Matching Items (220)
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Solar cells are an increasingly important energy source for meeting growing energy demands. Organic photovoltaics in particular have potential in this area due to their low cost and the relative abundance of their constituents. One concern with the inverted configuration (a type of OPV with increased long-term stability) is their

Solar cells are an increasingly important energy source for meeting growing energy demands. Organic photovoltaics in particular have potential in this area due to their low cost and the relative abundance of their constituents. One concern with the inverted configuration (a type of OPV with increased long-term stability) is their reliance on activation by ultraviolet (UV) light. Here we examine the incorporation of a new electron transport layer (ETL) material, zinc tin oxide (ZTO), in order to assess its interaction with UV light. Current-voltage characteristics were analyzed using a 420 nm cutoff filter to control UV light exposure. ZTO proved to be an adequate alternative to ZnO when comparing photovoltaic response. However, no improvement was found in terms of UV light activation. In addition, recent works show that oxygen plasma treatment of metal oxides used for hole transport layers modifies the work function and yields higher efficiency devices. Spin cast benzyl phosphonic acid self-assembled monolayers (BPA SAMs) provide similar results without the need for plasma treatment. Here we examine the use of BPA SAMs in standard devices utilizing PV2000, a proprietary active layer blend made by Plextronics. The use of BPA SAMs on a nickel oxide hole transport layer deepened the work function significantly, yielding greater device performance.
ContributorsJackson, Skyler (Author) / Phelan, Patrick (Thesis director) / Gust, Devans (Committee member) / Barrett, The Honors College (Contributor)
Created2014-05
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Rapid urbanization of the planet is occurring at an unprecedented pace, primarily in arid and semi-arid hot climates [Golden, J.S., 2004. The built environment induced urban heat island effect in rapidly urbanizing arid regions – a sustainable urban engineering complexity. Environ. Sci. J. Integr. Environ. Res. 1 (4), 321–349]. This

Rapid urbanization of the planet is occurring at an unprecedented pace, primarily in arid and semi-arid hot climates [Golden, J.S., 2004. The built environment induced urban heat island effect in rapidly urbanizing arid regions – a sustainable urban engineering complexity. Environ. Sci. J. Integr. Environ. Res. 1 (4), 321–349]. This growth has manifested itself as a cause of various impacts including elevated urban temperatures in comparison to rural sites known as the Urban Heat Island (UHI) effect [Oke, T.R., 1982. The energetic basis of the urban heat island. Q. J. R. Meteor. Soc. 108, 1–24]. Related are the increased demands for electric power as a result of population growth and increased need for mechanical cooling due to the UHI. In the United States, the Environmental Protection Agency has developed a three-prong approach of (1) cool pavements, (2) urban forestry and (3) cool roofs to mitigate the UHI. Researchers undertook an examination of micro scale benefits of the utilization of photovoltaic panels to reduce the thermal impacts to surface temperatures of pavements in comparison to urban forestry. The results of the research indicate that photovoltaic panels provide a greater thermal reduction benefit during the diurnal cycle in comparison to urban forestry while also providing the additional benefits of supporting peak energy demand, conserving water resources and utilizing a renewable energy source.

ContributorsGolden, Jay S. (Author) / Carlson, Joby (Author) / Kaloush, Kamil (Author) / Phelan, Patrick (Author)
Created2006-12-26
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Description
Portable devices rely on battery systems that contribute largely to the overall device form factor and delay portability due to recharging. Membraneless microfluidic fuel cells are considered as the next generation of portable power sources for their compatibility with higher energy density reactants. Microfluidic fuel cells are potentially cost effective

