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- All Subjects: thermochronology
- Creators: Till, Christy
- Member of: ASU Electronic Theses and Dissertations
Description
A mineral’s helium content reflects a balance between two competing processes: accumulation by radioactive decay and temperature-dependent diffusive loss. (U-Th)/He dating of zircon and other uranium and thorium-bearing minerals provides insight into the temperature histories of rocks at or near Earth’s surface that informs geoscientists’ understanding of tectonic and climate-driven exhumation, magmatic activity, and other thermal events. The crystal structure and chemistry of minerals affect helium diffusion kinetics, recorded closure temperatures, and interpretations of (U-Th)/He datasets. I used empirical and experimental methods to investigate helium systematics in two minerals chronometers: zircon and xenotime.
The same radioactivity that makes zircon a valuable chronometer damages its crystal structure over time and changes zircon helium kinetics. I used a zircon, titanite, and apatite (U-Th)/He dataset combined with previously published data and a new thermal model to place empirical constraints on the closure temperature for helium in a suite of variably damaged zircon crystals from the McClure Mountain syenite of Colorado. Results of this study suggest that the widely-used zircon damage accumulation and annealing model (ZRDAAM) does not accurately predict helium closure temperatures for a majority of the dated zircons. Detailed Raman maps of Proterozoic zircon crystals from the Lyon Mountain Granite of New York document complex radiation damage zoning. Models based on these results suggest that most ancient zircons are likely to exhibit intracrystalline variations in helium diffusivity due to radiation damage zoning, which may, in part, explain discrepancies between my empirical findings and ZRDAAM.
Zircon crystallography suggests that helium diffusion should be fastest along the crystallographic c-axis. I used laser depth profiling to show that diffusion is more strongly anisotropic than previously recognized. These findings imply that crystal morphology affects the closure temperature for helium in crystalline zircon. Diffusivity and the magnitude of diffusive anisotropy decrease with low doses of radiation damage.
Xenotime would make a promising (U-Th)/He thermochronometer if its helium kinetics were better known. I performed classic step-wise degassing experiments to characterize helium diffusion in xenotime FPX-1. Results suggest that this xenotime sample is sensitive to exceptionally low temperatures (∼50 °C) and produces consistent (U-Th)/He dates.
The same radioactivity that makes zircon a valuable chronometer damages its crystal structure over time and changes zircon helium kinetics. I used a zircon, titanite, and apatite (U-Th)/He dataset combined with previously published data and a new thermal model to place empirical constraints on the closure temperature for helium in a suite of variably damaged zircon crystals from the McClure Mountain syenite of Colorado. Results of this study suggest that the widely-used zircon damage accumulation and annealing model (ZRDAAM) does not accurately predict helium closure temperatures for a majority of the dated zircons. Detailed Raman maps of Proterozoic zircon crystals from the Lyon Mountain Granite of New York document complex radiation damage zoning. Models based on these results suggest that most ancient zircons are likely to exhibit intracrystalline variations in helium diffusivity due to radiation damage zoning, which may, in part, explain discrepancies between my empirical findings and ZRDAAM.
Zircon crystallography suggests that helium diffusion should be fastest along the crystallographic c-axis. I used laser depth profiling to show that diffusion is more strongly anisotropic than previously recognized. These findings imply that crystal morphology affects the closure temperature for helium in crystalline zircon. Diffusivity and the magnitude of diffusive anisotropy decrease with low doses of radiation damage.
Xenotime would make a promising (U-Th)/He thermochronometer if its helium kinetics were better known. I performed classic step-wise degassing experiments to characterize helium diffusion in xenotime FPX-1. Results suggest that this xenotime sample is sensitive to exceptionally low temperatures (∼50 °C) and produces consistent (U-Th)/He dates.
