Matching Items (162)
Description
Solid-state lithium-ion batteries are a major area of research due to their increased safety characteristics over conventional liquid electrolyte batteries. Lithium lanthanum zirconate (LLZO) is a promising garnet-type ceramic for use as a solid-state electrolyte due to its high ionic conductivity. The material exists in two dierent phases, one that is cubic in structure and one that is tetragonal. One potential synthesis method that results in LLZO in the more useful, cubic phase, is electrospinning, where a mat of nanowires is spun and then calcined into LLZO. A phase containing lanthanum zirconate (LZO) and amorphous lithium occursas an intermediate during the calcination process. LZO has been shown to be a sintering aid for LLZO, allowing for lower sintering temperatures. Here it is shown the eects of internal LZO on the sintered pellets. This is done by varying the 700C calcination time to transform diering amounts of LZO and LLZO in electrospun nanowires, and then using the same sintering parameters for each sample. X-ray diraction was used to get structural and compositional analysis of both the calcined powders and sintered pellets. Pellets formed from wires calcined at 1 hour or longer contained only LLZO even if the calcined powder had only undergone the rst phase transformation. The relative density of the pellet with no initial LLZO of 61.0% was higher than that of the pellet with no LZO, which had a relative density of 57.7%. This allows for the same, or slightly higher, quality material to be synthesized with a shorter amount of processing time.
ContributorsLondon, Nathan Harry (Author) / Chan, Candace (Thesis director) / Tongay, Sefaattin (Committee member) / Department of Physics (Contributor) / Materials Science and Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2017-05
Description
Photovoltaic panels are commonly used for their versatility in on-site generation of clean electricity in urban environments, specifically on rooftops. However, their implementation on rooftops poses potential (positive and negative) impacts on the energy use of buildings, and urban climates. The negative impacts are compounded if PV is installed on top of a high-albedo rooftop. This study quantitively investigates these impacts from PV installation on top of a building with a white roof in Phoenix, AZ. We supplemented our measurements with EnergyPlus simulations to model the energy implications for archetypical residential and retail buildings and calculated the energy penalty to generation ratio as well as sensible heat flux for each combination of panel height and building type. Results indicate that the daily cooling energy penalty to due blockage of outgoing longwave radiation can be 4.9—11.2% of the PV generation. In addition, while we observed a small decrease in nighttime sensible heat flux to the ambient, PV cases increased the daytime heat flux by more than a factor of 10. This study highlights the potential unintended consequences of rooftop PV under certain conditions and provides a broader perspective for building designers and urban planners.
ContributorsBrown, Kyle (Author) / Sailor, David (Thesis director) / Phelan, Patrick (Committee member) / Department of Physics (Contributor) / Dean, W.P. Carey School of Business (Contributor) / School of Sustainability (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
Description
The Epoch of Reionization (EoR) is the period in the evolution of the universe during which neutral hydrogen was ionized by the first luminous sources, and is closely linked to the formation of structure in the early universe. The Hydrogen Epoch of Reionization Array (HERA) is a radio interferometer currently under construction in South Africa designed to study this era. Specifically, HERA is dedicated to studying the large-scale structure during the EoR and the preceding Cosmic Dawn by measuring the redshifted 21-cm line from neutral hydrogen. However, the 21-cm signal from the EoR is extremely faint relative to galactic and extragalactic radio foregrounds, and instrumental and environmental systematics make measuring the signal all the more difficult. Radio frequency interference (RFI) from terrestrial sources is one such systematic. In this thesis, we explore various methods of removing RFI from early science-grade HERA data and characterize the effects of different removal patterns on the final 21-cm power spectrum. In particular, we focus on the impact of masking narrowband signals, such as those characteristic of FM radio and aircraft or satellite communications, in the context of the algorithms currently used by the HERA collaboration for analysis.