Portable devices rely on battery systems that contribute largely to the overall device form factor and delay portability due to recharging. Membraneless microfluidic fuel cells are considered as the next generation of portable power sources for their compatibility with higher energy density reactants. Microfluidic fuel cells are potentially cost effective and robust because they use low Reynolds number flow to maintain fuel and oxidant separation instead of ion exchange membranes. However, membraneless fuel cells suffer from poor efficiency due to poor mass transport and Ohmic losses. Current microfluidic fuel cell designs suffer from reactant cross-diffusion and thick boundary layers at the electrode surfaces, which result in a compromise between the cell's power output and fuel utilization. This dissertation presents novel flow field architectures aimed at alleviating the mass transport limitations. The first architecture provides a reactant interface where the reactant diffusive concentration gradients are aligned with the bulk flow, mitigating reactant mixing through diffusion and thus crossover. This cell also uses porous electro-catalysts to improve electrode mass transport which results in higher extraction of reactant energy. The second architecture uses porous electrodes and an inert conductive electrolyte stream between the reactants to enhance the interfacial electrical conductivity and maintain complete reactant separation. This design is stacked hydrodynamically and electrically, analogous to membrane based systems, providing increased reactant utilization and power. These fuel cell architectures decouple the fuel cell's power output from its fuel utilization. The fuel cells are tested over a wide range of conditions including variation of the loads, reactant concentrations, background electrolytes, flow rates, and fuel cell geometries. These experiments show that increasing the fuel cell power output is accomplished by increasing reactant flow rates, electrolyte conductivity, and ionic exchange areas, and by decreasing the spacing between the electrodes. The experimental and theoretical observations presented in this dissertation will aid in the future design and commercialization of a new portable power source, which has the desired attributes of high power output per weight and volume and instant rechargeability.
ContributorsSalloum, Kamil S (Author) / Posner, Jonathan D (Thesis advisor) / Adrian, Ronald (Committee member) / Christen, Jennifer (Committee member) / Phelan, Patrick (Committee member) / Chen, Kangping (Committee member) / Arizona State University (Publisher)
Created2010
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Description
Many expect renewable energy technologies to play a leading role in a sustainable energy supply system and to aid the shift away from an over-reliance on traditional hydrocarbon resources in the next few decades. This dissertation develops environmental, policy and social models to help understand various aspects of photovoltaic (PV)

Many expect renewable energy technologies to play a leading role in a sustainable energy supply system and to aid the shift away from an over-reliance on traditional hydrocarbon resources in the next few decades. This dissertation develops environmental, policy and social models to help understand various aspects of photovoltaic (PV) technologies. The first part of this dissertation advances the life cycle assessment (LCA) of PV systems by expanding the boundary of included processes using hybrid LCA and accounting for the technology-driven dynamics of environmental impacts. Hybrid LCA extends the traditional method combining bottom-up process-sum and top-down economic input-output (EIO) approaches. The embodied energy and carbon of multi-crystalline silicon photovoltaic systems are assessed using hybrid LCA. From 2001 to 2010, the embodied energy and carbon fell substantially, indicating that technological progress is realizing reductions in environmental impacts in addition to lower module price. A variety of policies support renewable energy adoption, and it is critical to make them function cooperatively. To reveal the interrelationships among these policies, the second part of this dissertation proposes three tiers of policy architecture. This study develops a model to determine the specific subsidies required to support a Renewable Portfolio Standard (RPS) goal. The financial requirements are calculated (in two scenarios) and compared with predictable funds from public sources. A main result is that the expected investments to achieve the RPS goal far exceed the economic allocation for subsidy of distributed PV. Even with subsidies there are often challenges with social acceptance. The third part of this dissertation originally develops a fuzzy logic inference model to relate consumers' attitudes about the technology such as perceived cost, maintenance, and environmental concern to their adoption intention. Fuzzy logic inference model is a type of soft computing models. It has the advantage of dealing with imprecise and insufficient information and mimicking reasoning processes of human brains. This model is implemented in a case study of residential PV adoption using data through a survey of homeowners in Arizona. The output of this model is the purchasing probability of PV.
ContributorsZhai, Pei (Author) / Williams, Eric D. (Thesis advisor) / Allenby, Braden (Committee member) / Phelan, Patrick (Committee member) / Arizona State University (Publisher)
Created2010
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Description

