Matching Items (16)
Description
Zinc telluride (ZnTe) is an attractive II-VI compound semiconductor with a direct
bandgap of 2.26 eV that is used in many applications in optoelectronic devices. Compared
to the two dimensional (2D) thin-film semiconductors, one-dimensional (1D)
nanowires can have different electronic properties for potential novel applications.
In this work, we present the study of ZnTe nanowires (NWs) that are synthesized
through a simple vapor-liquid-solid (VLS) method. By controlling the presence or
the absence of Au catalysts and controlling the growth parameters such as growth
temperature, various growth morphologies of ZnTe, such as thin films and nanowires
can be obtained. The characterization of the ZnTe nanostructures and films was
performed using scanning electron microscope (SEM), energy-dispersive X-ray spectroscopy
(EDX), high- resolution transmission electron microscope (HRTEM), X-ray
diffraction (XRD), photoluminescence (PL), Raman spectroscopy and light scattering
measurement. After confirming the crystal purity of ZnTe, two-terminal diodes and
three-terminal transistors were fabricated with both nanowire and planar nano-sheet
configurations, in order to correlate the nanostructure geometry to device performance
including field effect mobility, Schottky barrier characteristics, and turn-on
characteristics. Additionally, optoelectronic properties such as photoconductive gain
and responsivity were compared against morphology. Finally, ZnTe was explored in
conjunction with ZnO in order to form type-II band alignment in a core-shell nanostructure.
Various characterization techniques including scanning electron microscopy,
energy-dispersive X-ray spectroscopy , x-ray diffraction, Raman spectroscopy, UV-vis
reflectance spectra and photoluminescence were used to investigate the modification
of ZnO/ZnTe core/shell structure properties. In PL spectra, the eliminated PL intensity
of ZnO wires is primarily attributed to the efficient charge transfer process
occurring between ZnO and ZnTe, due to the band alignment in the core/shell structure. Moreover, the result of UV-vis reflectance spectra corresponds to the band
gap energy of ZnO and ZnTe, respectively, which confirm that the sample consists of
ZnO/ZnTe core/shell structure of good quality.
bandgap of 2.26 eV that is used in many applications in optoelectronic devices. Compared
to the two dimensional (2D) thin-film semiconductors, one-dimensional (1D)
nanowires can have different electronic properties for potential novel applications.
In this work, we present the study of ZnTe nanowires (NWs) that are synthesized
through a simple vapor-liquid-solid (VLS) method. By controlling the presence or
the absence of Au catalysts and controlling the growth parameters such as growth
temperature, various growth morphologies of ZnTe, such as thin films and nanowires
can be obtained. The characterization of the ZnTe nanostructures and films was
performed using scanning electron microscope (SEM), energy-dispersive X-ray spectroscopy
(EDX), high- resolution transmission electron microscope (HRTEM), X-ray
diffraction (XRD), photoluminescence (PL), Raman spectroscopy and light scattering
measurement. After confirming the crystal purity of ZnTe, two-terminal diodes and
three-terminal transistors were fabricated with both nanowire and planar nano-sheet
configurations, in order to correlate the nanostructure geometry to device performance
including field effect mobility, Schottky barrier characteristics, and turn-on
characteristics. Additionally, optoelectronic properties such as photoconductive gain
and responsivity were compared against morphology. Finally, ZnTe was explored in
conjunction with ZnO in order to form type-II band alignment in a core-shell nanostructure.
Various characterization techniques including scanning electron microscopy,
energy-dispersive X-ray spectroscopy , x-ray diffraction, Raman spectroscopy, UV-vis
reflectance spectra and photoluminescence were used to investigate the modification
of ZnO/ZnTe core/shell structure properties. In PL spectra, the eliminated PL intensity
of ZnO wires is primarily attributed to the efficient charge transfer process
occurring between ZnO and ZnTe, due to the band alignment in the core/shell structure. Moreover, the result of UV-vis reflectance spectra corresponds to the band
gap energy of ZnO and ZnTe, respectively, which confirm that the sample consists of
ZnO/ZnTe core/shell structure of good quality.
