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- Genre: Masters Thesis
- Creators: Holbert, Keith E.
- Creators: Tamizhmani, Govindasamy
Description
Encapsulant is a key packaging component of photovoltaic (PV) modules, which protects the solar cell from physical, environmental and electrical damages. Ethylene-vinyl acetate (EVA) is one of the major encapsulant materials used in the PV industry. This work focuses on indoor accelerated ultraviolet (UV) stress testing and characterization to investigate the EVA discoloration and delamination in PV modules by using various non-destructive characterization techniques, including current-voltage (IV) measurements, UV fluorescence (UVf) and colorimetry measurements. Mini-modules with glass/EVA/cell/EVA/backsheet construction were fabricated in the laboratory with two types of EVA, UV-cut EVA (UVC) and UV-pass EVA (UVP).
The accelerated UV testing was performed in a UV chamber equipped with UV lights at an ambient temperature of 50°C, little or no humidity and total UV dosage of 400 kWh/m2. The mini-modules were maintained at three different temperatures through UV light heating by placing different thickness of thermal insulation sheets over the backsheet. Also, prior to thermal insulation sheet placement, the backsheet and laminate edges were fully covered with aluminum tape to prevent oxygen diffusion into the module and hence the photobleaching reaction.
The characterization results showed that mini-modules with UV-cut EVA suffered from discoloration while the modules with UV-pass EVA suffered from delamination. UVf imaging technique has the capability to identify the discoloration region in the UVC modules in the very early stage when the discoloration is not visible to the naked eyes, whereas Isc measurement is unable to measure the performance loss until the color becomes visibly darker. YI also provides the direct evidence of yellowing in the encapsulant. As expected, the extent of degradation due to discoloration increases with the increase in module temperature. The Isc loss is dictated by both the regions – discolored area at the center and non-discolored area at the cell edges, whereas the YI is only determined at the discolored region due to low probe area. This led to the limited correlation between Isc and YI in UVC modules.
In case of UVP modules, UV radiation has caused an adverse impact on the interfacial adhesion between the EVA and solar cell, which was detected from UVf images and severe Isc loss. No change in YI confirms that the reason for Isc loss is not due to yellowing but the delamination.
Further, the activation energy of encapsulant discoloration was estimated by using Arrhenius model on two types of data, %Isc drop and ΔYI. The Ea determined from the change in YI data for the EVA encapsulant discoloration reaction without the influence of oxygen and humidity is 0.61 eV. Based on the activation energy determined in this work and hourly weather data of any site, the degradation rate for the encaspulant browning mode can be estimated.
The accelerated UV testing was performed in a UV chamber equipped with UV lights at an ambient temperature of 50°C, little or no humidity and total UV dosage of 400 kWh/m2. The mini-modules were maintained at three different temperatures through UV light heating by placing different thickness of thermal insulation sheets over the backsheet. Also, prior to thermal insulation sheet placement, the backsheet and laminate edges were fully covered with aluminum tape to prevent oxygen diffusion into the module and hence the photobleaching reaction.
The characterization results showed that mini-modules with UV-cut EVA suffered from discoloration while the modules with UV-pass EVA suffered from delamination. UVf imaging technique has the capability to identify the discoloration region in the UVC modules in the very early stage when the discoloration is not visible to the naked eyes, whereas Isc measurement is unable to measure the performance loss until the color becomes visibly darker. YI also provides the direct evidence of yellowing in the encapsulant. As expected, the extent of degradation due to discoloration increases with the increase in module temperature. The Isc loss is dictated by both the regions – discolored area at the center and non-discolored area at the cell edges, whereas the YI is only determined at the discolored region due to low probe area. This led to the limited correlation between Isc and YI in UVC modules.
In case of UVP modules, UV radiation has caused an adverse impact on the interfacial adhesion between the EVA and solar cell, which was detected from UVf images and severe Isc loss. No change in YI confirms that the reason for Isc loss is not due to yellowing but the delamination.
Further, the activation energy of encapsulant discoloration was estimated by using Arrhenius model on two types of data, %Isc drop and ΔYI. The Ea determined from the change in YI data for the EVA encapsulant discoloration reaction without the influence of oxygen and humidity is 0.61 eV. Based on the activation energy determined in this work and hourly weather data of any site, the degradation rate for the encaspulant browning mode can be estimated.
