to quantify the risk for each of the visual defects without any human subjectivity. The best way to quantify the risk of each defect is to perform current-voltage measurements of the defective modules installed in the plant but it requires disruption of plant operation, expensive measuring equipment and intensive human resources. One of the most riskiest and dominant visual defects is encapsulant browning which affects the PV module performance in the form of current degradation. The present study deals with developing an automated image processing tool which can address the issues of human subjectivity on browning level impacting performance. The image processing tool developed in this work can be directly used to quantify the impact of browning on performance without intrusively disconnecting the modules from the plant. In this work, the quantified browning level impact on performance has also been experimentally validated through a correlation study using short-circuit current and reflectance/transmittance measurements of browned PV modules retrieved from aged plants/systems installed in diverse climatic conditions. The primary goal of the image processing tool developed in this work is to determine the performance impact of encapsulant browning without interrupting the plant operation for I-V measurements. The use of image processing tool provides a single numerical value, called browning index (BI), which can accurately quantify browning levels on modules and also correlate with the performance and reflectance/transmittance parameters of the modules.
ContributorsGudla, Sushanth (Author) / Govindasamy, Tamizhmani (Thesis advisor) / Patrick, Phelan E (Thesis advisor) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2016
Description
Origami and kirigami, the technique of generating three-dimensional (3D) structures from two-dimensional (2D) flat sheets, are now more and more involved in scientific and engineering fields. Therefore, the development of tools for their theoretical analysis becomes more and more important. Since much effort was paid on calculations based on pure mathematical consideration and only limited effort has been paid to include mechanical properties, the goal of my research is developing a method to analyze the mechanical behavior of origami and kirigami based structures. Mechanical characteristics, including nonlocal effect and fracture of the structures, as well as elasticity and plasticity of materials are studied. For calculation of relative simple structures and building of structures’ constitutive relations, analytical approaches were used. For more complex structures, finite element analysis (FEA), which is commonly applied as a numerical method for the analysis of solid structures, was utilized. The general study approach is not necessarily related to characteristic size of model. I believe the scale-independent method described here will pave a new way to understand the mechanical response of a variety of origami and kirigami based structures under given mechanical loading.
ContributorsLv, Cheng (Author) / Jiang, Hanqing (Thesis advisor) / Yu, Hongbin (Committee member) / Wang, Liping (Committee member) / Mignolet, Marc (Committee member) / Hildreth, Owen (Committee member) / Arizona State University (Publisher)
Created2016
Description
The operating temperature of photovoltaic (PV) modules is affected by external factors such as irradiance, wind speed and ambient temperature as well as internal factors like material properties and design properties. These factors can make a difference in the operating temperatures between cells within a module and between modules within a plant. This is a three-part thesis.
Part 1 investigates the behavior of temperature distribution of PV cells within a module through outdoor temperature monitoring under various operating conditions (Pmax, Voc and Isc) and examines deviation in the temperature coefficient values pertaining to this temperature variation. ANOVA, a statistical tool, was used to study the influence of various factors on temperature variation. This study also investigated the thermal non-uniformity affecting I-V parameters and performance of four different PV technologies (crystalline silicon, CdTe, CIGS, a-Si). Two new approaches (black-colored frame and aluminum tape on back-sheet) were implemented in addition to the two previously-used approaches (thermally insulating the frame, and frame and back sheet) to study temperature uniformity improvements within c-Si PV modules on a fixed latitude-tilt array. This thesis concludes that frame thermal insulation and black frame help reducing thermal gradients and next best viable option to improve temperature uniformity measurements is by using average of four thermocouples as per IEC 61853-2 standard.
Part 2 analyzes the temperature data for two power plants (fixed-tilt and one-axis) to study the temperature variation across the cells in a module and across the modules in a power plant. The module placed in the center of one-axis power plant had higher temperature, whereas in fixed-tilt power plant, the module in north-west direction had higher temperatures. Higher average operating temperatures were observed in one-axis tracking as compared to the fixed-tilt PV power plant, thereby expected to lowering their lifetime.
Part 3 focuses on determination of a thermal model coefficients, using parameters similar to Uc and Uv thermal loss factors used in PVsyst, for modules of four different PV technologies experiencing hot-desert climate conditions by statistically correlating a year-long monitored data. Thermal models help to effectively quantity factors influencing module temperatures to estimate performance and energy models.
Part 1 investigates the behavior of temperature distribution of PV cells within a module through outdoor temperature monitoring under various operating conditions (Pmax, Voc and Isc) and examines deviation in the temperature coefficient values pertaining to this temperature variation. ANOVA, a statistical tool, was used to study the influence of various factors on temperature variation. This study also investigated the thermal non-uniformity affecting I-V parameters and performance of four different PV technologies (crystalline silicon, CdTe, CIGS, a-Si). Two new approaches (black-colored frame and aluminum tape on back-sheet) were implemented in addition to the two previously-used approaches (thermally insulating the frame, and frame and back sheet) to study temperature uniformity improvements within c-Si PV modules on a fixed latitude-tilt array. This thesis concludes that frame thermal insulation and black frame help reducing thermal gradients and next best viable option to improve temperature uniformity measurements is by using average of four thermocouples as per IEC 61853-2 standard.
