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- All Subjects: Planetology
- All Subjects: Molybdenum
- Creators: Sharp, Thomas G
Description
The occurrence of exogenic, meteoritic materials on the surface of any world presents opportunities to explore a variety of significant problems in the planetary sciences. In the case of Mars, meteorites found on its surface may help to 1) constrain atmospheric conditions during their time of arrival; 2) provide insights into possible variabilities in meteoroid type sampling between Mars and Earth space environments; 3) aid in our understanding of soil, dust, and sedimentary rock chemistry; 4) assist with the calibration of crater-age dating techniques; and 5) provide witness samples for chemical and mechanical weathering processes. The presence of reduced metallic iron in approximately 88 percent of meteorite falls renders the majority of meteorites particularly sensitive to oxidation by H2O interaction. This makes them excellent markers for H2O occurrence. Several large meteorites have been discovered at Gusev Crater and Meridiani Planum by the Mars Exploration Rovers (MERs). Significant morphologic characteristics interpretable as weathering features in the Meridiani suite of iron meteorites include a 1) large pit lined with delicate iron protrusions suggestive of inclusion removal by corrosive interaction; 2) differentially eroded kamacite and taenite lamellae on three of the meteorites, providing relative timing through cross-cutting relationships with deposition of 3) an iron oxide-rich dark coating; and 4) regmaglypted surfaces testifying to regions of minimal surface modification; with other regions in the same meteorites exhibiting 5) large-scale, cavernous weathering. Iron meteorites found by Mini-TES at both Meridiani Planum and Gusev Crater have prompted laboratory experiments designed to explore elements of reflectivity, dust cover, and potential oxide coatings on their surfaces in the thermal infrared using analog samples. Results show that dust thickness on an iron substrate need be only one tenth as great as that on a silicate rock to obscure its infrared signal. In addition, a database of thermal emission spectra for 46 meteorites was prepared to aid in the on-going detection and interpretation of these valuable rocks on Mars using Mini-TES instruments on both MER spacecraft. Applications to the asteroidal sciences are also relevant and intended for this database.
ContributorsAshley, James Warren (Author) / Christensen, Philip R. (Thesis advisor) / Sharp, Thomas G (Committee member) / Shock, Everett L (Committee member) / Hervig, Richard L (Committee member) / Zolotov, Mikhail Y (Committee member) / Arizona State University (Publisher)
Created2011
Description
Molybdenum and uranium isotope variations are potentially powerful tools for reconstructing the paleoredox history of seawater. Reliable application and interpretation of these proxies requires not only detailed knowledge about the fractionation factors that control the distribution of molybdenum and uranium isotopes in the marine system, but also a thorough understanding of the diagenetic processes that may affect molybdenum and uranium isotopes entering the rock record. Using samples from the Black Sea water column, the first water column profile of 238U/235U variations from a modern euxinic basin has been measured. This profile allows the direct determination of the 238U/235U fractionation factor in a euxinic marine setting. More importantly however, these data demonstrate the extent of Rayleigh fractionation of U isotopes that can occur in euxinic restricted basins. Because of this effect, the offset of 238U/235U between global average seawater and coeval black shales deposited in restricted basins is expected to depend on the degree of local uranium drawdown from the water column, potentially complicating the interpretation 238U/235U paleorecords. As an alternative to the black shales typically used for paleoredox reconstructions, molybdenum and uranium isotope variations in bulk carbonate sediments from the Bahamas are examined. The focus of this work was to determine what processes, if any, fractionate molybdenum and uranium isotopes during incorporation into bulk carbonate sediments and their subsequent diagenesis. The results demonstrate that authigenic accumulation of molybdenum and uranium from anoxic and sulfidic pore waters is a dominant process controlling the concentration and isotopic composition of these sediments during early diagenesis. Examination of ODP drill core samples from the Bahamas reveals similar behavior for sediments during the first ~780ka of burial, but provides important examples where isolated cores and samples occasionally demonstrate additional fractionation, the cause of which remains poorly understood.