ContributorsDolia, Kshitiz (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Green, Matthew (Thesis advisor) / Srinivasan, Devarajan (Committee member) / Arizona State University (Publisher)
Created2018
Description
The volume of end-of-life photovoltaic (PV) modules is increasing as the global PV market increases, and the global PV waste streams are expected to reach 250,000 metric tons by the end of 2020. If the recycling processes are not in place, there would be 60 million tons of end-of-life PV modules lying in the landfills by 2050, that may not become a not-so-sustainable way of sourcing energy since all PV modules could contain certain amount of toxic substances. Currently in the United States, PV modules are categorized as general waste and can be disposed in landfills. However, potential leaching of toxic chemicals and materials, if any, from broken end-of-life modules may pose health or environmental risks. There is no standard procedure to remove samples from PV modules for chemical toxicity testing in the Toxicity Characteristic Leaching Procedure (TCLP) laboratories as per EPA 1311 standard. The main objective of this thesis is to develop an unbiased sampling approach for the TCLP testing of PV modules. The TCLP testing was concentrated only for the laminate part of the modules, as they are already existing recycling technologies for the frame and junction box components of PV modules. Four different sample removal methods have been applied to the laminates of five different module manufacturers: coring approach, cell-cut approach, strip-cut approach, and hybrid approach. These removed samples were sent to two different TCLP laboratories, and TCLP results were tested for repeatability within a lab and reproducibility between the labs. The pros and cons of each sample removal method have been explored and the influence of sample removal methods on the variability of TCLP results has been discussed. To reduce the variability of TCLP results to an acceptable level, additional improvements in the coring approach, the best of the four tested options, are still needed.
ContributorsLeslie, Joswin (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Srinivasan, Devarajan (Committee member) / Kuitche, Joseph (Committee member) / Arizona State University (Publisher)
Created2018
Description
Concrete is relatively brittle, and its tensile strength is typically only about one-tenth of its compressive strength. Regular concrete is therefore normally uses reinforcement steel bars to increase the tensile strength. It is becoming increasingly popular to use random distributed fibers as reinforcement and polymeric fibers is once such kind. In the case of polymeric fibers, due to hydrophobicity and lack of any chemical bond between the fiber and matrix, the weak interface zone limits the ability of the fibers to effectively carry the load that is on the matrix phase. Depending on the fiber’s surface asperity, shape, chemical nature, and mechanical bond characteristic of the load transfer between matrix and fiber can be altered so that the final composite can be improved. These modifications can be carried out by means of thermal treatment, mechanical surface modifications, or chemical changes The objective of this study is to measure and document the effect of gamma ray irradiation on the mechanical properties of macro polymeric fibers. The objective is to determine the mechanical properties of macro-synthetic fibers and develop guidelines for treatment and characterization that allow for potential positive changes due to exposure to irradiation. Fibers are exposed to various levels of ionizing radiation and the tensile, interface and performance in a mortar matrix are documented. Uniaxial tensile tests were performed on irradiated fibers to study fiber strength and failure pattern. SEM tests were carried out in order to study the surface characteristic and effect of different radiation dose on polymeric fiber. The interaction of the irradiated fiber with the cement composite was studied by a series of quasi-static pullout test for a specific embedded length. As a final task, flexural tests were carried out for different irradiated fibers to sum up the investigation. An average increase of 13% in the stiffness of the fiber was observed for 5 kGy of radiation. Flexural tests showed an average increase of 181% in the Req3 value and 102 % in the toughness of the sample was observed for 5 kGy of dose.
ContributorsTiwari, Sanchay Sushil (Author) / Mobasher, Barzin (Thesis advisor) / Neithalath, Narayanan (Thesis advisor) / Dharmarajan, Subramaniam (Committee member) / Holbert, Keith E. (Committee member) / Arizona State University (Publisher)
Created2018
Description
Alternative sources of power generation interconnected at the transmission level have witnessed an increase in investment in the last few years. On the other hand, when the power systems are being operated close to their limits, power system operators and engineers face the challenge of ensuring a safe and reliable supply of electricity. In such a scenario, the reliability of the transmission system is crucial as it ensures secure transfer of uninterrupted power from the generating sources to the load centers. This thesis is aimed at ensuring the reliability of the transmission system from two perspectives. First, this work monitors power system disturbances such as unintentional islanding to ensure prompt detection and implementation of restorative actions and thus, minimizes the extent of damage. Secondly, it investigates power system disturbances such as transmission line outages through reliability evaluation and outage analysis in order to prevent reoccurrence of similar failures.