ContributorsPeng, Jhih-hong (Author) / Yu, Hongbin (Thesis advisor) / Roedel, Ronald (Committee member) / Goryll, Michael (Committee member) / Zhao, Yuji (Committee member) / Arizona State University (Publisher)
Created2017
Description
The project described here is a solar powered intrusion detection system consisting of three modules: a battery recharging circuit, a laser emitter and photodetector pair, and a Wi- Fi connectivity board. Over the preceding seven months, great care has been taken for the design and construction of this system. The first three months were spent researching and selecting suitable IC's and external components (e.g. solar panel, batteries, etc.). Then, the next couple of months were spent ordering specific materials and equipment for the construction of our prototype. Finally, the last two months were used to build a working prototype, with a substantial amount of time used for perfecting our system's packaging and operation. This report will consist of a detailed discussion of our team's research, design activities, prototype implementation, final budget, and final schedule. Technical discussion of the concepts behind our design will assist with understanding the design activities and prototype implementation sections that will follow. Due to the generous funding of the group from the Barrett Honors College, our overall budget available for the project was $1600. Of that amount, only $334.51 was spent on the actual system components, with $829.42 being spent on the equipment and materials needed for the testing and construction of the prototype. As far as the schedule goes, we are essentially done with the project. The only tasks left to finish are a successful defense of the project at the oral presentation on Friday, 29 March 2013, followed by a successful demo on 26 April 2013.
ContributorsTroyer, Nicole L. (Co-author) / Shtayer, Idan (Co-author) / Guise, Chris (Co-author) / Kozicki, Michael (Thesis director) / Roedel, Ronald (Committee member) / Goodnick, Stephen (Committee member) / Barrett, The Honors College (Contributor) / Electrical Engineering Program (Contributor)
Created2013-05
DescriptionExploring solar cell model alternatives using electrochemically deposited dendrites as a form of current collection to increase efficiency and top electrode transparency.
ContributorsKrawczyk, Joseph Robert (Author) / Kozicki, Michael (Thesis director) / Roedel, Ronald (Committee member) / Gonzalez Velo, Yago (Committee member) / Barrett, The Honors College (Contributor) / Electrical Engineering Program (Contributor)
Created2013-05
Description
Water desalination has become one of the viable solutions to provide drinking water in regions with limited natural resources. This is particularly true in small communities in arid regions, which suffer from low rainfall, declining surface water and increasing salinity of groundwater. Yet, current desalination methods are difficult to be implemented in these areas due to their centralized large-scale design. In addition, these methods require intensive maintenance, and sometimes do not operate in high salinity feedwater. Membrane distillation (MD) is one technology that can potentially overcome these challenges and has received increasing attention in the last 15 years. The driving force of MD is the difference in vapor pressure across a microporous hydrophobic membrane. Compared to conventional membrane-based technologies, MD can treat high concentration feedwater, does not need intensive pretreatment, and has better fouling resistance. More importantly, MD operates at low feed temperatures and so it can utilize low–grade heat sources such as solar energy for its operation. While the integration of solar energy and MD was conventionally indirect (i.e. by having two separate systems: a solar collector and an MD module), recent efforts were focused on direct integration where the membrane itself is integrated within a solar collector aiming to have a more compact, standalone design suitable for small-scale applications. In this dissertation, a comprehensive review of these efforts is discussed in Chapter 2. Two novel direct solar-powered MD systems were proposed and investigated experimentally: firstly, a direct contact MD (DCMD) system was designed by placing capillary membranes within an evacuated tube solar collector (ETC) (Chapter 3), and secondly, a submerged vacuum MD (S-VMD) system that uses circulation and aeration as agitation techniques was investigated (Chapter 4). A maximum water production per absorbing area of 0.96 kg·m–2·h–1 and a thermal efficiency of 0.51 were achieved. A final study was conducted to investigate the effect of ultrasound in an S-VMD unit (Chapter 5), which significantly enhanced the permeate flux (up to 24%) and reduced the specific energy consumption (up to 14%). The results add substantially to the understanding of integrating ultrasound with different MD processes.