ContributorsRomaniello, Stephen J. (Author) / Anbar, Ariel (Thesis advisor) / Hartnett, Hilairy (Committee member) / Herrmann, Achim (Committee member) / Shock, Everett (Committee member) / Wadhwa, Meenakshi (Committee member) / Arizona State University (Publisher)
Created2012
Description
Remote sensing in visible to near-infrared wavelengths is an important tool for identifying and understanding compositional differences on planetary surfaces. Electronic transitions produce broad absorption bands that are often due to the presence of iron cations in crystalline mineral structures or amorphous phases. Mars’ iron-rich and variably oxidized surface provides an ideal environment for detecting spectral variations that can be related to differences in surface dust cover or the composition of the underlying bedrock. Several imaging cameras sent to Mars include the capability to selectively filter incoming light to discriminate between surface materials.
At the coarse spatial resolution provided by the wide-angle Mars Color Imager (MARCI) camera aboard the Mars Reconnaissance Orbiter (MRO), regional scale differences in reflectance at all wavelengths are dominated by the presence or absence of Fe3+-rich dust. The dust cover in many regions is highly variable, often with strong seasonal dependence although major storm events can redistribute dust in ways that significantly alter the albedo of large-scale regions outside of the normal annual cycle. Surface dust reservoirs represent an important part of the martian climate system and may play a critical role in the growth of regional dust storms to planet-wide scales. Detailed investigation of seasonal and secular changes permitted by repeated MARCI imaging coverage have allowed the surface dust coverage of the planet at large to be described and have revealed multiannual replenishing of regions historically associated with the growth of storms.
From the ground, rover-based multispectral imaging acquired by the Mastcam cameras allows compositional discrimination between bedrock units and float material encountered along the Curiosity rover’s traverse across crater floor and lower Mt. Sharp units. Mastcam spectra indicate differences in primary mineralogy, the presence of iron-bearing alteration phases, and variations in iron oxidation state, which occur at specific locations along the rover’s traverse. These changes represent differences in the primary depositional environment and the action of later alteration by fluids circulating through fractures in the bedrock. Loose float rocks sample materials brought into the crater by fluvial or other processes. Mastcam observations provide important constraints on the geologic history of the Gale Crater site.
At the coarse spatial resolution provided by the wide-angle Mars Color Imager (MARCI) camera aboard the Mars Reconnaissance Orbiter (MRO), regional scale differences in reflectance at all wavelengths are dominated by the presence or absence of Fe3+-rich dust. The dust cover in many regions is highly variable, often with strong seasonal dependence although major storm events can redistribute dust in ways that significantly alter the albedo of large-scale regions outside of the normal annual cycle. Surface dust reservoirs represent an important part of the martian climate system and may play a critical role in the growth of regional dust storms to planet-wide scales. Detailed investigation of seasonal and secular changes permitted by repeated MARCI imaging coverage have allowed the surface dust coverage of the planet at large to be described and have revealed multiannual replenishing of regions historically associated with the growth of storms.
From the ground, rover-based multispectral imaging acquired by the Mastcam cameras allows compositional discrimination between bedrock units and float material encountered along the Curiosity rover’s traverse across crater floor and lower Mt. Sharp units. Mastcam spectra indicate differences in primary mineralogy, the presence of iron-bearing alteration phases, and variations in iron oxidation state, which occur at specific locations along the rover’s traverse. These changes represent differences in the primary depositional environment and the action of later alteration by fluids circulating through fractures in the bedrock. Loose float rocks sample materials brought into the crater by fluvial or other processes. Mastcam observations provide important constraints on the geologic history of the Gale Crater site.
ContributorsWellington, Danika (Author) / Bell Iii, James F (Thesis advisor) / Christensen, Philip R. (Committee member) / Robinson, Mark S (Committee member) / Sharp, Thomas G (Committee member) / Till, Christy B. (Committee member) / Arizona State University (Publisher)
Created2018
Description
Biochemical reactions underlie all living processes. Their complex web of interactions is difficult to fully capture and quantify with simple mathematical objects. Applying network science to biology has advanced our understanding of the metabolisms of individual organisms and the organization of ecosystems, but has scarcely been applied to life at a planetary scale. To characterize planetary-scale biochemistry, I constructed biochemical networks using global databases of annotated genomes and metagenomes, and biochemical reactions. I uncover scaling laws governing biochemical diversity and network structure shared across levels of organization from individuals to ecosystems, to the biosphere as a whole. Comparing real biochemical reaction networks to random reaction networks reveals the observed biological scaling is not a product of chemistry alone, but instead emerges due to the particular structure of selected reactions commonly participating in living processes. I perform distinguishability tests across properties of individual and ecosystem-level biochemical networks to determine whether or not they share common structure, indicative of common generative mechanisms across levels. My results indicate there is no sharp transition in the organization of biochemistry across distinct levels of the biological hierarchy—a result that holds across different network projections.
