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Description
Tri-layer lithium ion battery separators were synthesized by dip-coating macroporous YSZ and mesoporous sol-gel derived gamma-alumina films onto porous polypropylene. These separators were installed into coin-cell lithium ion batteries and subjected to charge/discharge cycle testing to determine specific capacity. The gamma-alumina coated separators exhibited low capacity, while the YSZ coated separators failed immediately. Investigation by SEM and a surface wettability test indicated that the gamma alumina and YSZ coatings exhibited low wettability, and the YSZ coating exhibited low porosity. These factors resulted in high internal resistance of the battery, due to electrolyte failing to permeate the separator and provide transport of lithium ions between the electrodes.
ContributorsMcafee, Paul Milton (Author) / Lin, Jerry Y.S. (Thesis director) / Kasik, Alexandra (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor)
Created2015-05
Description
This document outlines the research work done by Shona Becwar in the process design and refinement for the production of sustainable butanol from Clostridium, along with the required background knowledge on the subject. The process that the microbiological organisms go through to produce butanol must be an oxygen free environment for up to 21 days with multiple perforations made into the environment in this period. There was not previously a cost effective method to do this, even in small scale. It was determined that using a butyl rubber septa would allow for the environment to be sustained during the growth process. The pervaporation process was losing butanol product at a rate of approximately 60%, changing the tubing from silicon to stainless steel allowed for a mere 7% loss during the separation process, greatly increasing the prospective of upscaling this process. These improvements to the sustainable butanol production process will allow for a more efficient, therefore more economically competitive product which can be used as a drop in equivalent to the current butanol market.
ContributorsBecwar, Shona Marie (Author) / Nielsen, David R. (Thesis director) / Staggs, Kyle (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
Description
Sex trafficking in the United States is an enormous illegal underground business economy that involves the sexual exploitation of many persons. Due to the large nature of the sex trafficking business and the many different types of sex trafficking, it is helpful for social workers, government agencies, and activists to understand the intricacies of the various types of sex trafficking. This research focused on determining the human resources business structures behind pimp businesses that relied on mental coercion of the victim. The data source used, Pimpfeet.com—an online pimp authored blog—provided data from actual pimps on their business practices that were analyzed to determine trends in recruitment and retention. These trends were compared to human resource management theories from business literature to determine to what extent, or if at all, a pimp’s business recruited and retained workers in a way that was similar to how a legal business would, according to human resources strategies. The data extracted from Pimpfeet.com and used in this study consisted of 69 pimp quotes that were put into three recruitment categories and five retention categories based on human resource management literature in order to see which categories were used for recruitment and retention by pimps. This study found that pimp recruitment and retention followed, to some extent, the same models described in the human resource management literature, with slight modifications. This study showed that job embeddedness theory (Holtom, Mitchel and Lee, 2009) was able to explain much of why sex trafficking victims are retained so well by pimps since they are so embedded in the prostitution lifestyle. These findings show the different business techniques that pimps use for recruitment and retention of sex workers and are useful for understanding how a social worker, government entity or an activist can combat these forces to help remove victims from a pimp’s control, or keep victims from getting recruited in the first place. Further areas of research related to this topic were suggested.
ContributorsRivera, Kameron (Co-author) / La Benz, Alexis (Co-author) / Roe-Sepowitz, Dominique (Thesis director) / Corley, Kevin (Committee member) / W. P. Carey School of Business (Contributor) / Chemical Engineering Program (Contributor) / T. Denny Sanford School of Social and Family Dynamics (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
Description
In a dormant state, cancer cells survive chemotherapy leaving the opportunity for cancer cell relapse and metastasis ultimately leading to patient death. A novel aminoglycoside-based hydrogel ‘Amikagel’ developed in Dr. Rege’s lab serves as a platform for a 3D tumor microenvironment (3DTM) mimicking cancer cell dormancy and relapse. Six Amikagels of varying mechanical stiffness and adhesivities were synthesized and evaluated as platforms for 3DTM formation through cell viability and cell cycle arrest analyses. The impact of fetal bovine serum concentration and bovine serum albumin concentration in the media were studied for their impact on 3DTM formation. These experiments allow us to identify the best possible Amikagel formulation for 3DTM.
