Matching Items (215)
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Description
In this investigation, copper slag was used as a coarse aggregate in four different mixes of concrete, consisting of 0%, 25%, 50%, and 100% copper slag by volume. Locally available Salt river aggregate was used as a control, and mixes were tested for density, strength, thermal conductivity, specific heat capacity,

In this investigation, copper slag was used as a coarse aggregate in four different mixes of concrete, consisting of 0%, 25%, 50%, and 100% copper slag by volume. Locally available Salt river aggregate was used as a control, and mixes were tested for density, strength, thermal conductivity, specific heat capacity, and thermal diffusivity. Density was shown to increase with increasing copper slag content, increasing an average of 2298 kg/m^3, 2522 kg/m^3, and 2652 kg/m^3 in the 25%, 50%, and 100% mixes. This represents a 15% increase in density from 0% to 100%. Compressive strength testing indicated that the presence of copper slag in concrete provides no definitive strength benefit over Salt River aggregate. This result was expected, as concrete's strength is primarily derived from the cement matrix and not the aggregate. Thermal conductivity showed a decreasing trend with increasing copper slag content. Th control mix had an average conductivity of 0.660 W/m*K, and the 25%, 50%, and 100% mixes had conductivities of 0.649 W/m*K, 0.647 W/m*K, and 0.519 W/m*K, respectively. This represents 21% drop in thermal conductivity over the control. This result was also expected, as materials formed at higher temperatures, like copper slag, tend to have lower thermal conductivities. Specific heat capacity testing yielded results that were statistically indeterminate, though unlike strength testing this arose from inaccurate assumptions made during testing. This also prevented accurate thermal diffusivity results, as diffusivity is a function of density, thermal conductivity, and specific heat capacity. However, given the trends of the first two parameters, it is plausible to say that diffusivity in copper slag concrete would be lower than that of the control ix. All of these results were plugged into ASU's Pavement Temperature Model to see what effect they had in mitigating the UHI effect.
ContributorsLaughlin, Colin (Author) / Kaloush, Kamil (Thesis director) / Phelan, Patrick (Committee member) / Witczak, Kenneth (Committee member) / Barrett, The Honors College (Contributor)
Created2012-05
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Description
The two central goals of this project were 1) to develop a testing method utilizing coatings on ultra-thin stainless steel to measure the thermal conductivity (k) of battery electrode materials and composites, and 2) to measure and compare the thermal conductivities of lithium iron phosphate (LiFePO4, "LFP") in industry-standard graphite/LFP

The two central goals of this project were 1) to develop a testing method utilizing coatings on ultra-thin stainless steel to measure the thermal conductivity (k) of battery electrode materials and composites, and 2) to measure and compare the thermal conductivities of lithium iron phosphate (LiFePO4, "LFP") in industry-standard graphite/LFP mixtures as well as graphene/LFP mixtures and a synthesized graphene/LFP nanocomposite. Graphene synthesis was attempted before purchasing graphene materials, and further exploration of graphene synthesis is recommended due to limitations in purchased product quality. While it was determined after extensive experimentation that the graphene/LFP nanocomposite could not be successfully synthesized according to current literature information, a mixed composite of graphene/LFP was successfully tested and found to have k = 0.23 W/m*K. This result provides a starting point for further thermal testing method development and k optimization in Li-ion battery electrode nanocomposites.
ContributorsStehlik, Daniel Wesley (Author) / Chan, Candace K. (Thesis director) / Dai, Lenore (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor)
Created2014-05
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Description
Recently, a number of publications have suggested that ionic liquids (ILs) can absorb solid particles. This development may have implications in fields like oil sand processing, oil spill beach cleanup, and water treatment. In this Honors Thesis, computational investigation of this phenomenon is provided via molecular dynamics simulations. Two particle