In this thesis, a passive Wide Area Measurement System (WAMS) based islanding detection scheme called Cumulative Sum of Change in Voltage Phase Angle Difference (CUSPAD) is proposed and tested on a modified 18 bus test system and a modified IEEE 118 bus system with various wind energy penetration levels. Comparative analysis between accuracies of the proposed approach and the conventional relative angle difference approach in presence of measurement errors indicate a superior performance of the former. Results obtained from the proposed approach also reveal that power system disturbances such as unintentional island formations are accurately detected in wind integrated transmission systems.
Quantitative evaluation of the transmission system reliability aids in the assessment of the existing system performance. Further, post-mortem analysis of failures is an important step in minimizing recurrent failures. Reliability evaluation and outage analysis of transmission line outages carried out in this thesis have revealed chronological trends in the system performance. A new index called Outage Impact Index (OII) is also been proposed which can identify and prioritize outages based on their severity. This would serve as a baselining index for assessing and monitoring future transmission system performances and will facilitate implementation of reliability improvement measures if found necessary.
In this thesis, a passive Wide Area Measurement System (WAMS) based islanding detection scheme called Cumulative Sum of Change in Voltage Phase Angle Difference (CUSPAD) is proposed and tested on a modified 18 bus test system and a modified IEEE 118 bus system with various wind energy penetration levels. Comparative analysis between accuracies of the proposed approach and the conventional relative angle difference approach in presence of measurement errors indicate a superior performance of the former. Results obtained from the proposed approach also reveal that power system disturbances such as unintentional island formations are accurately detected in wind integrated transmission systems.
Quantitative evaluation of the transmission system reliability aids in the assessment of the existing system performance. Further, post-mortem analysis of failures is an important step in minimizing recurrent failures. Reliability evaluation and outage analysis of transmission line outages carried out in this thesis have revealed chronological trends in the system performance. A new index called Outage Impact Index (OII) is also been proposed which can identify and prioritize outages based on their severity. This would serve as a baselining index for assessing and monitoring future transmission system performances and will facilitate implementation of reliability improvement measures if found necessary.
ContributorsBarkakati, Meghna (Author) / Pal, Anamitra (Thesis advisor) / Holbert, Keith E. (Committee member) / Weng, Yang (Committee member) / Arizona State University (Publisher)
Created2018
Description
The lifetime of a transformer is essentially determined by the life of its insulation
system which is a time function of the temperature defined by its thermal class. A large
quantity of studies and international standards have been published indicating the
possibility of increasing the thermal class of cellulose based materials when immersed
in natural esters which are superior to traditional mineral oils. Thus, a transformer
having thermally upgraded Kraft paper and natural ester dielectric fluid can be
classified as a high temperature insulation system. Such a transformer can also
operate at temperatures 20C higher than its mineral oil equivalent, holding additional
loading capability without losing life expectancy. This thesis focuses on evaluating
the use of this feature as an additional capability for enhancing the loadability and/or
extending the life of the distribution transformers for the Phoenix based utility - SRP
using FR3 brand natural ester dielectric fluid.
Initially, different transformer design options to use this additional loadability
are compared allowing utilities to select an optimal FR3 filled transformer design
for their application. Yearlong load profiles for SRP distribution transformers, sized
conventionally on peak load demands, are analyzed for their oil temperatures, winding
temperatures and loss of insulation life. It is observed that these load profiles can be
classified into two types: 1) Type-1 profiles with high peak and high average loads,
and 2) Type-2 profiles with comparatively low peak and low average load.
For the Type 1 load profiles, use of FR3 natural ester fluid with the same nominal
rating showed 7.4 times longer life expectation. For the Type 2 load profiles, a new
way of sizing ester filled transformers based on both average and peak load, instead of
only peak load, called “Sustainable Peak Loading” showed smaller size transformers
can handle the same yearly peak loads while maintaining superior insulation lifespan.
