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Description
Natural resource depletion and environmental degradation are the stark realities of the times we live in. As awareness about these issues increases globally, industries and businesses are becoming interested in understanding and minimizing the ecological footprints of their activities. Evaluating the environmental impacts of products and processes has become a

Natural resource depletion and environmental degradation are the stark realities of the times we live in. As awareness about these issues increases globally, industries and businesses are becoming interested in understanding and minimizing the ecological footprints of their activities. Evaluating the environmental impacts of products and processes has become a key issue, and the first step towards addressing and eventually curbing climate change. Additionally, companies are finding it beneficial and are interested in going beyond compliance using pollution prevention strategies and environmental management systems to improve their environmental performance. Life-cycle Assessment (LCA) is an evaluative method to assess the environmental impacts associated with a products' life-cycle from cradle-to-grave (i.e. from raw material extraction through to material processing, manufacturing, distribution, use, repair and maintenance, and finally, disposal or recycling). This study focuses on evaluating building envelopes on the basis of their life-cycle analysis. In order to facilitate this analysis, a small-scale office building, the University Services Building (USB), with a built-up area of 148,101 ft2 situated on ASU campus in Tempe, Arizona was studied. The building's exterior envelope is the highlight of this study. The current exterior envelope is made of tilt-up concrete construction, a type of construction in which the concrete elements are constructed horizontally and tilted up, after they are cured, using cranes and are braced until other structural elements are secured. This building envelope is compared to five other building envelope systems (i.e. concrete block, insulated concrete form, cast-in-place concrete, steel studs and curtain wall constructions) evaluating them on the basis of least environmental impact. The research methodology involved developing energy models, simulating them and generating changes in energy consumption due to the above mentioned envelope types. Energy consumption data, along with various other details, such as building floor area, areas of walls, columns, beams etc. and their material types were imported into Life-Cycle Assessment software called ATHENA impact estimator for buildings. Using this four-stepped LCA methodology, the results showed that the Steel Stud envelope performed the best and less environmental impact compared to other envelope types. This research methodology can be applied to other building typologies.
ContributorsRamachandran, Sriranjani (Author) / Bryan, Harvey (Thesis advisor) / Reddy T, Agami (Committee member) / White, Philip (Committee member) / Arizona State University (Publisher)
Created2013
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Description
Life cycle assessment (LCA) is a powerful framework for environmental decision making because the broad boundaries called for prevent shifting of burden from one life-cycle phase to another. Numerous experts and policy setting organizations call for the application of LCA to developing nanotechnologies. Early application of LCA to nanotechnology may

Life cycle assessment (LCA) is a powerful framework for environmental decision making because the broad boundaries called for prevent shifting of burden from one life-cycle phase to another. Numerous experts and policy setting organizations call for the application of LCA to developing nanotechnologies. Early application of LCA to nanotechnology may identify environmentally problematic processes and supply chain components before large investments contribute to technology lock in, and thereby promote integration of environmental concerns into technology development and scale-up (enviro-technical integration). However, application of LCA to nanotechnology is problematic due to limitations in LCA methods (e.g., reliance on data from existing industries at scale, ambiguity regarding proper boundary selection), and because social drivers of technology development and environmental preservation are not identified in LCA. This thesis proposes two methodological advances that augment current capabilities of LCA by incorporating knowledge from technical and social domains. Specifically, this thesis advances the capacity for LCA to yield enviro-technical integration through inclusion of scenario development, thermodynamic modeling, and use-phase performance bounding to overcome the paucity of data describing emerging nanotechnologies. With regard to socio-technical integration, this thesis demonstrates that social values are implicit in LCA, and explores the extent to which these values impact LCA practice and results. There are numerous paths of entry through which social values are contained in LCA, for example functional unit selection, impact category selection, and system boundary definition - decisions which embody particular values and determine LCA results. Explicit identification of how social values are embedded in LCA promotes integration of social and environmental concerns into technology development (socio-enviro-technical integration), and may contribute to the development of socially-responsive and environmentally preferable nanotechnologies. In this way, tailoring LCA to promote socio-enviro-technical integration is a tangible and meaningful step towards responsible innovation processes.
ContributorsWender, Ben A. (Author) / Seager, Thomas P (Thesis advisor) / Crozier, Peter (Committee member) / Fraser, Matthew (Committee member) / Guston, David (Committee member) / Arizona State University (Publisher)
Created2013
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Description
Life Cycle Assessment (LCA) quantifies environmental impacts of products in raw material extraction, processing, manufacturing, distribution, use and final disposal. The findings of an LCA can be used to improve industry practices, to aid in product development, and guide public policy. Unfortunately, existing approaches to LCA are unreliable in the

