This research is a comprehensive study of the sustainable modifiers for asphalt binder. It is a common practice to use modifiers to impart certain properties to asphalt binder; however, in order to facilitate the synthesis and design of highly effective sustainable modifiers, it is critical to thoroughly understand their underlying molecular level mechanisms in combination with micro and macro-level behavior. Therefore, this study incorporates a multi-scale approach using computational modeling and laboratory experiments to provide an in-depth understanding of the mechanisms of interaction between selected modifiers and the constituents of asphalt binder, at aged and unaged conditions. This study investigated the effect of paraffinic wax as a modifier for virgin binder in warm-mix asphalt that can reduce the environmental burden of asphalt pavements. The addition of wax was shown to reduce the viscosity of bitumen by reducing the self-interaction of asphaltene molecules and penetrating the existing nano agglomerates of asphaltenes. This study further examined how the interplay of various modifiers affects the modified binder’s thermomechanical properties. It was found that the presence of wax-based modifiers has a disrupting effect on the role of polyphosphoric acid that is another modifier of bitumen and its interactions with resin-type molecules.
This study was further extended to using nanozeolite as a mineral carrier for wax to better disperse wax in bitumen and reduce the wax's adverse effects such as physical hardening at low service temperatures and rutting at high service temperatures. This novel technique showed that using a different method of adding a modifier can help reduce the modifier's unwanted effects. It further showed that nanozeolite could carry wax-based modifiers and release them in bitumen, then acting as a scavenger for acidic compounds in the binder. This, in turn, could promote the resistance of asphalt binder to moisture damage by reducing the quantity of acidic compounds at the interface between the binder and the stone aggregates.
Furthermore, this study shows that iso-paraffin wax can reduce oxidized asphaltene molecules self-interaction and therefore, reduce the viscosity of aged bitumen while cause brittleness at low temperatures.
Additionally, a cradle to gate life-cycle assessment was performed for a new bio-modifier obtained from swine manure. This study showed that by partially replacing the bitumen with bio-binder from swine manure, the carbon footprint of the binder can be reduced by 10% in conjunction with reducing the cost and environmental impact of storing the manure in lagoons.
This PhD research examines the integration of DSM strategies in existing residential and commercial buildings in the Phoenix, Arizona metropolitan area, a hot-arid climate. The author proposes three different case studies to evaluate the effectiveness of one DSM strategy in buildings, namely the integration of Phase Change Materials (PCMs). PCMs store energy in the freezing process and use that stored energy in the melting process to reduce the energy demand. The goal of these case studies is to analyze the potential of each strategy to reduce peak load and overall energy consumption in existing buildings.
First, this dissertation discusses the efficacy of coupling PCMs with precooling strategies in residential buildings to reduce peak demand. The author took a case study approach and simulated two precooling strategies, with and without PCM integration, in two sample single-family homes to assess the impact of the DSM strategies (i.e., precooling and PCM integration) on load shifting and load shedding in each home.
Second, this research addresses the feasibility of using PCMs as sensible and latent heat storage in commercial buildings. The author documents the process of choosing buildings for PCM installation, as well as the selection of PCMs for retrofitting purposes. Commercial building case studies compare experimental and simulation results, focusing on the impact of the PCMs on reducing the total annual energy demand and energy cost.
Finally, this research proposes a novel process for selecting PCMs as energy efficiency measures for building retrofits. This process facilitates the selection of a building and PCM that are complementary. Implementation of this process has not yet been tested; however, the process was developed based on experimental and simulation results from prior studies, and it would alleviate many of the PCM performance issues documented in those studies.