It is additionally possible to have reduction in the total energy dissipation over the
year. A net present value cost savings up to US$1200 per transformer quantifying
benefits of the life extension and the total ownership cost savings up to 30% for
sustainable peak loading showed SRP distribution transformers can gain substantial
economic savings when the distribution transformer fleet is replaced with FR3 ester
filled units.
system which is a time function of the temperature defined by its thermal class. A large
quantity of studies and international standards have been published indicating the
possibility of increasing the thermal class of cellulose based materials when immersed
in natural esters which are superior to traditional mineral oils. Thus, a transformer
having thermally upgraded Kraft paper and natural ester dielectric fluid can be
classified as a high temperature insulation system. Such a transformer can also
operate at temperatures 20C higher than its mineral oil equivalent, holding additional
loading capability without losing life expectancy. This thesis focuses on evaluating
the use of this feature as an additional capability for enhancing the loadability and/or
extending the life of the distribution transformers for the Phoenix based utility - SRP
using FR3 brand natural ester dielectric fluid.
Initially, different transformer design options to use this additional loadability
are compared allowing utilities to select an optimal FR3 filled transformer design
for their application. Yearlong load profiles for SRP distribution transformers, sized
conventionally on peak load demands, are analyzed for their oil temperatures, winding
temperatures and loss of insulation life. It is observed that these load profiles can be
classified into two types: 1) Type-1 profiles with high peak and high average loads,
and 2) Type-2 profiles with comparatively low peak and low average load.
For the Type 1 load profiles, use of FR3 natural ester fluid with the same nominal
rating showed 7.4 times longer life expectation. For the Type 2 load profiles, a new
way of sizing ester filled transformers based on both average and peak load, instead of
only peak load, called “Sustainable Peak Loading” showed smaller size transformers
can handle the same yearly peak loads while maintaining superior insulation lifespan.
It is additionally possible to have reduction in the total energy dissipation over the
year. A net present value cost savings up to US$1200 per transformer quantifying
benefits of the life extension and the total ownership cost savings up to 30% for
sustainable peak loading showed SRP distribution transformers can gain substantial
economic savings when the distribution transformer fleet is replaced with FR3 ester
filled units.
ContributorsVaidya, Chinmay Vishwas (Author) / Holbert, Keith E. (Thesis advisor) / Ayyanar, Raja (Committee member) / Pal, Anamitra (Committee member) / Arizona State University (Publisher)
Created2018
Description
Transmission line parameters play an important role in state estimation, dynamic line rating, and fault analysis. Because of this, several methods have been proposed in the literature for line parameter estimation, especially using synchrophasor data. However, success of most prior research has been demonstrated using purely synthetic data. A synthetic dataset does not have the problems encountered with real data, such as invariance of measurements and realistic field noise. Therefore, the algorithms developed using synthetic datasets may not be as effective when used in practice. On the other hand, the true values of the line parameters are unknown and therefore the algorithms cannot be directly implemented on real data. A multi-stage test procedure is developed in this work to circumvent this problem.
In this thesis, two popular algorithms, namely, moving-window total least squares (MWTLS) and recursive Kalman filter (RKF) are applied on real data in multiple stages. In the first stage, the algorithms are tested on a purely synthetic dataset. This is followed by testing done on pseudo-synthetic datasets generated using real PMU data. In the final stage, the algorithms are implemented on the real PMU data obtained from a local utility. The results show that in the context of the given problem, RKF has better performance than MWTLS. Furthermore, to improve the performance of RKF on real data, ASPEN data are used to calculate the initial estimates. The estimation results show that the RKF algorithm can reliably estimate the sequence impedances, using ASPEN data as a starting condition. The estimation procedure is repeated over different time periods and the corresponding results are presented.
Finally, the significance of data drop-outs and its impact on the use of parameter estimates for real-time power system applications, such as state estimation and dynamic line rating, is discussed. To address the problem (of data drop-outs), an auto regressive integrated moving average (ARIMA) model is implemented. The ability of this model to predict the variations in sequence impedances is demonstrated.
In this thesis, two popular algorithms, namely, moving-window total least squares (MWTLS) and recursive Kalman filter (RKF) are applied on real data in multiple stages. In the first stage, the algorithms are tested on a purely synthetic dataset. This is followed by testing done on pseudo-synthetic datasets generated using real PMU data. In the final stage, the algorithms are implemented on the real PMU data obtained from a local utility. The results show that in the context of the given problem, RKF has better performance than MWTLS. Furthermore, to improve the performance of RKF on real data, ASPEN data are used to calculate the initial estimates. The estimation results show that the RKF algorithm can reliably estimate the sequence impedances, using ASPEN data as a starting condition. The estimation procedure is repeated over different time periods and the corresponding results are presented.
