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- Member of: Barrett, The Honors College Thesis/Creative Project Collection
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Description
Calcium hydroxide carbonation processes were studied to investigate the potential for abiotic soil improvement. Different mixtures of common soil constituents such as sand, clay, and granite were mixed with a calcium hydroxide slurry and carbonated at approximately 860 psi. While the carbonation was successful and calcite formation was strong on sample exteriors, a 4 mm passivating boundary layer effect was observed, impeding the carbonation process at the center. XRD analysis was used to characterize the extent of carbonation, indicating extremely poor carbonation and therefore CO2 penetration inside the visible boundary. The depth of the passivating layer was found to be independent of both time and choice of aggregate. Less than adequate strength was developed in carbonated trials due to formation of small, weakly-connected crystals, shown with SEM analysis. Additional research, especially in situ analysis with thermogravimetric analysis would be useful to determine the causation of poor carbonation performance. This technology has great potential to substitute for certain Portland cement applications if these issues can be addressed.
ContributorsHermens, Stephen Edward (Author) / Bearat, Hamdallah (Thesis director) / Dai, Lenore (Committee member) / Mobasher, Barzin (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor)
Created2015-05
Description
Utilizing an urban canopy model (UCM) developed by Zhihua Wang, Ph.D. for a research study conducted for the National Asphalt Pavement Association (NAPA), several scenarios were run in order to determine the impact on the mitigation of the urban heat island (UHI) effect. These scenarios included various roof albedo, wall albedo, ground albedo, a combination of all three albedos, roof emissivity, wall emissivity, ground emissivity, a combination of all three emissivities, and normalized building height as independent variables. Dependent variables included canyon air temperature, effective ground temperature, effective roof temperature, effective wall temperature, and sensible heat flux. It was found that emissivity does play a part in reducing the different dependent variables; however, typically emissivity values are already within a preferred range that not much can be done with them. Normalized building height has a minor impact but the impact that it does have upon the different variables is lessened with lower values of the normalized building height. Increasing the wall albedo decreased the canyon air temperature and the effective wall temperature the most compared to the other variables when considering expenses. An increase in roof albedo reduced effective roof temperature and sensible heat flux the most when taking into consideration the cost of changing the albedo of the surface. Larger values of ground albedo helped to reduce the effective ground temperature more than the other variables considered when a budget is necessary.
ContributorsHousenga, Hannah Eileen (Author) / Kaloush, Kamil (Thesis director) / Wang, Zhihua (Committee member) / Civil, Environmental and Sustainable Engineering Programs (Contributor) / Barrett, The Honors College (Contributor)
Created2015-05
Description
In this investigation, copper slag was used as a coarse aggregate in four different mixes of concrete, consisting of 0%, 25%, 50%, and 100% copper slag by volume. Locally available Salt river aggregate was used as a control, and mixes were tested for density, strength, thermal conductivity, specific heat capacity, and thermal diffusivity. Density was shown to increase with increasing copper slag content, increasing an average of 2298 kg/m^3, 2522 kg/m^3, and 2652 kg/m^3 in the 25%, 50%, and 100% mixes. This represents a 15% increase in density from 0% to 100%. Compressive strength testing indicated that the presence of copper slag in concrete provides no definitive strength benefit over Salt River aggregate. This result was expected, as concrete's strength is primarily derived from the cement matrix and not the aggregate. Thermal conductivity showed a decreasing trend with increasing copper slag content. Th control mix had an average conductivity of 0.660 W/m*K, and the 25%, 50%, and 100% mixes had conductivities of 0.649 W/m*K, 0.647 W/m*K, and 0.519 W/m*K, respectively. This represents 21% drop in thermal conductivity over the control. This result was also expected, as materials formed at higher temperatures, like copper slag, tend to have lower thermal conductivities. Specific heat capacity testing yielded results that were statistically indeterminate, though unlike strength testing this arose from inaccurate assumptions made during testing. This also prevented accurate thermal diffusivity results, as diffusivity is a function of density, thermal conductivity, and specific heat capacity. However, given the trends of the first two parameters, it is plausible to say that diffusivity in copper slag concrete would be lower than that of the control ix. All of these results were plugged into ASU's Pavement Temperature Model to see what effect they had in mitigating the UHI effect.
ContributorsLaughlin, Colin (Author) / Kaloush, Kamil (Thesis director) / Phelan, Patrick (Committee member) / Witczak, Kenneth (Committee member) / Barrett, The Honors College (Contributor)
Created2012-05
Description
While public transit systems are perceived to produce lower GHG emission intensities per passenger miles traveled (PMT) and per vehicle miles traveled (VMT), there is a limited understanding of emissions per PMT/VMT across cities, or of how emissions may change across modes (light, metro, commuter, and bus) and time (e.g., with changing electricity mixes in the future). In order to better understand the GHG emissions intensity of public transit systems, a comparative emissions assessment was developed utilizing the National Transit Database (NTD) which reports energy use from 1997 to 2012 of rail and bus systems across the US. By determining the GHG emission intensities (per VMT or per PMT) for each mode of transit across multiple years, the modes of transit can be better compared between one another. This comparison can help inform future goals to reduce GHG emissions as well as target reductions from the mode of transit that has the highest emissions. The proposed analysis of the NTD and comparison of modal emission intensities will be used to develop future forecasting that can guide public transit systems towards a sustainable future.