This paper discusses the theoretical approximation and attempted measurement of the quantum <br/>force produced by material interactions though the use of a tuning fork-based atomic force microscopy <br/>device. This device was built and orientated specifically for the measurement of the Casimir force as a <br/>function of separation distance using a

This paper discusses the theoretical approximation and attempted measurement of the quantum <br/>force produced by material interactions though the use of a tuning fork-based atomic force microscopy <br/>device. This device was built and orientated specifically for the measurement of the Casimir force as a <br/>function of separation distance using a piezo actuator for approaching and a micro tuning fork for the <br/>force measurement. This project proceeds with an experimental measurement of the ambient Casmir force <br/>through the use of a tuning fork-based AFM to determine its viability in measuring the magnitude of the <br/>force interaction between an interface material and the tuning fork probe. The ambient measurements <br/>taken during the device’s development displayed results consistent with theoretical approximations, while<br/>demonstrating the capability to perform high-precision force measurements. The experimental results<br/>concluded in a successful development of a device which has the potential to measure forces of <br/>magnitude 10−6 to 10−9 at nanometric gaps. To conclude, a path to material analysis using an approach <br/>stage, alternative methods of testing, and potential future experiments are speculated upon.

ContributorsMulkern, William Michael (Author) / Wang, Liping (Thesis director) / Kwon, Beomjin (Committee member) / Mechanical and Aerospace Engineering Program (Contributor) / Barrett, The Honors College (Contributor)
Created2021-05
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Water heaters that are manufactured for swimming pools come in several forms, most of which require an electrical input for a source of power. Passive-circulation systems, however, require no electrical power input because fluid circulation occurs as a result of thermal gradients. In solar-based systems, thermal gradients are developed by

Water heaters that are manufactured for swimming pools come in several forms, most of which require an electrical input for a source of power. Passive-circulation systems, however, require no electrical power input because fluid circulation occurs as a result of thermal gradients. In solar-based systems, thermal gradients are developed by energy collected from sunlight. The combination of solar collection and passive circulation yields a system in which fluids, particularly water, are heated and circulated without need of assistance from external mechanical or electrical sources. The design of such a system was adapted from that of forced-circulation solar collector systems, as were the equations describing its thermodynamic properties. The design was developed based on such constraints as material corrosion resistance, overall system cost, and location-controlled size limitations. The thermodynamic description of the designed system was adjusted on the basis of the designed system’s physical aspects, such as the configuration and material of each component within the solar collector. Numerical analysis performed with the altered thermodynamic equations projected a total energy gain of 7.39 W between 9:00 and 10:00 A.M. and a total energy gain of 13.12 W between 4:00 and 5:00 P.M. The temperature of heated water exiting the collector system was projected to be 17.62°C in the morning and 25.56°C in the afternoon. The morning projection utilized an initial fluid temperature of 12°C and an ambient air temperature of 13°C, while the afternoon projection utilized an initial fluid temperature of 17°C and an ambient air temperature of 22°C. Field testing of the designed passive thermosyphon solar collector system was performed over a period of about one month with one temperature measurement taken at the collector outlet in the morning and another taken in the afternoon. For an ambient air temperature of 13°C, the linear regression developed from the morning dataset yielded an outlet water temperature of 20°C and that for the afternoon dataset yielded an outlet water temperature of 39°C for an ambient air temperature of 17°C. The percentage error between the projected and measured results was 13.51% for the morning period and 52.58% for the afternoon period. Numerical simulation and field data demonstrated that while the collector system operated successfully, its effects were limited to the volume of water immediately surrounding the outlet of the system; the rate of circulation within the system was too low for there to be a meaningful increase in the temperature of the water body at large. The stated results demonstrate that while the particular configuration of passive circulation solar collection technology developed in this instance is capable of transferring solar thermal energy to water without additional energy sources, significant modifications are necessary in order to improve the effectiveness of the technology. Such changes may come from improvements in material availability or alterations to the configuration of components of the collector system.