Finally, the significance of data drop-outs and its impact on the use of parameter estimates for real-time power system applications, such as state estimation and dynamic line rating, is discussed. To address the problem (of data drop-outs), an auto regressive integrated moving average (ARIMA) model is implemented. The ability of this model to predict the variations in sequence impedances is demonstrated.
ContributorsMansani, Prashanth Kumar (Author) / Pal, Anamitra (Thesis advisor) / Holbert, Keith E. (Committee member) / Tylavsky, Daniel (Committee member) / Arizona State University (Publisher)
Created2018
Description
In the past, the photovoltaic (PV) modules were typically constructed with glass superstrate containing cerium oxide and EVA (ethylene vinyl acetate) encapsulant containing UV absorbing additives. However, in the current industry, the PV modules are generally constructed without cerium oxide in the glass and UV absorbing additives in EVA to increase quantum efficiency of crystalline silicon solar cells in the UV regions. This new approach is expected to boost the initial power output of the modules and reduce the long-term encapsulant browning issues. However, this new approach could lead to other durability and reliability issues such as delamination of encapsulant by damaging interfacial bonds, destruction of antireflection coating on solar cells and even breakage of polymeric backbone of EVA. This work compares the durability and reliability issues of PV modules having glass without cerium oxide and EVA with (aka, UVcut or UVC) and without (aka, UVpass or UVP) UV absorbing additives. In addition, modules with UVP front and UVC back EVA have also been investigated (aka, UVhybrid or UVH). The mini-modules with nine split cells used in this work were fabricated at ASU’s Photovoltaic Reliability Laboratory. The durability and reliability caused by three stress variables have been investigated and the three variables are temperature, humidity/oxygen and UV dosage. The influence of up to 800 kWh/m2 UV dosage has been investigated at various dosage levels. Many material and device characterizations have been performed to ascertain the degradation modes and effects. The UVC modules showed encapsulant discoloration at the cell centers as expected but the UVH modules showed a ring-shaped encapsulant discoloration close to the cell edges as evidenced in the UV fluorescence (UVF) imaging study. The PV modules containing UVP on both sides of cells with limited access to humidity or oxygen through backsheet (covered backsheet with adhesive aluminum tape) seem to experience encapsulant delamination as evidenced in the UVF images. Plausible explanations for these observations have been presented.
ContributorsArularasu, Pooja (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Mu, Bin (Thesis advisor) / Varman, Arul M (Committee member) / Arizona State University (Publisher)
Created2019
Description
Ethylene vinyl acetate (EVA) is the most commonly used encapsulant in photovoltaic modules. However, EVA degrades over time and causes performance losses in PV system. Therefore, EVA degradation is a matter of concern from a durability point of view.
This work compares EVA encapsulant degradation in glass/backsheet and glass/glass field-aged PV modules. EVA was extracted from three field-aged modules (two glass/backsheet and one glass/glass modules) from three different manufacturers from various regions (cell edges, cell centers, and non-cell region) from each module based on their visual and UV Fluorescence images. Characterization techniques such as I-V measurements, Colorimetry, Different Scanning Calorimetry, Thermogravimetric Analysis, Raman spectroscopy, and Fourier Transform Infrared Spectroscopy were performed on EVA samples.
The intensity of EVA discoloration was quantified using colorimetric measurements. Module performance parameters like Isc and Pmax degradation rates were calculated from I-V measurements. Properties such as degree of crystallinity, vinyl acetate content and degree of crosslinking were calculated from DSC, TGA, and Raman measurements, respectively. Polyenes responsible for EVA browning were identified in FTIR spectra.
The results from the characterization techniques confirmed that when EVA undergoes degradation, crosslinking in EVA increases beyond 90% causing a decrease in the degree of crystallinity and an increase in vinyl acetate content of EVA. Presence of polyenes in FTIR spectra of degraded EVA confirmed the occurrence of Norrish II reaction. However, photobleaching occurred in glass/backsheet modules due to the breathable backsheet whereas no photobleaching occurred in glass/glass modules because they were hermetically sealed. Hence, the yellowness index along with the Isc and Pmax degradation rates of EVA in glass/glass module is higher than that in glass/backsheet modules.