ContributorsAnderson, Alyssa Jordan (Author) / Hodges, Kip (Thesis advisor) / van Soest, Matthijs (Committee member) / Till, Christy (Committee member) / Shim, Sang-Heon (Committee member) / Sharp, Tom (Committee member) / Arizona State University (Publisher)
Created2019
Description
The collision of India and Eurasia constructed the Himalayan Mountains. Questions remain regarding how subsequent exhumation by climatic and tectonic processes shaped the landscape throughout the Late Cenozoic to create the complex architecture observed today. The Mount Everest region underwent tectonic denudation by extension and bestrides one of the world’s most significant rain shadows. Also, glacial and fluvial processes eroded the Everest massif over shorter timescales. In this work, I review new bedrock and detrital thermochronological and geochronological data and both one- and two-dimensional thermal-mechanical modeling that provides insights on the age range and rates of tectonic and erosional processes in this region.
A strand of the South Tibetan detachment system (STDS), a series of prominent normal-sense structures that dip to the north and strike along the Himalayan spine, is exposed in the Rongbuk valley near Everest. Using thermochronometric techniques, thermal-kinematic modeling, and published (U-Th)/Pb geochronology, I show exhumation rates were high (~3-4 mm/a) from at least 20 to 13 Ma because of slip on the STDS. Subsequently, exhumation rates dropped drastically to ≤ 0.5 mm/a and remain low today. However, thermochronometric datasets and thermal-kinematic modeling results from Nepal south of Everest reveal a sharp transition in cooling ages and exhumation rates across a major knickpoint in the river profile, corresponding to the modern-day Himalayan rainfall transition. To the north of this transition, exhumation histories are similar to those in Tibet. Conversely, < 3 km south of the transition, exhumation rates were relatively low until the Pliocene, when they increased to ~4 mm/a before slowing at ~3 Ma. Such contrasting exhumation histories over a short distance suggest that bedrock exhumation rates correlate with modern precipitation patterns in deep time, however, there are competing interpretations regarding this correlation.
My work also provides insights regarding how processes of glacial erosion act in a glacio-fluvial valley north of Everest. Integrated laser ablation U/Pb and (U-Th)/He dating of detrital zircon from fluvial and moraine sediments reveal sourcing from distinctive areas of the catchment. In general, the glacial advances eroded material from lower elevations, while the glacial outwash system carries material from higher elevations.
A strand of the South Tibetan detachment system (STDS), a series of prominent normal-sense structures that dip to the north and strike along the Himalayan spine, is exposed in the Rongbuk valley near Everest. Using thermochronometric techniques, thermal-kinematic modeling, and published (U-Th)/Pb geochronology, I show exhumation rates were high (~3-4 mm/a) from at least 20 to 13 Ma because of slip on the STDS. Subsequently, exhumation rates dropped drastically to ≤ 0.5 mm/a and remain low today. However, thermochronometric datasets and thermal-kinematic modeling results from Nepal south of Everest reveal a sharp transition in cooling ages and exhumation rates across a major knickpoint in the river profile, corresponding to the modern-day Himalayan rainfall transition. To the north of this transition, exhumation histories are similar to those in Tibet. Conversely, < 3 km south of the transition, exhumation rates were relatively low until the Pliocene, when they increased to ~4 mm/a before slowing at ~3 Ma. Such contrasting exhumation histories over a short distance suggest that bedrock exhumation rates correlate with modern precipitation patterns in deep time, however, there are competing interpretations regarding this correlation.
My work also provides insights regarding how processes of glacial erosion act in a glacio-fluvial valley north of Everest. Integrated laser ablation U/Pb and (U-Th)/He dating of detrital zircon from fluvial and moraine sediments reveal sourcing from distinctive areas of the catchment. In general, the glacial advances eroded material from lower elevations, while the glacial outwash system carries material from higher elevations.
ContributorsSchultz, Mary Hannah (Author) / Hodges, Kip V (Thesis advisor) / Whipple, Kelin X (Committee member) / Semken, Steven (Committee member) / Heimsath, Arjun M (Committee member) / Till, Christy (Committee member) / Arizona State University (Publisher)
Created2017