ContributorsZimmerman, Julia Elizabeth (Author) / Garcia, Margaret (Thesis director) / Phelan, Patrick (Committee member) / Civil, Environmental and Sustainable Eng Program (Contributor) / Barrett, The Honors College (Contributor)
Created2021-05
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Description

This paper investigates near-field thermal radiation as the primary source of heat transfer between two parallel surfaces. This radiation takes place extremely close to the heated surfaces in study so the experimental set-up to be used will be done at the nanometer scale. The primary theory being investigated is that

This paper investigates near-field thermal radiation as the primary source of heat transfer between two parallel surfaces. This radiation takes place extremely close to the heated surfaces in study so the experimental set-up to be used will be done at the nanometer scale. The primary theory being investigated is that near-field radiation generates greater heat flux that conventional radiation governed by Planck’s law with maximum for blackbodies. Working with a phase shift material such as VO2 enables a switch-like effect to occur where the total amount of heat flux fluctuates as VO2 transitions from a metal to an insulator. In this paper, the theoretical heat flux and near-field radiation effect are modeled for a set-up of VO2 and SiO2 layers separated by different vacuum gaps. In addition, a physical experimental set-up is validated for future near-field radiation experiments.

ContributorsSluder, Nicole (Author) / Wang, Liping (Thesis director) / Wang, Ropert (Committee member) / Mechanical and Aerospace Engineering Program (Contributor, Contributor) / Barrett, The Honors College (Contributor)
Created2021-05
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Description
This study analyzes the thermoelectric phenomena of nanoparticle suspensions, which are composed of liquid and solid nanoparticles that show a relatively stable Seebeck coefficient as bulk solids near room temperature. The approach is to explore the thermoelectric character of the nanoparticle suspensions, predict the outcome of the experiment and compare

This study analyzes the thermoelectric phenomena of nanoparticle suspensions, which are composed of liquid and solid nanoparticles that show a relatively stable Seebeck coefficient as bulk solids near room temperature. The approach is to explore the thermoelectric character of the nanoparticle suspensions, predict the outcome of the experiment and compare the experimental data with anticipated results. In the experiment, the nanoparticle suspension is contained in a 15cm*2.5cm*2.5cm glass container, the temperature gradient ranges from 20 °C to 60 °C, and room temperature fluctuates from 20 °C to 23°C. The measured nanoparticles include multiwall carbon nanotubes, aluminum dioxide and bismuth telluride. A temperature gradient from 20 °C to 60 °C is imposed along the length of the container, and the resulting voltage (if any) is measured. Both heating and cooling processes are measured. With three different nanoparticle suspensions (carbon nano tubes, Al2O3 nanoparticles and Bi2Te3 nanoparticles), the correlation between temperature gradient and voltage is correspondingly 8%, 38% and 96%. A comparison of results calculated from the bulk Seebeck coefficients with our measured results indicate that the Seebeck coefficient measured for each suspension is much more than anticipated, which indicates that the thermophoresis effect could have enhanced the voltage. Further research with a closed-loop system might be able to affirm the results of this study.
ContributorsZhu, Moxuan (Author) / Phelan, Patrick (Thesis advisor) / Trimble, Steve (Committee member) / Prasher, Ravi (Committee member) / Arizona State University (Publisher)
Created2010
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Description
Phase Change Material (PCM) plays an important role as a thermal energy storage device by utilizing its high storage density and latent heat property. One of the potential applications for PCM is in buildings by incorporating them in the envelope for energy conservation. During the summer season, the benefits are