The results implied that more acetic acid was produced in the non-cell region due to its double layer of EVA compared to the front EVA from cell region. But, since glass/glass module is hermetically sealed, acetic acid gets entrapped inside the module further accelerating EVA degradation whereas it diffuses out through backsheet in glass/backsheet modules. Hence, it can be said that EVA might be a good encapsulant for glass/backsheet modules, but the same cannot be said for glass/glass modules.
This work compares EVA encapsulant degradation in glass/backsheet and glass/glass field-aged PV modules. EVA was extracted from three field-aged modules (two glass/backsheet and one glass/glass modules) from three different manufacturers from various regions (cell edges, cell centers, and non-cell region) from each module based on their visual and UV Fluorescence images. Characterization techniques such as I-V measurements, Colorimetry, Different Scanning Calorimetry, Thermogravimetric Analysis, Raman spectroscopy, and Fourier Transform Infrared Spectroscopy were performed on EVA samples.
The intensity of EVA discoloration was quantified using colorimetric measurements. Module performance parameters like Isc and Pmax degradation rates were calculated from I-V measurements. Properties such as degree of crystallinity, vinyl acetate content and degree of crosslinking were calculated from DSC, TGA, and Raman measurements, respectively. Polyenes responsible for EVA browning were identified in FTIR spectra.
The results from the characterization techniques confirmed that when EVA undergoes degradation, crosslinking in EVA increases beyond 90% causing a decrease in the degree of crystallinity and an increase in vinyl acetate content of EVA. Presence of polyenes in FTIR spectra of degraded EVA confirmed the occurrence of Norrish II reaction. However, photobleaching occurred in glass/backsheet modules due to the breathable backsheet whereas no photobleaching occurred in glass/glass modules because they were hermetically sealed. Hence, the yellowness index along with the Isc and Pmax degradation rates of EVA in glass/glass module is higher than that in glass/backsheet modules.
The results implied that more acetic acid was produced in the non-cell region due to its double layer of EVA compared to the front EVA from cell region. But, since glass/glass module is hermetically sealed, acetic acid gets entrapped inside the module further accelerating EVA degradation whereas it diffuses out through backsheet in glass/backsheet modules. Hence, it can be said that EVA might be a good encapsulant for glass/backsheet modules, but the same cannot be said for glass/glass modules.
ContributorsPatel, Aesha Parimalbhai (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Green, Matthew (Committee member) / Mu, Bin (Committee member) / Arizona State University (Publisher)
Created2018
Description
Global photovoltaic (PV) module installation in 2018 is estimated to exceed 100 GW, and crystalline Si (c-Si) solar cell-based modules have a share more than 90% of the global PV market. To reduce the social cost of PV electricity, further developments in reliability of solar panels are expected. These will lead to realize longer module lifetime and reduced levelized cost of energy. As many as 86 failure modes are observed in PV modules [1] and series resistance increase is one of the major durability issues of all. Series resistance constitutes emitter sheet resistance, metal-semiconductor contact resistance, and resistance across the metal-solder ribbon. Solder bond degradation at the cell interconnect is one of the primary causes for increase in series resistance, which is also considered to be an invisible defect [1]. Combination of intermetallic compounds (IMC) formation during soldering and their growth due to solid state diffusion over its lifetime result in formation of weak interfaces between the solar cell and the interconnect. Thermal cycling under regular operating conditions induce thermo-mechanical fatigue over these weak interfaces resulting in contact reduction or loss. Contact reduction or loss leads to increase in series resistance which further manifests into power and fill factor loss. The degree of intermixing of metallic interfaces and contact loss depends on climatic conditions as temperature and humidity (moisture ingression into the PV module laminate) play a vital role in reaction kinetics of these layers. Modules from Arizona and Florida served as a good sample set to analyze the effects of hot and humid climatic conditions respectively. The results obtained in the current thesis quantifies the thickness of IMC formation from SEM-EDS profiles, where similar modules obtained from different climatic conditions were compared. The results indicate the thickness of the IMC and detachment degree to be growing with age and operating temperatures of the module. This can be seen in CuxSny IMC which is thicker in the case of Arizona module. The results obtained from FL
ii
aged modules also show that humidity accelerates the formation of IMC as they showed thicker AgxSny layer and weak interconnect-contact interfaces as compared to Arizona modules. It is also shown that climatic conditions have different effects on rate at which CuxSny and AgxSny intermetallic compounds are formed.
ii
aged modules also show that humidity accelerates the formation of IMC as they showed thicker AgxSny layer and weak interconnect-contact interfaces as compared to Arizona modules. It is also shown that climatic conditions have different effects on rate at which CuxSny and AgxSny intermetallic compounds are formed.