Life Cycle Assessment (LCA) quantifies environmental impacts of products in raw material extraction, processing, manufacturing, distribution, use and final disposal. The findings of an LCA can be used to improve industry practices, to aid in product development, and guide public policy. Unfortunately, existing approaches to LCA are unreliable in the cases of emerging technologies, where data is unavailable and rapid technological advances outstrip environmental knowledge. Previous studies have demonstrated several shortcomings to existing practices, including the masking of environmental impacts, the difficulty of selecting appropriate weight sets for multi-stakeholder problems, and difficulties in exploration of variability and uncertainty. In particular, there is an acute need for decision-driven interpretation methods that can guide decision makers towards making balanced, environmentally sound decisions in instances of high uncertainty. We propose the first major methodological innovation in LCA since early establishment of LCA as the analytical perspective of choice in problems of environmental management. We propose to couple stochastic multi-criteria decision analytic tools with existing approaches to inventory building and characterization to create a robust approach to comparative technology assessment in the context of high uncertainty, rapid technological change, and evolving stakeholder values. Namely, this study introduces a novel method known as Stochastic Multi-attribute Analysis for Life Cycle Impact Assessment (SMAA-LCIA) that uses internal normalization by means of outranking and exploration of feasible weight spaces.
ContributorsPrado, Valentina (Author) / Seager, Thomas P (Thesis advisor) / Landis, Amy E. (Committee member) / Chester, Mikhail (Committee member) / White, Philip (Committee member) / Arizona State University (Publisher)
Created2013
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Description
Natural rubber and rubber products can be produced from the guayule plant (Parthenium argentatum Gray), which is a low input perennial shrub native to Mexico and the American Southwest. Guayule rubber has the potential to replace Hevea (Hevea brasiliensis) rubber, the most common natural rubber, and synthetic rubber, which is

Natural rubber and rubber products can be produced from the guayule plant (Parthenium argentatum Gray), which is a low input perennial shrub native to Mexico and the American Southwest. Guayule rubber has the potential to replace Hevea (Hevea brasiliensis) rubber, the most common natural rubber, and synthetic rubber, which is derived from petroleum, in a wide variety of products, including automobile tires. Rubbers make up approximately 47% of the analyzed conventional passenger tire's weight, with 31% from synthetic rubber and 16% from natural Hevea rubber. Replacing the current rubber sources used for the tire industry with guayule rubber could help reduce dependency on imported rubber in addition to reducing greenhouse gas emissions. Moreover, residues from guayule rubber are being researched as a bioenergy feedstock to further improve the environmental footprint of guayule rubber products. This study used life cycle assessment (LCA), a useful tool to determine environmental impacts from a product or process, to quantify and compare environmental impacts of the raw material extraction, transportation and manufacturing of a conventional and a guayule rubber based passenger tire. The impact results of this comparative LCA identified the major environmental impacts and contributing process and informed how the impacts from the tire production can be reduced through utilization of natural rubber co-products as electricity off-sets and reducing guayule rubber's environmental impacts through agricultural and transportation modifications. Results showed that tire raw material extraction contributed the majority of impacts in all categories, where the production of guayule rubber for guayule tires, and the production of synthetic rubber for conventional tires, were the main contributors. Guayule rubber impacts occurred mainly from electricity consumption for agricultural irrigation, while synthetic rubber is a petroleum-based material resulting in high impacts. Transportation impacts had little significance compared to other stages in the life cycle, except for smog impacts, which occurred mainly from truck transport for guayule tires, and transoceanic transport for conventional tires. Tire manufacturing impacts occurred mainly from electricity use in the facilities and were reduced with the use of guayule rubber in guayule tires.
ContributorsRasutis, Daina (Author) / Landis, Amy E. (Thesis advisor) / Colvin, Howard (Committee member) / Seager, Thomas P. (Committee member) / Arizona State University (Publisher)
Created2014
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Description
In recent years, the length of time people use and keep belongings has decreased. With the acceptance of short-lived furniture and inexpensive replacements, the American mentality has shifted to thinking that discarding furniture is normal, often in the guise of recycling. Americans are addicted to landfills. The high cost of

In recent years, the length of time people use and keep belongings has decreased. With the acceptance of short-lived furniture and inexpensive replacements, the American mentality has shifted to thinking that discarding furniture is normal, often in the guise of recycling. Americans are addicted to landfills. The high cost of landfill real estate and other considerable ecological impacts created by the manufacturing of furniture should persuade people to give their belongings a longer life, but in reality, furniture is often prematurely discarded. This grounded theory study takes a multi-method approach to analyze why some types of furniture are kept longer and to theorize about new ways to design and sell furniture that lasts well past its warranty. Case studies bring new insight into designer intention, manufacturer intent, the world of auction-worthy collectables and heirlooms, why there is a booming second-hand furniture market and the growing importance of informed interior designers and architects who specify or help clients choose interior furnishings. An environmental life cycle assessment compares how the length of furniture life affects environmental impacts. A product's life could continue for generations if properly maintained. Designers and manufacturers hoping to promote longevity can apply the conclusions of this report in bringing new pieces to the market that have a much longer life span. This study finds areas of opportunity that promote user attachment, anticipate future repurposing, and provide services. This thinking envisions a paradigm for furniture that can re-invent itself over multiple generations of users, and ultimately lead to a new wave of desirable heirloom furniture.
ContributorsIngham, Sarah (Author) / White, Philip (Thesis advisor) / Wolf, Peter (Committee member) / Underhill, Michael (Committee member) / Arizona State University (Publisher)
Created2011
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Description
In recent years environmental life-cycle assessments (LCA) have been increasingly used to support planning and development of sustainable infrastructure. This study demonstrates the application of LCA to estimate embedded energy use and greenhouse gas (GHG) emissions related to materials manufacturing and construction processes for low and high density single-family neighborhoods