ContributorsWhitler, Lily (Author) / Jacobs, Daniel (Thesis director) / Bowman, Judd (Committee member) / Beardsley, Adam (Committee member) / School of Mathematical and Statistical Sciences (Contributor) / Department of Physics (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
Description
This past summer, Pew Research Center conducted a ten-question survey to test Americans' knowledge on current events. Questions ranged from how Zika virus is transmitted, to the name of the current president of France. A majority of the participants were unable to answer half of the questions correctly (Pew Research Center, 2017). While previous Pew knowledge surveys saw a majority of Americans answer only one quarter of the questions correctly (2014), it is clear that Americans today are still not completely up-to-date on current affairs. Along with Americans lacking knowledge of current affairs, the recent election saw the rise in accusations of "fake news." These calls inspired me to undertake my thesis project to try to answer the question: "does fake news actually impact the public's policy preferences, and if so, by how much?" While studies have been conducted to test the relationship between policy misperceptions and policy preferences, there have not been many studies released to directly test the impact of incorrect information on policy preferences. The underlying purpose of this study is to test how introduction of new information, particularly falsehoods, influences policy preferences. Specifically, I focus on policy preferences related to anthropogenic climate change . Any valid research that seeks to analyze the effect of political information on policy preferences needs to starts by discovering how much the public knows about the particular policy issue that the researcher is focusing on. Without explicitly saying as much, all of the research on the subject that I have read has come to the same conclusion: American's are indeed politically unaware on a wide array of issues. The areas of policy that Americans lack knowledge on are widespread: education (Howell and West, 2009), welfare (Gilens, 2001), the war in Iraq (Berinsky, 2007; Kull, 2003), and facts about political candidates (Nyhan and Reifler, 2012) are just some of the issues that Americans seem to know little about. Literature discussed in the following section shows how researchers have tried to understand how policy knowledge impacts policy opinions. Researchers primarily collected their data either one of two ways: by analyzing existing survey data or by conducting their own survey.
ContributorsRoth, Benjamin (Author) / Woodall, Gina (Thesis director) / Feary, David (Committee member) / School of Politics and Global Studies (Contributor) / Department of Physics (Contributor) / Barrett, The Honors College (Contributor)
Created2018-05
Description
A search is underway to find baryon resonances that have been predicted, but yet remain unobserved. Nucleon resonances, due to their broad energy widths, overlap and must be disentangled in order to be identified. Meson photoproduction observables related to the orientation of the spin of the incoming photon and the spin of the target proton are useful tools to deconvolve the nucleon resonance spectrum. These observables are particularly sensitive to interference between phases of the complex amplitudes. A set of these observables has been measured using the CEBAF Large Acceptance Spectrometer (CLAS) at Jefferson Lab with linearly-polarized photons having energies from 725 to 1575 MeV with polar angle values of cos(theta) between -0.8 and 0.9 and transversely-polarized protons in the Jefferson Lab FRozen Spin Target (FROST). By fitting neutron yields from gamma p -> pi^+ n over azimuthal scattering angle, the observables \H and P have been extracted. These observables manifest as azimuthal modulations in the yields for the double-polarization experiment. Preliminary results for these observables will be presented and compared with predictions provided by the SAID Partial-Wave Analysis Facility.
ContributorsLee, Robert John (Author) / Dugger, Michael (Thesis director) / Ritchie, Barry (Committee member) / Department of Physics (Contributor) / Barrett, The Honors College (Contributor)
Created2018-05
Description
Error-correcting codes are fundamental in modern digital communication with applications in data storage and data transmission. Interest in a class of error-correcting codes called low-density parity-check (LDPC) codes has been growing since their recent rediscovery because of their low decoding complexity and their high-performance. However, practical applications have been limited due to the difficulty of finding good LDPC codes for practical parameters. This paper proposes an exhaustive and a randomized algorithm for constructing a family of LDPC codes with practical parameters whose matrix representations meet the following requirements: for each row in the LDPC code matrix there exists exactly one common nonzero element, each row has a minimum weight of one and must be odd, and each column has a weight of at least two. These conditions improve performance of the resulting codes and simplify conversion into codes for quantum systems. Both algorithms utilize a maximal clique algorithm to construct LDPC matrices from graphs whose vertices are possible rows within said matrices and are adjacent the first condition is true. While these algorithms were found to be suitable for small parameters, future work which optimizes the resulting codes for their expected applications could also dramatically increase performance of the algorithms themselves.
ContributorsShurman, Andrew Christian (Author) / Colbourn, Charles (Thesis director) / Bazzi, Rida (Committee member) / Computer Science and Engineering Program (Contributor) / Department of Physics (Contributor) / Barrett, The Honors College (Contributor)
Created2018-12
Description
X-ray Free Electron Lasers (XFELs) are used for diffractive x-ray imaging of the structure of many biological particles, such as viruses and proteins. The ultimate goal for XFEL-based microscopy is atomic resolution images of non-crystalline particles. However, data collection efficiency as well as the limited amount of measurement time given annually to researchers, such high-resolution images are presently impossible to attain. Here, we consider two potential solutions to the single-particle hit rate problem; the first looks at applying static electric fields to existing aerodynamic particle injectors, and the second looks at the viability of using time-varying electric fields associated with ion traps to create high-density regions of particles. For the static solution, we looked at applying a constant electric potential to the nozzle, as well as applying a high voltage to a ring electrode in close proximity to a grounded nozzle. We considered the breakdown field strength of the helium gas used to determine how closely the ring electrode could be placed without creating an arc that could potentially destroy expensive equipment. Then, we considered the possibility of using electrodynamic ion traps to increase particle densities. We first characterized how charged particles behave in oscillating electric fields using a simple electrode geometry. Using the general results from this, we then constructed a rudimentary ion trap to test if our experiment agreed with the theory. Finally, we conducted a literature review to determine what particle densities other scientists have been able to measure using ion traps. We then compared existing ion traps to what we expect from the nozzle injectors to determine which method may be the better solution.