Finally, I leverage these large biochemical datasets, in conjunction with planetary observations and computational tools, to provide a methodological foundation for the quantitative assessment of biology’s viability amongst other geospheres. Investigating a case study of alkaliphilic prokaryotes in the context of Enceladus, I find that the chemical compounds observed on Enceladus thus far would be insufficient to allow even these extremophiles to produce the compounds necessary to sustain a viable metabolism. The environmental precursors required by these organisms provides a reference for the compounds which should be prioritized for detection in future planetary exploration missions. The results of this framework have further consequences in the context of planetary protection, and hint that forward contamination may prove infeasible without meticulous intent. Taken together these results point to a deeper level of organization in biochemical networks than what has been understood so far, and suggests the existence of common organizing principles operating across different levels of biology and planetary chemistry.
Finally, I leverage these large biochemical datasets, in conjunction with planetary observations and computational tools, to provide a methodological foundation for the quantitative assessment of biology’s viability amongst other geospheres. Investigating a case study of alkaliphilic prokaryotes in the context of Enceladus, I find that the chemical compounds observed on Enceladus thus far would be insufficient to allow even these extremophiles to produce the compounds necessary to sustain a viable metabolism. The environmental precursors required by these organisms provides a reference for the compounds which should be prioritized for detection in future planetary exploration missions. The results of this framework have further consequences in the context of planetary protection, and hint that forward contamination may prove infeasible without meticulous intent. Taken together these results point to a deeper level of organization in biochemical networks than what has been understood so far, and suggests the existence of common organizing principles operating across different levels of biology and planetary chemistry.
ContributorsSmith, Harrison Brodsky (Author) / Walker, Sara I (Thesis advisor) / Anbar, Ariel D (Committee member) / Line, Michael R (Committee member) / Okie, Jordan G. (Committee member) / Romaniello, Stephen J. (Committee member) / Arizona State University (Publisher)
Created2018
Description
Space weathering of planetary surfaces is a complex process involving many mechanisms that work independently over different timescales. This research aims to address outstanding questions related to solar wind rim formation on space weathered regolith and tests a new hypothesis that dielectric breakdown plays an important role in the optical maturation of lunar regolith. The purpose of this work is to highlight the limitations imposed by laboratory equipment to accurately simulate the solar wind’s effects on regolith and to provide physical context for the possible contributions of dielectric breakdown to space weathering. Terrestrial and lunar samples were experimentally irradiated and damage was characterized using electron microscopy techniques. Low-fluence proton irradiation produced differential weathering in a lunar mare basalt, with radiation damage on some phases being inconsistent with that found in the natural lunar environment. Dielectric breakdown of silicates revealed two electrical processes that produce characteristic surface and subsurface damage, in addition to amorphous rims. The results of this research highlight experimental parameters that if ignored, can significantly affect the results and interpretations of simulated solar wind weathering, and provides a framework for advancing space weathering research through experimental studies.
