Urban green space is purported to offset greenhouse‐gas (GHG) emissions, remove air and water pollutants, cool local climate, and improve public health. To use these services, municipalities have focused efforts on designing and implementing ecosystem‐services‐based “green infrastructure” in urban environments. In some cases the environmental benefits of this infrastructure have been well documented, but they are often unclear, unquantified, and/or outweighed by potential costs. Quantifying biogeochemical processes in urban green infrastructure can improve our understanding of urban ecosystem services and disservices (negative or unintended consequences) resulting from designed urban green spaces. Here we propose a framework to integrate biogeochemical processes into designing, implementing, and evaluating the net effectiveness of green infrastructure, and provide examples for GHG mitigation, stormwater runoff mitigation, and improvements in air quality and health.

The leading source of weather-related deaths in the United States is heat, and future projections show that the frequency, duration, and intensity of heat events will increase in the Southwest. Presently, there is a dearth of knowledge about how infrastructure may perform during heat waves or could contribute to social vulnerability. To understand how buildings perform in heat and potentially stress people, indoor air temperature changes when air conditioning is inaccessible are modeled for building archetypes in Los Angeles, California, and Phoenix, Arizona, when air conditioning is inaccessible is estimated.

An energy simulation model is used to estimate how quickly indoor air temperature changes when building archetypes are exposed to extreme heat. Building age and geometry (which together determine the building envelope material composition) are found to be the strongest indicators of thermal envelope performance. Older neighborhoods in Los Angeles and Phoenix (often more centrally located in the metropolitan areas) are found to contain the buildings whose interiors warm the fastest, raising particular concern because these regions are also forecast to experience temperature increases. To combat infrastructure vulnerability and provide heat refuge for residents, incentives should be adopted to strategically retrofit buildings where both socially vulnerable populations reside and increasing temperatures are forecast.

This study assessed the spatial distribution of vulnerability to extreme heat in 1990 and 2000 within metropolitan Phoenix based on an index of seven equally weighted measures of physical exposure and adaptive capacity. These measures were derived from spatially interpolated climate, normalized differential vegetation index, and U.S. Census data. From resulting vulnerability maps, we also analyzed population groups living in areas of high heat vulnerability. Results revealed that landscapes of heat vulnerability changed substantially in response to variations in physical and socioeconomic factors, with significant alterations to spatial distribution of vulnerability especially between eastern and western sectors of Phoenix. These changes worked to the detriment of Phoenix's Hispanic population and the elderly concentrated in urban-fringe retirement communities.