Recently, a number of publications have suggested that ionic liquids (ILs) can absorb solid particles. This development may have implications in fields like oil sand processing, oil spill beach cleanup, and water treatment. In this Honors Thesis, computational investigation of this phenomenon is provided via molecular dynamics simulations. Two particle surface chemistries were investigated: (1) hydrocarbon-saturated and (2) silanol-saturated, representing hydrophobic and hydrophilic particles, respectively. Employing 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM]-[PF6]) as a model IL, these nanoparticles were allowed to equilibrate at the IL/water and IL/hexane interfaces to observe the interfacial self-assembled structures. At the IL/water interface, the hydrocarbon-based nanoparticles were nearly completely absorbed by the IL, while the silica nanoparticles maintained equal volume in both phases. At the IL/hexane interface, the hydrocarbon nanoparticles maintained minimal interactions with the IL, whereas the silica nanoparticles were nearly completely absorbed by it. Studies of these two types of nanoparticles immersed in the bulk IL indicate that the surface chemistry has a great effect on the corresponding IL liquid structure. These effects include layering of the ions, hydrogen bonding, and irreversible absorption of some ions to the silica nanoparticle surface. These effects are quantified with respect to each nanoparticle. The results suggest that ILs likely exhibit this absorption capability because they can form solvation layers with reduced dynamics around the nanoparticles.
ContributorsMachas, Michael Stafford (Author) / Dai, Lenore (Thesis director) / Lind, Mary Laura (Committee member) / Frost, Denzil (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor)
Created2013-05
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Description
"The Wedding Dress" is a creative project investigating the history of wedding dress design that led to the design and construction of a wedding dress with historical inspiration. The project details the process of creating the wedding dress, in addition to the historical study of wedding dresses, and the designer/author's

"The Wedding Dress" is a creative project investigating the history of wedding dress design that led to the design and construction of a wedding dress with historical inspiration. The project details the process of creating the wedding dress, in addition to the historical study of wedding dresses, and the designer/author's inspiration.
ContributorsAlbasha, Heba (Author) / Facinelli, Diane (Thesis director) / Dai, Lenore (Committee member) / Raad, Nada (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor)
Created2013-05
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Description
This project is part of a larger project involving making membranes for the separation of potable water from urine solutions for applications in space travel. This project deals specifically with testing LTA nanozeolites that will be used in the membrane under a variety of acidic conditions, specifically in solutions of

This project is part of a larger project involving making membranes for the separation of potable water from urine solutions for applications in space travel. This project deals specifically with testing LTA nanozeolites that will be used in the membrane under a variety of acidic conditions, specifically in solutions of sulfuric acid, chromium trioxide, and potassium phosphate of pHs ranging from .5 to 5, in order to investigate the effects of pH, acid type, and time. They were analyzed using SEM, FTIR, and XRD, in order to analyze how much the zeolite was degraded under the conditions of each solution. It was determined that, for high pH values (4-5), potassium phosphate had the strongest effect, as it degraded the zeolite to the point of destroying the crystal structure completely. Because of the solubility limit of potassium phosphate in water, it could not be analyzed at low pH, so only sulfuric acid and chromium trioxide were analyzed at low pH (.5-3). They both had severe effects, sulfuric acid being slightly more severe, with both of them completely dissolving the zeolite at pH values of 1 and lower. Decreasing pH increased degradation for all of the acids, with pH values above 2 for sulfuric acid and chromium trioxide showing only minor degradation, and pH 5 potassium phosphate showing only minor degradation.
ContributorsWaller, Aaron Christopher (Author) / Lind, Mary Laura (Thesis director) / Dai, Lenore (Committee member) / Lin, Jerry (Committee member) / Barrett, The Honors College (Contributor)
Created2013-05
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Description
Asymmetric polystyrene-gold composite particles are successfully synthesized alongside core-shell composite particles via a one-step Pickering emulsion polymerization method. Unlike core-shell particles which form in the droplet phase of a stabilized Pickering emulsion, asymmetric particles form via a seeded growth mechanism. These composite particles act as catalysts with higher recyclability than