ContributorsShusterman, Morgan (Author) / Robinson, Mark S (Thesis advisor) / Sharp, Thomas G (Thesis advisor) / Hibbits, Charles (Committee member) / Bose, Maitrayee (Committee member) / Semken, Steven (Committee member) / Arizona State University (Publisher)
Created2023
Description
Understanding the history of water on Mars is one of the highest priority goals of the international Mars exploration community. Water would have played a key role in any potential abiogenesis in the past and will play a key role in the future human exploration of the planet. Chloride salts are an indicator of past hydrologic activity in the Martian geologic record and have the potential to preserve fluid inclusions and organic material within their crystal structure over geologic timescales. This dissertation will describe an innovative method for identifying chloride salts on the Martian surface, explore the implication of their distribution within Early Noachian terrains, and document important opportunistic discoveries made in the process. Decorrelation stretched Thermal Emission Imaging System (THEMIS) infrared images have long been used to identify chloride salts on Mars, but the process has been time-consuming, subjective, and qualitative. By analyzing the entire THEMIS dataset, acquired over more than twenty years at Mars, a globally-applicable covariance matrix was calculated that describes the geologic diversity of the Martian surface. This covariance matrix allows all THEMIS daytime infrared images to be translated into globally-consistent decorrelation stretch and principal component images, enabling an automatic, objective, and quantitative method for identifying chloride salts. A new global survey located 1,605 chloride salt deposits across the Martian surface, a significant increase over previous surveys. In particular, the 257 deposits in Early Noachian terrains have characteristics that indicate they formed contemporaneously with the surrounding terrain. In addition, a chloride salt formation was identified on the floor of Ares Vallis with a unique three-dimensional structure that has been interpreted as an exposed chloride salt diapir, which would indicate the presence of a significant subsurface chloride salt layer. By improving our understanding of the distribution and diversity of chloride salts on the Martian surface, this work has provided future investigators with new tools and avenues of research to explore the history of water on Mars.
ContributorsHill, Jonathon Ryan (Author) / Christensen, Philip R. (Thesis advisor) / Sharp, Thomas G (Committee member) / Ruff, Steven W (Committee member) / Simon, Molly N (Committee member) / O'Rourke, Joseph G (Committee member) / Arizona State University (Publisher)
Created2022
Description
Establishing the timing of impact crater formation is essential to exploring the relationship between bolide impact and biological evolution, and constraining the tempo of planetary surface evolution. Unfortunately, precise and accurate impact geochronology can be challenging. Many of the rock products of impact (impactites) contain relict, pre-impact phases that may have had their isotopic systematics completely reset during the impact event, only partially reset, or not reset at all. Of the many isotopic chronometers that have been used to date impactites, the U/Pb zircon chronometer (ZrnPb) seems least susceptible to post-impact disturbances, and ZrnPb dates are typically much more precise than those obtained using other chronometers. However, the ZrnPb system is so resistant to resetting that relict zircons in impactites often yield dates that reflect the igneous or metamorphic ages of the target rocks rather than the age of the impact itself. The present study was designed to answer a simple question: is there a straightforward sample collection and analysis strategy for high-accuracy ZrnPb dating of an impact structure if the impactites collected from it may contain inherited zircons? To study this, ZrnPb dates were determined for impactites from a single crater with a well-constrained impact age: the West Clearwater Lake impact structure, located at Lake Wiyâshâkimî, Québec, Canada.
The amount of ZrnPb resetting and the mechanisms responsible for resetting varied amongst the samples. Each sample characteristically contained either: newly crystallized zircons from the impact melt ("neocrystalline"), relict zircons ~50-100% reset, or, relict zircons ~0-50% reset. The variably reset relict zircons define a discordia line from ~2700 Ma to ~286 Ma – consistent with the ages of the target rock and the impact, respectively (Schmieder et al., 2015a; Simard, 2004). ZrnPb measurements from the neocrystalline zircons provided a new preferred impact age of 286.64 ± 0.35 Ma (2σ), a ~10x improvement in precision. The characteristics of the West Clearwater ZrnPb data vary between samples yet become easily interpretable as a whole, showing that efforts to measure robust, precise impact ages benefit from strategies that prioritize applying multiple analytical techniques to multiple types of impactite from the same crater.
The amount of ZrnPb resetting and the mechanisms responsible for resetting varied amongst the samples. Each sample characteristically contained either: newly crystallized zircons from the impact melt ("neocrystalline"), relict zircons ~50-100% reset, or, relict zircons ~0-50% reset. The variably reset relict zircons define a discordia line from ~2700 Ma to ~286 Ma – consistent with the ages of the target rock and the impact, respectively (Schmieder et al., 2015a; Simard, 2004). ZrnPb measurements from the neocrystalline zircons provided a new preferred impact age of 286.64 ± 0.35 Ma (2σ), a ~10x improvement in precision. The characteristics of the West Clearwater ZrnPb data vary between samples yet become easily interpretable as a whole, showing that efforts to measure robust, precise impact ages benefit from strategies that prioritize applying multiple analytical techniques to multiple types of impactite from the same crater.