ContributorsGjertsen, Haley Nicole (Author) / Rege, Kaushal (Thesis director) / Grandhi, Taraka Sai Pavan (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
Description
Based on theoretical calculations, a material that is highly transmissive below 3000 nm and opaque above 3000 nm is desired to replace glass covers for flat plate solar thermal systems. Additionally, a suitable replacement material needs to have a sufficiently high operating temperature in order to prevent the glazing from melting and warping in a solar system. Traditional solar thermal applications use conventional soda lime glass or low iron content glass to accomplish this; however, this project aims to investigate acrylic, polycarbonate, and FEP film as suitable alternatives for conventional solar glazings. While UV-Vis and FT-IR spectroscopy indicate that these polymer substitutes may not be ideal when used alone, when used in combination with coatings and additives, these materials may present an opportunity for a glazing replacement. A model representing a flat plate solar collector was developed to qualitatively analyze the various materials and their performance. Using gathered spectroscopy data, the model was developed for a multi-glazing system and it was found that polymer substitutes could perform better in certain system configurations. To complete the model, the model must be verified using empirical data and coatings and additives investigated for the purposes of achieving the desired materials optical specifications.
ContributorsBessant, Justin Zachary (Author) / Friesen, Cody (Thesis director) / Lorzel, Heath (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
Description
This paper intends to analyze the Phoenix Suns' shooting patterns in real NBA games, and compare them to the "NBA 2k16" Suns' shooting patterns. Data was collected from the first five Suns' games of the 2015-2016 season and the same games played in "NBA 2k16". The findings of this paper indicate that "NBA 2k16" utilizes statistical findings to model their gameplay. It was also determined that "NBA 2k16" modeled the shooting patterns of the Suns in the first five games of the 2015-2016 season very closely. Both, the real Suns' games and the "NBA 2k16" Suns' games, showed a higher probability of success for shots taken in the first eight seconds of the shot clock than the last eight seconds of the shot clock. Similarly, both game types illustrated a trend that the probability of success for a shot increases as a player holds onto a ball longer. This result was not expected for either game type, however, "NBA 2k16" modeled the findings consistent with real Suns' games. The video game modeled the Suns with significantly more passes per possession than the real Suns' games, while they also showed a trend that more passes per possession has a significant effect on the outcome of the shot. This trend was not present in the real Suns' games, however literature supports this finding. Also, "NBA 2k16" did not correctly model the allocation of team shots for each player, however, the differences were found only in bench players. Lastly, "NBA 2k16" did not correctly allocate shots across the seven regions for Eric Bledsoe, however, there was no evidence indicating that the game did not correctly model the allocation of shots for the other starters, as well as the probability of success across the regions.
ContributorsHarrington, John P. (Author) / Armbruster, Dieter (Thesis director) / Kamarianakis, Ioannis (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
Description
One of the grand challenges of engineering is to provide access to clean water because it is predicted that by 2025 more than two thirds of the world’s population will face severe water shortages. To combat this global issue, our lab focuses on creating a novel composite membrane to recover potable water from waste. For use as the water-selective component in this membrane design Linde Type A zeolites were synthesized for optimal size without the use of a template. Current template-free synthesis of zeolite LTA produces particles that are too large for our application therefore the particle size was reduced in this study to reduce fouling of the membrane while also investigating the nanoparticle synthesis mechanisms. The time and temperature of the reaction and the aging of the precursor gel were systematically modified and observed to determine the optimal conditions for producing the particles. Scanning electron microscopy, x-ray diffraction, and energy dispersive x-ray analysis were used for characterization. Sub-micron sized particles were synthesized at 2 weeks aging time at -8°C with an average size of 0.6 micrometers, a size suitable for our membrane. There is a limit to the posterity and uniformity of particles produced from modifying the reaction time and temperature. All results follow general crystallization theory. Longer aging produced smaller particles, consistent with nucleation theory. Spinodal decomposition is predicted to affect nucleation clustering during aging due to the temperature scheme. Efforts will be made to shorten the effective aging time and these particles will eventually be incorporated into our mixed matrix osmosis membrane.