Asymmetric polystyrene-gold composite particles are successfully synthesized alongside core-shell composite particles via a one-step Pickering emulsion polymerization method. Unlike core-shell particles which form in the droplet phase of a stabilized Pickering emulsion, asymmetric particles form via a seeded growth mechanism. These composite particles act as catalysts with higher recyclability than pure gold nanoparticles due to reduced agglomeration. With the addition of N-isopropylacrylamide (NIPAAM) monomers, temperature-responsive asymmetric and core-shell polystyrene/poly(N-isopropylacrylamide)-gold composite particles are also synthesized via Pickering emulsion polymerization. The asymmetric particles have a greater thermo-responsiveness than the core-shell particles due to the increased presence of NIPAAM monomers in the seeded-growth formation. Poly(N-isopropylacrylamide) (PNIPAM)-containing asymmetric particles have tunable rheological and optical properties due to their significant size decrease above the lower critical solution temperature (LCST).
ContributorsRabiah, Noelle Ibrahim (Author) / Dai, Lenore (Thesis director) / Torres, Cesar (Committee member) / Zhang, Mingmeng (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor)
Created2014-05
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Description
It is the intent of this research to determine the feasibility of utilizing industrial byproducts in cementitious systems in lieu of Portland Cement to reduce global CO2 emissions. Class C and Class F Fly Ash (CFA and FFA, respectively) derived from industrial coal combustion were selected as the replacement materials

It is the intent of this research to determine the feasibility of utilizing industrial byproducts in cementitious systems in lieu of Portland Cement to reduce global CO2 emissions. Class C and Class F Fly Ash (CFA and FFA, respectively) derived from industrial coal combustion were selected as the replacement materials for this study. Sodium sulfate and calcium oxide were used as activators. In Part 1 of this study, focus was placed on high volume replacement of OPC using sodium sulfate as the activator. Despite improvements in heat generation for both CFA and FFA systems in the presence of sulfate, sodium sulfate was found to have adverse effects on the compressive strength of CFA mortars. In the CFA mixes, strength improved significantly with sulfate addition, but began to decrease in strength around 14 days due to expansive ettringite formation. Conversely, the addition of sulfate led to improved strength for FFA mixes such that the 28 day strength was comparable to that of the CFA mixes with no observable strength loss. Maximum compressive strengths achieved for the high volume replacement mixes was around 40 MPa, which is considerably lower than the baseline OPC mix used for comparison. In Part 2 of the study, temperature dependency and calcium oxide addition were studied for sodium sulfate activated systems composed of 100% Class F fly ash. In the presence of sulfate, added calcium increased reactivity and compressive strength at early ages, particularly at elevated temperatures. It is believed that sulfate and calcium react with alumina from fly ash to form ettringite, while heat overcomes the activation energy barrier of fly ash. The greatest strengths were obtained for mixes containing the maximum allowed quantity of calcium oxide (5%) and sodium sulfate (3%), and were around 12 MPa. This is a very low compressive strength relative to OPC and would therefore be an inadequate substitute for OPC needs.
Created2014-05
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Description
The civil engineering curriculum includes the engineering fields of environmental, geotechnical, hydrology, structural, and transportation. A particular focus on the structural engineering curriculum outline involves courses in mathematics, engineering mechanics, structural analysis, and structural design. The core structural analysis and design course at Arizona State University (CEE 321) is a