ContributorsBrunner, Anna Elizabeth (Author) / Hodges, Kip V (Thesis advisor) / Barboni, Melanie (Committee member) / Van Soest, Matthijs C (Committee member) / Sharp, Thomas G (Committee member) / Arizona State University (Publisher)
Created2019
Description
Archean oxidative weathering reactions were likely important O2 sinks that delayed the oxygenation of Earth’s atmosphere, as well as sources of bio-essential trace metals such as Mo to the biosphere. However, the rates of these reactions are difficult to quantify experimentally at relevantly low concentrations of O2. With newly developed O2 sensors, weathering experiments were conducted to measure the rate of sulfide oxidation at Archean levels of O2, a level three orders of magnitude lower than previous experiments. The rate laws produced, combined with weathering models, indicate that crustal sulfide oxidation by O2 was possible even in a low O2 Archean atmosphere.
Given the experimental results, it is expected that crustal delivery of bio-essential trace metals (such as Mo) from sulfide weathering was active even prior to the oxygenation of Earth’s atmosphere. Mo is a key metal for biological N2 fixation and its ancient use is evidenced by N isotopes in ancient sedimentary rocks. However, it is typically thought that Mo was too low to be effectively bioavailable early in Earth’s history, given the low abundances of Mo found in ancient sediments. To reconcile these observations, a computational model was built that leverages isotopic constraints to calculate the range of seawater concentrations possible in ancient oceans. Under several scenarios, bioavailable concentrations of seawater Mo were attainable and compatible with the geologic record. These results imply that Mo may not have been limiting for early metabolisms.
Titanium (Ti) isotopes were recently proposed to trace the evolution of the ancient continental crust, and have the potential to trace the distribution of other trace metals during magmatic differentiation. However, significant work remains to understand fully Ti isotope fractionation during crust formation. To calibrate this proxy, I carried out the first direct measurement of mineral-melt fractionation factors for Ti isotopes in Kilauea Iki lava lake and built a multi-variate fractionation law for Ti isotopes during magmatic differentiation. This study allows more accurate forward-modeling of isotope fractionation during crust differentiation, which can now be paired with weathering models and ocean mass balance to further reconstruct the composition of Earth’s early continental crust, atmosphere, and oceans.
Given the experimental results, it is expected that crustal delivery of bio-essential trace metals (such as Mo) from sulfide weathering was active even prior to the oxygenation of Earth’s atmosphere. Mo is a key metal for biological N2 fixation and its ancient use is evidenced by N isotopes in ancient sedimentary rocks. However, it is typically thought that Mo was too low to be effectively bioavailable early in Earth’s history, given the low abundances of Mo found in ancient sediments. To reconcile these observations, a computational model was built that leverages isotopic constraints to calculate the range of seawater concentrations possible in ancient oceans. Under several scenarios, bioavailable concentrations of seawater Mo were attainable and compatible with the geologic record. These results imply that Mo may not have been limiting for early metabolisms.
Titanium (Ti) isotopes were recently proposed to trace the evolution of the ancient continental crust, and have the potential to trace the distribution of other trace metals during magmatic differentiation. However, significant work remains to understand fully Ti isotope fractionation during crust formation. To calibrate this proxy, I carried out the first direct measurement of mineral-melt fractionation factors for Ti isotopes in Kilauea Iki lava lake and built a multi-variate fractionation law for Ti isotopes during magmatic differentiation. This study allows more accurate forward-modeling of isotope fractionation during crust differentiation, which can now be paired with weathering models and ocean mass balance to further reconstruct the composition of Earth’s early continental crust, atmosphere, and oceans.
ContributorsJohnson, Aleisha (Author) / Anbar, Ariel D. (Thesis advisor) / Till, Christy (Committee member) / Hartnett, Hilairy (Committee member) / Romaniello, Stephen J. (Committee member) / Sharp, Thomas (Committee member) / Arizona State University (Publisher)
Created2020