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The purpose of this thesis was to investigate the properties of amorphous and crystalline NaTaO3 to determine what makes amorphous NaTaO3 a suitable photocatalyst for water splitting applications. Amorphous and nanocrystalline NaTaO3 were synthesized and characterized using X-Ray Diffraction (XRD), Raman Spectroscopy, and Fourier Transform Infrared Spectroscopy (FT-IR). The photocatalytic activity of the materials was analyzed using methylene blue degradation as an indicator of photocatalytic activity. The amorphous material showed significant photocatalytic activity in methylene blue degradation experiments, removing 100% of a 0.1 mmol methylene blue solution in 20 minutes, compared to the monoclinic crystalline NaTaO3, which showed negligible photocatalytic activity. Additional electrochemical characterization studies were carried out with methyl viologen (MV2+) to determine the band structure of the materials. Performing these synthesis and characterization has provided insight into further investigation of amorphous NaTaO3 and what makes the material an effective and inexpensive photocatalyst.
ContributorsRorrer, Julie Elaine (Author) / Chan, Candace (Thesis director) / Bertoni, Mariana (Committee member) / Barrett, The Honors College (Contributor) / Chemical Engineering Program (Contributor)
Created2014-05
Description
The Solar Powered Amphibious Transport (SPAT) is an amphibious hovercraft that uses solar energy as a power source and is fully controlled via iOS application on a phone or tablet. The hovercraft field is relatively unexplored with a solar power source, and one of the goals of the SPAT was to spark interest in sustainable hovercraft design. By challenging the potential of solar power, the SPAT proves that solar energy can be used in high power transportation applications. The second motive behind the creation a hovercraft was for it to serve as a disaster relief vehicle. A hovercraft can traverse both ground and water, which makes it ideal in flooded areas. With the SPAT being remote controlled it can allow the operator to stay at a safe distance while sending supplies or rescuing a person. The SPAT design covered multiple size options, however a small prototype version was built to serve as a proof of concept that a larger solar hovercraft is possible. Our analysis suggests that a larger craft will be able to carry more weight, and be more power efficient. A larger SPAT could help deliver supplies or rescue stranded people after a flood or hurricane. One issue faced however, was that many hovercrafts are highly expensive. The SPAT prototype was designed on a tight budget that did not exceed $800. The possibility of achieving this cost levels allows hovercraft to be a reasonable option for disaster relief agencies. After many long hours spent the SPAT became a fully operational remote control solar powered hovercraft.
ContributorsDavis, Parker William (Co-author) / Clenney, Jacob (Co-author) / Nachman, Michael (Co-author) / Melillo, Nick (Co-author) / Bertoni, Mariana (Thesis director) / Kozicki, Michael (Committee member) / Electrical Engineering Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2017-05
Description
To reduce the cost of silicon solar cells and improve their efficiency, it is crucial to identify and understand the defects limiting the electrical performance in silicon wafers. Bulk defects in semiconductors produce discrete energy levels within the bandgap and may act as recombination centers. This project investigates the viability of using machine learning for characterizing bulk defects in Silicon by using a Random Forest Regressor to extract the defect energy level and capture cross section ratios for a simulated Molybdenum defect and experimental Silicon Vacancy defect. Additionally, a dual convolutional neural network is used to classify the defect energy level in the upper or lower half bandgap.
ContributorsWoo, Vanessa (Author) / Bertoni, Mariana (Thesis director) / Rolston, Nicholas (Committee member) / Barrett, The Honors College (Contributor) / Electrical Engineering Program (Contributor)
Created2023-05
Description
The investigation into wide band gap semiconductors for use in tandem solar cells has become an increasingly more researched area with many new absorbers outlining the landscape. Pairing silicon with another cheap wide band gap semiconductor absorber can generate more efficient solar cell, which could continue to drive up the energy output from solar. One such recently researched wide band gap absorber is ZnSnN2. ZnSnN2 proves too difficult to form under most conditions, but has the necessary band gap to make it a potential earth abundant solar absorber. The deposition process for ZnSnN2 is usually conducted with Zn and Sn metal targets while flowing N2 gas. Due to restrictions with chamber depositions, instead ZnO and SnO2 targets were sputtered with N2 gas to attempt to form separate zinc and tin oxynitrides as an initial single target study prior to future combinatorial studies. The electrical and optical properties and crystal structure of these thin films were analyzed to determine the nitrogen incorporation in the thin films through X-ray diffraction, UV-Vis spectrophotometry, and 4-point probe measurements. The SnO2 thin films showed a clear response in the absorption coefficient leading but showed no observable XRD peak shift. Thus, it is unlikely that substantial amounts of nitrogen were incorporated into SnO¬2. ZnO showed a clear response increase in conductivity with N2 with an additional shift in the XRD peak at 300 °C and potential secondary phase peak. Nitrogen incorporation was achieved with fair amounts of certainty for the ZnO thin films.
ContributorsTheut, Nicholas C (Author) / Bertoni, Mariana (Thesis director) / Holman, Zachary (Committee member) / Materials Science and Engineering Program (Contributor) / Chemical Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2019-05