ContributorsCano, Alex (Author) / Chester, Mikhail (Thesis director) / Seager, Thomas (Committee member) / Civil, Environmental and Sustainable Engineering Programs (Contributor) / Barrett, The Honors College (Contributor) / School of Sustainability (Contributor) / School of Human Evolution and Social Change (Contributor)
Created2014-12
Description
ABSTRACT Water and energy resources are intrinsically linked, yet they are managed separately even in the water scarce America southwest. This study develops a spatially explicit model of water energy inter-dependencies in Arizona and assesses the potential for co beneficial conservation programs. The interdependent benefits of investments in 8 conservation strategies are assessed within the context of legislated renewable energy portfolio and energy efficiency standards. The co- benefits of conservation are found to be significant. Water conservation policies have the potential to reduce statewide electricity demand by 1.0 - 3.0 %, satisfying 3.3 -10 % of the state's mandated energy-efficiency-standard. Adoption of energy -efficiency measures and renewable generation portfolios can reduce non - agricultural water demand by 2.3 - 12 %. The conservation co- benefits are typically not included in conservation plans or benefit cost analyses. Many co-benefits offer negative costs of saved water and energy, indicating that these measures provide water and energy savings at no net cost. Because ranges of costs and savings for water energy conservation measures are somewhat uncertain, future studies should investigate the co-benefits of individual conservation strategies in detail. Although this study focuses on Arizona, the analysis can be extended elsewhere as renewable portfolio and energy efficiency standards become more common nationally and internationally.
ContributorsBartos, Matthew D. (Author) / Chester, Mikhail (Thesis director) / Mays, Larry (Committee member) / Barrett, The Honors College (Contributor)
Created2013-12
Description
Transit-oriented developments (TODs) are a promising strategy to increase public transit use and, as a result, reduce personal car travel. By using TOD infill to increase urban population density and encourage transportation mode-shifting, the potential exists to reduce life-cycle per capita energy use and environmental impacts of the interdependent infrastructure systems. This project specifically examined the Gold Line of light rail and Orange Line of bus rapid transit in Los Angeles, CA.
ContributorsNahlik, Matthew John (Author) / Chester, Mikhail (Thesis director) / Pendyala, Ram (Committee member) / Pincetl, Stephanie (Committee member) / Civil, Environmental and Sustainable Engineering Programs (Contributor) / Barrett, The Honors College (Contributor) / School of Sustainability (Contributor)
Created2013-05
Description
Concrete stands at the forefront of the construction industry as one of the most useful building materials. Economic and efficient improvements in concrete strengthening and manufacturing are widely sought to continuously improve the performance of the material. Fiber reinforcement is a significant technique in strengthening precast concrete, but manufacturing limitations are common which has led to reliance on steel reinforcement. Two-dimensional textile reinforcement has emerged as a strong and efficient alternative to both fiber and steel reinforced concrete with pultrusion manufacturing shown as one of the most effective methods of precasting concrete. The intention of this thesis project is to detail the components, functions, and outcomes shown in the development of an automated pultrusion system for manufacturing textile reinforced concrete (TRC). Using a preexisting, manual pultrusion system and current-day manufacturing techniques as a basis, the automated pultrusion system was designed as a series of five stations that centered on textile impregnation, system driving, and final pressing. The system was then constructed in the Arizona State University Structures Lab over the course of the spring and summer of 2015. After fabricating each station, a computer VI was coded in LabVIEW software to automatically drive the system. Upon completing construction of the system, plate and angled structural sections were then manufactured to verify the adequacy of the technique. Pultruded TRC plates were tested in tension and flexure while full-scale structural sections were tested in tension and compression. Ultimately, the automated pultrusion system was successful in establishing an efficient and consistent manufacturing process for continuous TRC sections.
ContributorsBauchmoyer, Jacob Macgregor (Author) / Mobasher, Barzin (Thesis director) / Neithalath, Narayanan (Committee member) / Civil, Environmental and Sustainable Engineering Programs (Contributor) / The Design School (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
Description
Climate change has necessitated the transition from non-renewable energy sources such as coal, oil, and natural gas to renewable, low-carbon energy sources such as solar, wind, and hydroelectric. These energy sources, although much better equipped to reduce carbon-induced climate change, require materials that pollute the environment when mined and can release toxic waste during processing and disposal. Critical minerals are used in low-carbon renewable energy, and they are subject to both the environmental issues that accompany regular mineral extraction as well as issues related to scarcity from geopolitical issues, trade policy, and geological rarity. Tellurium is a critical mineral produced primarily as a byproduct of copper and used in cadmium-telluride (CdTe) solar panels. As these solar panels become more common, the problems that arise with many critical minerals’ usage (pollution, unfair distribution, human health complications) become more apparent. Looking at these issues through an energy justice framework can help to ensure availability, sustainability, inter/intragenerational equity, and accountability, and this framework can provide a more nuanced understanding of the costs and the benefits that will accrue with the transition to low-carbon, renewable energy. Energy justice issues surrounding the extraction of critical minerals will become increasingly prevalent as more countries pledge to have a zero-carbon future.
ContributorsMaas, Samantha (Author) / Jalbert, Kirk (Thesis director) / Chester, Mikhail (Committee member) / Barrett, The Honors College (Contributor) / School of Public Affairs (Contributor) / School of Life Sciences (Contributor)
Created2022-05