ContributorsBradshaw, Layne Nicholas (Author) / Kirian, Richard (Thesis director) / Weierstall, Uwe (Committee member) / Department of Physics (Contributor, Contributor) / School of Earth and Space Exploration (Contributor) / Barrett, The Honors College (Contributor)
Created2017-05
Description
Within the context of the Finite-Difference Time-Domain (FDTD) method of simulating interactions between electromagnetic waves and matter, we adapt a known absorbing boundary condition, the Convolutional Perfectly-Matched Layer (CPML) to a background of Drude-dispersive medium. The purpose of this CPML is to terminate the virtual grid of scattering simulations by absorbing all outgoing radiation. In this thesis, we exposit the method of simulation, establish the Perfectly-Matched Layer as a domain which houses a spatial-coordinate transform to the complex plane, construct the CPML in vacuum, adapt the CPML to the Drude medium, and conclude with tests of the adapted CPML for two different scattering geometries.
ContributorsThornton, Brandon Maverick (Author) / Sukharev, Maxim (Thesis director) / Goodnick, Stephen (Committee member) / School of Mathematical and Statistical Sciences (Contributor) / Department of Physics (Contributor) / Barrett, The Honors College (Contributor)
Created2018-05
Description
Proteins continually and naturally incur evolutionary selection through mutagenesis that optimizes their fitness, which is primarily determined by their function. It is known that allosteric regulation alters a protein's conformational dynamics leading to functional changes. We have computationally introduced a mutation at a predicted regulatory site of a short, 46 residue-long, protein interaction module composed of a WW domain and corresponding polyproline ligand (PDB id: 1k9r). The dynamic flexibility index (DFI) was computed for the binding site of the wild type and mutant WW domains to quantify the mutations effect on the rigidity of the binding pocket. DFI is used as a metric to quantify the resilience of a given position to perturbation along the chain. Using steered molecular dynamics (SMD), we also measure the effect of the point mutation on allosteric regulation by approximating the binding free energy of the system calculated using Jarzynski's Equality. Calculation of the DFI shows that the overall flexibility of the protein complex increases as a result of the distal point mutation. Total change in DFI percentile of the binding site showed a 0.067 increase suggesting an allosteric, loss of function mutation. Furthermore, we see that the change in the binding free energy is greater for that of the mutated complex supporting the idea that an increase in flexibility is correlated to a decrease in proteinlig and binding affinity. We show that sequence mutation of an allosteric site affects the mechanical stability and functionality of the binding pocket.
ContributorsMarianchuk, Tegan (Author) / Ozkan, Sefika (Thesis director) / Ros, Robert (Committee member) / Barrett, The Honors College (Contributor) / Department of Physics (Contributor)
Created2018-05
Description
This study explores the significant roles and responsibilities of Arizona physics teachers as well as the effect that these teachers have on students and thus their futures. In a two-fold survey administered to all 194 public comprehensive high school physics teachers with 60% participation, questions regarding the perception and expectations that physics teachers hold for themselves, students, and school counselors are addressed as well as the corresponding practices. This survey reveals that generally, teachers feel that students have preconceptions about what physics is and what the course requires, and yet approximately half of the teachers do not make significant recruitment efforts. It is pertinent to ask why physics has one of the lowest enrollment statuses out of all the sciences in high school. Even more so, it is crucial to ask why there is a teacher shortage in the subject of physics. In exploring these questions, results to the previously mentioned genres of questions will speak to the issues at hand and are intended to give a robust explanation as to why physics is fading away in Arizona.
ContributorsGagliardi, Toni (Author) / Jackson, Jane (Thesis director) / Culbertson, Robert (Committee member) / Department of Physics (Contributor) / Barrett, The Honors College (Contributor)
Created2018-05