ContributorsBuddha, Viswa Sai Pavan (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Alford, Terry (Thesis advisor) / Srinivasan, Devarajan (Committee member) / Arizona State University (Publisher)
Created2018
Description
This is a two-part thesis.
Part 1 of this thesis investigates the influence of spatial temperature distribution on the accuracy of performance data of photovoltaic (PV) modules in outdoor conditions and provides physical approaches to improve the spatial temperature distribution of the test modules so an accurate performance data can be obtained in the field. Conventionally, during outdoor performance testing, a single thermocouple location is used on the backsheet or back glass of a test module. This study clearly indicates that there is a large spatial temperature difference between various thermocouple locations within a module. Two physical approaches or configurations were experimented to improve the spatial temperature uniformity: thermally insulating the inner and outer surface of the frame; backsheet and inner surface of the frame. All the data were compared with un-insulated conventional configuration. This study was performed in an array setup of six modules under two different preconditioning electrical configurations, Voc and MPPT over several clear sunny days. This investigation concludes that the best temperature uniformity and the most accurate I-V data can be obtained only by thermally insulating the inner and outer frame surfaces or by using the average of four thermocouple temperatures, as specified in IEC 61853-2, without any thermal insulation.
Part 2 of this thesis analyzes the field data obtained from old PV power plants using various statistical techniques to identify the most influential degradation modes on fielded PV modules in two different climates: hot-dry (Arizona); cold-dry (New York). Performance data and visual inspection data of 647 modules fielded in five different power plants were analyzed. Statistical tests including hypothesis testing were carried out to identify the I-V parameter(s) that are affected the most. The affected performance parameters (Isc, Voc, FF and Pmax) were then correlated with the defects to determine the most dominant defect affecting power degradation. Analysis indicates that the cell interconnect discoloration (or solder bond deterioration) is the dominant defect in hot-dry climate leading to series resistance increase and power loss, while encapsulant delamination is being the most dominant defect in cold-dry climate leading to cell mismatch and power loss.
Part 1 of this thesis investigates the influence of spatial temperature distribution on the accuracy of performance data of photovoltaic (PV) modules in outdoor conditions and provides physical approaches to improve the spatial temperature distribution of the test modules so an accurate performance data can be obtained in the field. Conventionally, during outdoor performance testing, a single thermocouple location is used on the backsheet or back glass of a test module. This study clearly indicates that there is a large spatial temperature difference between various thermocouple locations within a module. Two physical approaches or configurations were experimented to improve the spatial temperature uniformity: thermally insulating the inner and outer surface of the frame; backsheet and inner surface of the frame. All the data were compared with un-insulated conventional configuration. This study was performed in an array setup of six modules under two different preconditioning electrical configurations, Voc and MPPT over several clear sunny days. This investigation concludes that the best temperature uniformity and the most accurate I-V data can be obtained only by thermally insulating the inner and outer frame surfaces or by using the average of four thermocouple temperatures, as specified in IEC 61853-2, without any thermal insulation.
Part 2 of this thesis analyzes the field data obtained from old PV power plants using various statistical techniques to identify the most influential degradation modes on fielded PV modules in two different climates: hot-dry (Arizona); cold-dry (New York). Performance data and visual inspection data of 647 modules fielded in five different power plants were analyzed. Statistical tests including hypothesis testing were carried out to identify the I-V parameter(s) that are affected the most. The affected performance parameters (Isc, Voc, FF and Pmax) were then correlated with the defects to determine the most dominant defect affecting power degradation. Analysis indicates that the cell interconnect discoloration (or solder bond deterioration) is the dominant defect in hot-dry climate leading to series resistance increase and power loss, while encapsulant delamination is being the most dominant defect in cold-dry climate leading to cell mismatch and power loss.
ContributorsUmachandran, Neelesh (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Wang, Liping (Committee member) / Phelan, Patrick (Committee member) / Arizona State University (Publisher)
Created2015