Part 2 analyzes the temperature data for two power plants (fixed-tilt and one-axis) to study the temperature variation across the cells in a module and across the modules in a power plant. The module placed in the center of one-axis power plant had higher temperature, whereas in fixed-tilt power plant, the module in north-west direction had higher temperatures. Higher average operating temperatures were observed in one-axis tracking as compared to the fixed-tilt PV power plant, thereby expected to lowering their lifetime.
Part 3 focuses on determination of a thermal model coefficients, using parameters similar to Uc and Uv thermal loss factors used in PVsyst, for modules of four different PV technologies experiencing hot-desert climate conditions by statistically correlating a year-long monitored data. Thermal models help to effectively quantity factors influencing module temperatures to estimate performance and energy models.
ContributorsPavgi, Ashwini (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Phelan, Patrick (Thesis advisor) / Wang, Liping (Committee member) / Arizona State University (Publisher)
Created2016
Description
Nanoparticle suspensions, popularly termed “nanofluids,” have been extensively investigated for their thermal and radiative properties. Such work has generated great controversy, although it is arguably accepted today that the presence of nanoparticles rarely leads to useful enhancements in either thermal conductivity or convective heat transfer. On the other hand, there are still examples of unanticipated enhancements to some properties, such as the reported specific heat of molten salt-based nanofluids and the critical heat flux. Another largely overlooked example is the apparent effect of nanoparticles on the effective latent heat of vaporization (hfg) of aqueous nanofluids. A previous study focused on molecular dynamics (MD) modeling supplemented with limited experimental data to suggest that hfg increases with increasing nanoparticle concentration.
Here, this research extends that exploratory work in an effort to determine if hfg of aqueous nanofluids can be manipulated, i.e., increased or decreased, by the addition of graphite or silver nanoparticles. Our results to date indicate that hfg can be substantially impacted, by up to ± 30% depending on the type of nanoparticle. Moreover, this dissertation reports further experiments with changing surface area based on volume fraction (0.005% to 2%) and various nanoparticle sizes to investigate the mechanisms for hfg modification in aqueous graphite and silver nanofluids. This research also investigates thermophysical properties, i.e., density and surface tension in aqueous nanofluids to support the experimental results of hfg based on the Clausius - Clapeyron equation. This theoretical investigation agrees well with the experimental results. Furthermore, this research investigates the hfg change of aqueous nanofluids with nanoscale studies in terms of melting of silver nanoparticles and hydrophobic interactions of graphite nanofluid. As a result, the entropy change due to those mechanisms could be a main cause of the changes of hfg in silver and graphite nanofluids.
Finally, applying the latent heat results of graphite and silver nanofluids to an actual solar thermal system to identify enhanced performance with a Rankine cycle is suggested to show that the tunable latent heat of vaporization in nanofluilds could be beneficial for real-world solar thermal applications with improved efficiency.
Here, this research extends that exploratory work in an effort to determine if hfg of aqueous nanofluids can be manipulated, i.e., increased or decreased, by the addition of graphite or silver nanoparticles. Our results to date indicate that hfg can be substantially impacted, by up to ± 30% depending on the type of nanoparticle. Moreover, this dissertation reports further experiments with changing surface area based on volume fraction (0.005% to 2%) and various nanoparticle sizes to investigate the mechanisms for hfg modification in aqueous graphite and silver nanofluids. This research also investigates thermophysical properties, i.e., density and surface tension in aqueous nanofluids to support the experimental results of hfg based on the Clausius - Clapeyron equation. This theoretical investigation agrees well with the experimental results. Furthermore, this research investigates the hfg change of aqueous nanofluids with nanoscale studies in terms of melting of silver nanoparticles and hydrophobic interactions of graphite nanofluid. As a result, the entropy change due to those mechanisms could be a main cause of the changes of hfg in silver and graphite nanofluids.
Finally, applying the latent heat results of graphite and silver nanofluids to an actual solar thermal system to identify enhanced performance with a Rankine cycle is suggested to show that the tunable latent heat of vaporization in nanofluilds could be beneficial for real-world solar thermal applications with improved efficiency.
ContributorsLee, Soochan (Author) / Phelan, Patrick E (Thesis advisor) / Wu, Carole-Jean (Thesis advisor) / Wang, Robert (Committee member) / Wang, Liping (Committee member) / Taylor, Robert A. (Committee member) / Prasher, Ravi (Committee member) / Arizona State University (Publisher)
Created2015