Hydrology and biogeochemistry are coupled in all systems. However, human decision-making regarding hydrology and biogeochemistry are often separate, even though decisions about hydrologic systems may have substantial impacts on biogeochemical patterns and processes. The overarching question of this dissertation was: How does hydrologic engineering interact with the effects of nutrient loading and climate to drive watershed nutrient yields? I conducted research in two study systems with contrasting spatial and temporal scales. Using a combination of data-mining and modeling approaches, I reconstructed nitrogen and phosphorus budgets for the northeastern US over the 20th century, including anthropogenic nutrient inputs and riverine fluxes, for ~200 watersheds at 5 year time intervals. Infrastructure systems, such as sewers, wastewater treatment plants, and reservoirs, strongly affected the spatial and temporal patterns of nutrient fluxes from northeastern watersheds. At a smaller scale, I investigated the effects of urban stormwater drainage infrastructure on water and nutrient delivery from urban watersheds in Phoenix, AZ. Using a combination of field monitoring and statistical modeling, I tested hypotheses about the importance of hydrologic and biogeochemical control of nutrient delivery. My research suggests that hydrology is the major driver of differences in nutrient fluxes from urban watersheds at the event scale, and that consideration of altered hydrologic networks is critical for understanding anthropogenic impacts on biogeochemical cycles. Overall, I found that human activities affect nutrient transport via multiple pathways. Anthropogenic nutrient additions increase the supply of nutrients available for transport, whereas hydrologic infrastructure controls the delivery of nutrients from watersheds. Incorporating the effects of hydrologic infrastructure is critical for understanding anthropogenic effects on biogeochemical fluxes across spatial and temporal scales.

Field observations were carried out to determine the influence of a park on the urban summer climate in the nearby areas. The possibilities of reduction in air conditioning energy were investigated. Air temperature, relative humidity and other meteorological factors were measured at many locations inside a park and in the surrounding areas in the Tama New Town, a city in the west of the Tokyo Metropolitan Area, Japan. The observations indicated that vegetation could significantly alter the climate in the town. At noon, the highest temperature of the ground surface of the grass field in the park was 40.3 °C, which was 19 °C lower than that of the asphalt surface or 15 °C lower than that of the concrete surface in the parking or commercial areas. At the same time, air temperature measured at 1.2 m above the ground at the grass field inside the park was more than 2 °C lower than that measured at the same height in the surrounding commercial and parking areas. Soon after sunset, the temperature of the ground surface at the grass field in the park became lower than that of the air, and the park became a cool island whereas paved asphalt or concrete surfaces in the town remained hotter than the overlying air even late at night. With a size of about 0.6 km2, at noon, the park can reduce by up to 1.5 °C the air temperature in a busy commercial area 1 km downwind. This can lead to a significant decrease of in air conditioning energy in the commercial area.