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There are many outstanding questions regarding the petrologic processes that give rise to andesitic and basaltic magmas in subduction zones, including the specifics that govern their geographical distribution in a given arc segment. Here I investigate the genesis of calc-alkaline and tholeiitic basalts from the Lassen Volcanic Center in order to determine the pressure, temperature, source composition, and method of melting that lead to the production of melt in the mantle below Lassen. To this aim, a suite of primitive basalts (i.e. SiO2<52 and Mg#>65) are corrected for fractional crystallization by adding minerals back to the bulk rock composition with the goal of returning them to a primary composition in equilibrium with the mantle. Thermobarometry of the primary melt compositions is conducted to determine temperature and pressure of melting, in addition to a forward mantle modeling technique to simulate mantle melting at varying pressures to constrain source composition and method of melting (batch vs. fractional). The results from the two techniques agree on an average depth of melt extraction of 36 km and a source composition similar to that of depleted mantle melted by batch melting. Although attempted for both calc-alkaline and tholeiitic basalts, the fractional crystallization correction and thus the pressure-temperature calculations were only successful for tholeiitic basalts due to the hydrous nature of the calc-alkaline samples. This leaves an opportunity to repeat this study with parameters appropriate for hydrous basalts, allowing for the comparison of calc-alkaline and tholeiitic melting conditions.
ContributorsSheppard, Katherine Davis (Author) / Till, Christy (Thesis director) / Hervig, Richard (Committee member) / Barrett, The Honors College (Contributor) / School of Earth and Space Exploration (Contributor)
Created2015-05
Description
Though large amounts of nitrogen are allocated to the Earth's mantle, not much is known concerning how it is stored and transported. In this study, stishovite is proposed as a host for nitrogen within the Earth's deep interior. Stishovite was synthesized and heated under nitrogen rich conditions using diamond-anvil cell equipment and double-sided laser heating. Synthesis pressures ranged from 16 to 44 GPa and temperatures centered at ~1800 K. Experimental products were removed from diamond anvil cells and analyzed for nitrogen content via SIMS and SEM/EDX analysis. Unit cell parameters were obtained through XRD analysis. N solubility in stishovite was calculated to be up to 1.54 wt % from SIMS data through the use of an ion implant and a relative sensitivity factor. XRD data indicated a decrease in unit cell volume at higher pressures, with the c-axis length showing larger compressibility than the a-axis length. Through SEM and EDX analysis, a uniformly low level of N was observed throughout the sample indicating that N was uniformly incorporated into the crystal structure of stishovite. The data suggests that, rather than existing separately from stishovite as a silicon or carbon nitride, N has substituted into the crystal structure of stishovite. Both O and N have largely similar atomic radii, with N being slightly smaller, indicating that N can substitute for O. With the levels of N observed in the experiment, it is implicated that the mantle has an extremely large storage capacity for N. Further experimentation, with the addition of TEM analysis, should be conducted in order to determine the effects of pressure and temperature on the solubility of N in stishovite. Additionally, substitution of N as HN into stishovite should be investigated as HN accounts for the charge imbalance seen when substituting N for O.
ContributorsNoble, Shaela Marie (Author) / Shim, Sang-Heon (Thesis director) / Hervig, Richard (Committee member) / School of Life Sciences (Contributor) / School of Molecular Sciences (Contributor) / Barrett, The Honors College (Contributor) / School of Earth and Space Exploration (Contributor)
Created2016-05
Description
Although nitrogen is the dominant element in Earth’s atmosphere, it is depleted in the bulk silicate Earth (relative to expected volatile abundances established by carbonaceous chondrites). To resolve this inconsistency, it has been hypothesized that this “missing nitrogen” may actually be stored within the Earth’s deep interior. In this work, we use multi-anvil press experiments to synthesize solid solution mixtures of the mantle transition zone mineral wadsleyite (Mg2SiO4) and silicon nitride (Si3N4). Successful synthesis of a 90% Si3N4, 10% Mg2SiO4 solid solution implies that nitrogen may not be sequestered within the most abundant mineral phases in the Earth’s mantle. Instead, nitrogen-rich accessory phases may hold the key to studying nitrogen storage within the deep interior. Ultimately, quantifying the amount of nitrogen within the mantle will further our understanding of the N cycle, which is vital to maintaining planetary habitability. Similar N cycling processes may be occurring on other rocky bodies; therefore, studying nitrogen storage may be an important part of determining habitability conditions on other worlds, both within in our solar system and beyond.