ContributorsBamasag, Ahmad (Author) / Phelan, Patrick E (Thesis advisor) / Shuaib, Abdelrahman (Committee member) / Wang, Liping (Committee member) / Bocanegra, Luis (Committee member) / Roedel, Ronald (Committee member) / Arizona State University (Publisher)
Created2020
Description
Ensuring that people across the globe have enough water and electricity are two large issues that continue to grow. This study performs a test on whether using solar photovoltaic modules to shade water can potentially help diminish the issues of water and power. Using the setup of a PV module shading water, a stand-alone PV module, and unshaded water, it was found that shading water can reduce evaporation and lower PV module operating temperature at the same time. Using averaged data from two days of testing, the volume per unit surface area of water that evaporated per hour was 0.319 cm3/cm2 less for the shaded water compared to the unshaded water. The evaporation rates found in the experiment are compared to those of Lake Mead to see the amount of water lost on a large scale. For the operating temperature of the PV module, the module used for shading had a consistently lower temperature than the stand-alone module. On the first day, the shading module had an average temperature 5.1 C lower than the stand-alone module average temperature. On day two, the shading module had an average temperature 3.4 C lower than the stand-alone module average temperature. Using average temperatures between the two days from 10:30am and 4:45pm, the average daily temperature of the panel used for shading was 4.5C less than the temperature of the stand-alone panel. These results prove water shading by solar PV modules to be effective in reducing evaporation and lowering module operating temperature. Last, suggestions for future studies are discussed, such as performance analysis of the PV modules in this setting, economic analysis of using PV modules as shading, and the isolation of the different factors of evaporation (temperature, wind speed, and humidity).
ContributorsLee, John C (Author) / Phelan, Patrick (Thesis director) / Roedel, Ronald (Committee member) / Dean, W.P. Carey School of Business (Contributor) / Mechanical and Aerospace Engineering Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2019-05
Description
Kuwait is committed to implementing the Kyoto Protocol in “Vision 2035” to reduce greenhouse gas emissions by shifting to the use of wind and solar energies [1]. The specific goal of the Vision 2035 is for renewables to comprise 15% of Kuwait’s electrical generation by 2030. Wind and solar are abundant in Kuwait and can easily provide 15% of the total electrical generation. However, there are three significant obstacles. The first is Kuwait currently depends heavily on rapidly diminishing fossil fuels which are the major sources of CO2, NOx, and SOx emissions. Unfortunately, current plans are to build two conventional power stations by 2024. The purpose is to cover the energy needs for growing population. The second problem is that Kuwait has a very small land area. Consequently, there is limited space to build new utility-scale renewable power stations. The third issue is the low electricity tariff provides little incentive for the population to save energy. Offshore wind farms have the potential to provide thousands of GWh/yr to accomplish the goals of Vision 2035. Kuwait has a vast untapped supply of offshore wind energy. Specifically, there are eight offshore locations in which 50 turbines could be built each, for a total of 400 turbines. Using 4.2 MW turbines, this would provide 1.68 GW of wind energy, and increase the renewable portion of the electrical energy production to 13.93% (including Shagaya renewable park). Installing battery storage with the proposed wind turbines could provide fast ramp response which would serve to complement existing power production on Kuwait’s grid. In this work, six different turbines with different sizes are considered from 2.5 MW to 4.2 MW (from well-known manufacturers, such as, Nordex and Vestas), but ultimately 4.2 MW turbines are recommended. Data for this study has been supplied by: A) Civil Aviation -- temperature and wind speed, B) Ministry of Electricity and Water (MEW) -- electricity data, and C) Public Authority for Civil Information -- population data.
ContributorsAlotaibi, Abdullah Saqer (Author) / Calhoun, Ronald (Thesis advisor) / Kitchen, Jennifer (Thesis advisor) / Roedel, Ronald (Committee member) / Mayyas, Abdul Ra'ouf (Committee member) / Arizona State University (Publisher)
Created2020