Phase Change Material (PCM) plays an important role as a thermal energy storage device by utilizing its high storage density and latent heat property. One of the potential applications for PCM is in buildings by incorporating them in the envelope for energy conservation. During the summer season, the benefits are a decrease in overall energy consumption by the air conditioning unit and a time shift in peak load during the day. Experimental work was carried out by Arizona Public Service (APS) in collaboration with Phase Change Energy Solutions (PCES) Inc. with a new class of organic-based PCM. This "BioPCM" has non-flammable properties and can be safely used in buildings. The experimental setup showed maximum energy savings of about 30%, a maximum peak load shift of ~ 60 min, and maximum cost savings of about 30%. Simulation was performed to validate the experimental results. EnergyPlus was chosen as it has the capability to simulate phase change material in the building envelope. The building material properties were chosen from the ASHRAE Handbook - Fundamentals and the HVAC system used was a window-mounted heat pump. The weather file used in the simulation was customized for the year 2008 from the National Renewable Energy Laboratory (NREL) website. All EnergyPlus inputs were ensured to match closely with the experimental parameters. The simulation results yielded comparable trends with the experimental energy consumption values, however time shifts were not observed. Several other parametric studies like varying PCM thermal conductivity, temperature range, location, insulation R-value and combination of different PCMs were analyzed and results are presented. It was found that a PCM with a melting point from 23 to 27 °C led to maximum energy savings and greater peak load time shift duration, and is more suitable than other PCM temperature ranges for light weight building construction in Phoenix.
ContributorsMuruganantham, Karthik (Author) / Phelan, Patrick (Thesis advisor) / Reddy, Agami (Committee member) / Lee, Taewoo (Committee member) / Arizona State University (Publisher)
Created2010
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Description
Efficient performance of gas turbines depends, among several parameters, on the mainstream gas entry temperature. At the same time, transport of this high temperature gas into the rotor-stator cavities of turbine stages affects the durability of rotor disks. This transport is usually countered by installing seals on the rotor and

Efficient performance of gas turbines depends, among several parameters, on the mainstream gas entry temperature. At the same time, transport of this high temperature gas into the rotor-stator cavities of turbine stages affects the durability of rotor disks. This transport is usually countered by installing seals on the rotor and stator disk rims and by pressurizing the cavities by injecting air (purge gas) bled from the compressor discharge. The configuration of the rim seals influences the magnitude of main gas ingestion as well as the interaction of the purge gas with the main gas. The latter has aerodynamic and hub endwall heat transfer implications in the main gas path. In the present work, experiments were performed on model single-stage and 1.5-stage axial-flow turbines. The turbines featured vanes, blades, and rim seals on both the rotor and stator disks. Three different rim seal geometries, viz., axially overlapping radial clearance rim seals for the single-stage turbine cavity and the 1.5-stage turbine aft cavity, and a rim seal with angular clearance for the single-stage turbine cavity were studied. In the single-stage turbine, an inner seal radially inboard in the cavity was also provided; this effectively divided the disk cavity into a rim cavity and an inner cavity. For the aft rotor-stator cavity of the 1.5-stage turbine, a labyrinth seal was provided radially inboard, again creating a rim cavity and an inner cavity. Measurement results of time-average main gas ingestion into the cavities using tracer gas (CO2), and ensemble-averaged trajectories of the purge gas flowing out through the rim seal gap into the main gas path using particle image velocimetry are presented. For both turbines, significant ingestion occurred only in the rim cavity. The inner cavity was almost completely sealed by the inner seal, at all purge gas flow rates for the single-stage turbine and at the higher purge gas flow rates for 1.5-stage turbine. Purge gas egress trajectory was found to depend on main gas and purge gas flow rates, the rim seal configuration, and the azimuthal location of the trajectory mapping plane with respect to the vanes.
ContributorsBalasubramanian, Jagdish Harihara (Author) / Roy, Ramendra P (Thesis advisor) / Lee, Taewoo (Committee member) / Phelan, Patrick (Committee member) / Arizona State University (Publisher)
Created2010