ContributorsKing, Julia Ann (Author) / Lind, Mary Laura (Thesis director) / Durgun, Pinar Cay (Committee member) / Chemical Engineering Program (Contributor) / Materials Science and Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
Description
The two authors completed the entirety of their schooling within the United States, from preschool to university. Both authors experienced loss of interest towards their education each successive year and assumed the nature of learning and education was to blame. The two students took a class on the Kashiwagi Information Measurement Theory their second years at Arizona State University and applied the concepts taught in that class to past experiences in the United States education system to determine the cause behind their waning interest in their education. Using KSM principles the authors identified that the environment produced by and ineffectual and inefficient educational system is what resulted in their, and the majority of their peers, growing dissatisfaction in their education. A negative correlation was found between GPA and control. As the control in a students environment increased, their GPA decreased. The data collected in this thesis also supports the conclusions that as a student is exposed to a high stress environment, their GPA and average amount of sleep per night decrease.
ContributorsKulanathan, Shivaan (Co-author) / Westlake, Kyle (Co-author) / Kashiwagi, Dean (Thesis director) / Kashiwagi, Jacob (Committee member) / Gunnoe, Jake (Committee member) / Computer Science and Engineering Program (Contributor) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
Description
Zeolitic Imidazolate Frameworks (ZIFs) are a promising technology for the separation of gases. ZIFs represent a type of hybrid material that is a subset of metal organic frameworks while displaying zeolite properties. ZIFs have tunable pore metrics, high thermal stability, and large surface areas giving them advantages over traditional zeolites. The experiment sought to determine the flux of hexane vapor through ZIF-68 with Fourier Transform Infrared Spectroscopy (FTIR) mapping. FTIR mapping was used to obtain three spectra per crystal and the concentration gradient was analyzed to determine the flux. ZIF-68 was completely stable when loaded with hexane and exposed to the atmosphere. There was no hexane diffusion out of the crystal. As a result, ZIF-68 was heated to 50°C to increase diffusion and calculate the flux. ZIF-68 adhered to Knudsen Diffusion, and the flux was calculated to be 2.00*10-5 kg mol/s*m2. The small flux occurred because almost no concentration gradient was obtained through the crystal. It was hypothesized that the resistance in the crystal was substantially lower than the resistance at the boundary layer, which would have caused a small concentration gradient. Using film mass transfer theory, the resistance inside the crystal was found to be 1200 times lower than the resistance at the boundary layer confirming the hypothesis.
ContributorsSigrist, Dallas Dale (Author) / Lin, Jerry (Thesis director) / Wang, Liping (Committee member) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2016-05
Description
As prices for fuel along with the demand for renewable resources grow, it becomes of paramount importance to develop new ways of obtaining the energy needed to carry out the tasks we face daily. Costs of production due to energy and time constraints impose severe limitations on what is viable. Biological systems, on the other hand, are innately efficient both in terms of time and energy by handling tasks at the molecular level. Utilizing this efficiency is at the core of this research. Proper manipulation of even common proteins can render complexes functionalized for specific tasks. In this case, the coupling of a rhenium-based organometallic ligand to a modified myoglobin containing a zinc porphyrin, allow for efficient reduction of carbon dioxide, resulting in energy that can be harnessed and byproducts which can be used for further processing. Additionally, a rhenium based ligand functionalized via biotin is tested in conjunction with streptavidin and ruthenium-bipyridine.
ContributorsAllen, Jason Kenneth (Author) / Ghirlanda, Giovanna (Thesis director) / Francisco, Wilson (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor)
Created2014-12