The civil engineering curriculum includes the engineering fields of environmental, geotechnical, hydrology, structural, and transportation. A particular focus on the structural engineering curriculum outline involves courses in mathematics, engineering mechanics, structural analysis, and structural design. The core structural analysis and design course at Arizona State University (CEE 321) is a transition course to connect realistic structural design and analysis concepts to an engineering foundation created by the first and second year mathematics and mechanics courses. CEE 321 is styled after a flipped classroom model and students are assessed through quizzes, midterms, design projects, and a final exam. Student performance was evaluated for the Spring 2013 and Fall 2013 semesters through an error analysis technique designed to categorize student mistakes based on type of error and related topic. This analysis revealed that student's basic engineering mechanics skills improved throughout the course as well as identified the areas that students struggle in. The slope-deflection and direct stiffness methods of analysis and calculating cross-sectional properties are the primary areas of concern. Using appropriate technology in the engineering classroom has the potential to enhance the learning environment and address the areas of inadequacy identified by the performance analysis. A survey of CEE 321 students demonstrated that technology is a highly integrated and useful portion of student's lives. Therefore, the engineering classroom should reflect this. Through the use of analysis and design software, students are able to begin to develop design intuition and understanding while completing realistic engineering projects in their third year of undergraduate studies. Additionally, incorporating internet resources into and outside of the classroom allows students to be connected to course content from any web-enabled device of their choice. Lecture videos posted online covering the course content were requested by many CEE 321 students and are an emerging resource that supplements the flipped classroom model. The availability of such a tool allows students to revisit concepts that they do not understand or pause, rewind, and replay the lectures when necessary. An expansion of the structural analysis and design online lecture videos for CEE 321 are expected to address and improve the areas that students struggle in as identified by the error analysis.
ContributorsMika, Krista Nicole (Author) / Rajan, Subramaniam (Thesis director) / Mamlouk, Michael (Committee member) / Civil, Environmental and Sustainable Engineering Programs (Contributor) / Barrett, The Honors College (Contributor)
Created2013-12
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Rapid urbanization of the planet is occurring at an unprecedented pace, primarily in arid and semi-arid hot climates [Golden, J.S., 2004. The built environment induced urban heat island effect in rapidly urbanizing arid regions – a sustainable urban engineering complexity. Environ. Sci. J. Integr. Environ. Res. 1 (4), 321–349]. This

Rapid urbanization of the planet is occurring at an unprecedented pace, primarily in arid and semi-arid hot climates [Golden, J.S., 2004. The built environment induced urban heat island effect in rapidly urbanizing arid regions – a sustainable urban engineering complexity. Environ. Sci. J. Integr. Environ. Res. 1 (4), 321–349]. This growth has manifested itself as a cause of various impacts including elevated urban temperatures in comparison to rural sites known as the Urban Heat Island (UHI) effect [Oke, T.R., 1982. The energetic basis of the urban heat island. Q. J. R. Meteor. Soc. 108, 1–24]. Related are the increased demands for electric power as a result of population growth and increased need for mechanical cooling due to the UHI. In the United States, the Environmental Protection Agency has developed a three-prong approach of (1) cool pavements, (2) urban forestry and (3) cool roofs to mitigate the UHI. Researchers undertook an examination of micro scale benefits of the utilization of photovoltaic panels to reduce the thermal impacts to surface temperatures of pavements in comparison to urban forestry. The results of the research indicate that photovoltaic panels provide a greater thermal reduction benefit during the diurnal cycle in comparison to urban forestry while also providing the additional benefits of supporting peak energy demand, conserving water resources and utilizing a renewable energy source.

ContributorsGolden, Jay S. (Author) / Carlson, Joby (Author) / Kaloush, Kamil (Author) / Phelan, Patrick (Author)
Created2006-12-26
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Engineered pavements cover a large fraction of cities and offer significant potential for urban heat island mitigation. Though rapidly increasing research efforts have been devoted to the study of pavement materials, thermal interactions between buildings and the ambient environment are mostly neglected. In this study, numerical models featuring a realistic

Engineered pavements cover a large fraction of cities and offer significant potential for urban heat island mitigation. Though rapidly increasing research efforts have been devoted to the study of pavement materials, thermal interactions between buildings and the ambient environment are mostly neglected. In this study, numerical models featuring a realistic representation of building-environment thermal interactions, were applied to quantify the effect of pavements on the urban thermal environment at multiple scales. It was found that performance of pavements inside the canyon was largely determined by the canyon geometry. In a high-density residential area, modifying pavements had insignificant effect on the wall temperature and building energy consumption. At a regional scale, various pavement types were also found to have a limited cooling effect on land surface temperature and 2-m air temperature for metropolitan Phoenix. In the context of global climate change, the effect of pavement was evaluated in terms of the equivalent CO2 emission. Equivalent CO2 emission offset by reflective pavements in urban canyons was only about 13.9e46.6% of that without building canopies, depending on the canyon geometry. This study revealed the importance of building-environment thermal interactions in determining thermal conditions inside the urban canopy.

ContributorsYang, Jiachuan (Author) / Wang, Zhi-Hua (Author) / Kaloush, Kamil (Author) / Dylla, Heather (Author)
Created2016-08-22