ContributorsRavikumar, Shradhanjli (Author) / Shim, Dan (Thesis director) / Sharp, Thomas (Committee member) / Hervig, Richard (Committee member) / Barrett, The Honors College (Contributor) / School of Earth and Space Exploration (Contributor)
Created2023-05
Description
Dissolved organic matter (DOM) can have numerous effects on the water chemistry and the biological life within an aquatic system with its wide variety of chemical structures and properties. The composition of the dissolved carbon can be estimated by utilizing the fluorescent properties of some DOM such as aromatic amino acids and humic material. This experiment was used to observe how organic matter could influence hydrothermal systems, such as Sylvan Springs in Yellowstone National Park, USA. Using optical density at 600 nm (OD 600), excitation-emission matrix spectra (EEMS), and Illumina sequencing methods (16S rRNA gene sequencing), changes in dissolved organic matter (DOM) were observed based on long term incubation at 84ºC and microbial influence. Four media conditions were tested over a two-month duration to assess these changes: inoculated pine needle media, uninoculated pine needle media, inoculated yeast extract media, and uninoculated yeast extract media. The inoculated samples contained microbes from a fluid and sediment sample of Sylvan Spring collected July 23, 2018. Absorbance indicated that media containing pine needle broth poorly support life, whereas media containing yeast extract revealed a positive increase in growth. Excitation-Emission Matrix Spectra of the all media conditions indicated changes in DOM composition throughout the trial. There were limited differences between the inoculated and uninoculated samples suggesting that the DOM composition change in this study was dominated by the two-month incubation at 84ºC more than biotic processes. Sequencing performed on a sediment sample collected from Sylvan Spring indicated five main order of prokaryotic phyla: Aquificales, Desulfurococcales, Thermoproteales, Thermodesulfobacteriales, and Crenarchaeota. These organisms are not regarded as heterotrophic microbes, so the lack of significant biotic changes in DOM could be a result of these microorganisms not being able to utilize these enrichments as their main metabolic energy supply.
ContributorsKnott, Nicholas Joseph (Author) / Shock, Everett (Thesis director) / Hartnett, Hilairy (Committee member) / Till, Christy (Committee member) / School of Molecular Sciences (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
Description
This project focuses on using Neutral Gas and Ion Mass Spectrometer (NGIMS) density data for carbon dioxide, oxygen, carbon monoxide, and nitrogen during deep dip campaigns 5, 6, and 8. Density profiles obtained from NGIMS were plotted against simulated density profiles from the Mars Global Ionosphere-Thermosphere Model (MGITM). Averaged temperature profiles were also plotted for the three deep dip campaigns, using NGIMS data and MGITM output. MGITM was also used as a tool to uncover potential heat balance terms needed to reproduce the mean density and temperature profiles measured by NGIMS.
This method of using NGIMS data as a validation tool for MGITM simulations has been tested previously using dayside data from deep dip campaigns 2 and 8. In those cases, MGITM was able to accurately reproduce the measured density and temperature profiles; however, in the deep dip 5 and 6 campaigns, the results are not quite the same, due to the highly variable nature of the nightside thermosphere. MGITM was able to fairly accurately reproduce the density and temperature profiles for deep dip 5, but the deep dip 6 model output showed unexpected significant variation. The deep dip 6 results reveal possible changes to be made to MGITM to more accurately reflect the observed structure of the nighttime thermosphere. In particular, upgrading the model to incorporate a suitable gravity wave parameterization should better capture the role of global winds in maintaining the nighttime thermospheric structure.
This project reveals that there still exist many unknowns about the structure and dynamics of the night side of the Martian atmosphere, as well as significant diurnal variations in density. Further study is needed to uncover these unknowns and their role in atmospheric mass loss.
This method of using NGIMS data as a validation tool for MGITM simulations has been tested previously using dayside data from deep dip campaigns 2 and 8. In those cases, MGITM was able to accurately reproduce the measured density and temperature profiles; however, in the deep dip 5 and 6 campaigns, the results are not quite the same, due to the highly variable nature of the nightside thermosphere. MGITM was able to fairly accurately reproduce the density and temperature profiles for deep dip 5, but the deep dip 6 model output showed unexpected significant variation. The deep dip 6 results reveal possible changes to be made to MGITM to more accurately reflect the observed structure of the nighttime thermosphere. In particular, upgrading the model to incorporate a suitable gravity wave parameterization should better capture the role of global winds in maintaining the nighttime thermospheric structure.
This project reveals that there still exist many unknowns about the structure and dynamics of the night side of the Martian atmosphere, as well as significant diurnal variations in density. Further study is needed to uncover these unknowns and their role in atmospheric mass loss.
ContributorsRobinson, Jenna (Author) / Desch, Steven (Thesis director) / Hervig, Richard (Committee member) / School of Earth and Space Exploration (Contributor) / School for the Future of Innovation in Society (Contributor) / School of International Letters and Cultures (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05