In recent years environmental life-cycle assessments (LCA) have been increasingly used to support planning and development of sustainable infrastructure. This study demonstrates the application of LCA to estimate embedded energy use and greenhouse gas (GHG) emissions related to materials manufacturing and construction processes for low and high density single-family neighborhoods typically found in the Southwest. The LCA analysis presented in this study includes the assessment of more than 8,500 single family detached units, and 130 miles of related roadway infrastructure. The study estimates embedded and GHG emissions as a function of building size (1,500 - 3000 square feet), number of stories (1 or 2), and exterior wall material composition (stucco, brick, block, wood), roof material composition (clay tile, cement tile, asphalt shingles, built up), and as a function of roadway typology per mile (asphalt local residential roads, collectors, arterials). While a hybrid economic input-out life-cycle assessment is applied to estimate the energy and GHG emissions impacts of the residential units, the PaLATE tool is applied to determine the environmental effects of pavements and roads. The results indicate that low density single family neighborhoods are 2 - 2.5 X more energy and GHG intensive, per residential dwelling (unit) built, than high density residential neighborhoods. This relationship holds regardless of whether the functional unit is per acre or per capita. The results also indicate that a typical low density neighborhood (less than 2 dwellings per acre) requires 78 percent more energy and resource in roadway infrastructure per residential unit than a traditional small lot high density (more than 6 dwelling per acre). Also, this study shows that new master planned communities tend to be more energy intensive than traditional non master planned residential developments.
ContributorsFrijia, Stephane (Author) / Guhathakurta, Subhrajit (Committee member) / Williams, Eric D. (Committee member) / Pijawka, David K (Committee member) / Arizona State University (Publisher)
Created2011
Description
Carbon capture and sequestration (CCS) is one of the important mitigation options for climate change. Numerous technologies to capture carbon dioxide (CO2) are in development but currently, capture using amines is the predominant technology. When the flue gas reacts with amines (Monoethanaloamine) the CO2 is absorbed into the solution and

Carbon capture and sequestration (CCS) is one of the important mitigation options for climate change. Numerous technologies to capture carbon dioxide (CO2) are in development but currently, capture using amines is the predominant technology. When the flue gas reacts with amines (Monoethanaloamine) the CO2 is absorbed into the solution and forms an intermediate product which then releases CO2 at higher temperature. The high temperature necessary to strip CO2 is provided by steam extracted from the powerplant thus reducing the net output of the powerplant by 25% to 35%. The reduction in electricity output for the same input of coal increases the emissions factor of Nitrogen Oxides, Mercury, Particulate matter, Ammonia, Volatile organic compounds for the same unit of electricity produced. The thesis questions if this tradeoff between CO2 and other emissions is beneficial or not. Three different methodologies, Life Cycle Assessment, Valuation models and cost benefit analysis are used to identify if there is a net benefit to the society on implementation of CCS to a Pulverized coal powerplant. These methodologies include the benefits due to reduction of CO2 and the disbenefits due to the increase of other emissions. The life cycle assessment using ecoindicator'99 methodology shows the CCS is not beneficial under Hierarchical and Egalitarian perspective. The valuation model shows that the inclusion of the other emissions reduces the benefit associated with CCS. For a lower CO2 price the valuation model shows that CCS is detrimental to the environment. The cost benefit analysis shows that a CO2 price of at least $80/tCO2 is required for the cost benefit ratio to be 1. The methodology integrates Montecarlo simulation to characterize the uncertainties associated with the valuation models.
ContributorsSekar, Ashok (Author) / Williams, Eric (Thesis advisor) / Chester, Mikhail (Thesis advisor) / Allenby, Braden (Committee member) / Arizona State University (Publisher)
Created2012
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Description
Ecolabels are the main driving force of consumer knowledge in the realm of sustainable product purchasing. While ecolabels strive to improve consumer's purchasing decisions, they have overwhelmed the market, leaving consumers confused and distrustful of what each label means. This study attempts to validate and understand environmental concerns commonly found

Ecolabels are the main driving force of consumer knowledge in the realm of sustainable product purchasing. While ecolabels strive to improve consumer's purchasing decisions, they have overwhelmed the market, leaving consumers confused and distrustful of what each label means. This study attempts to validate and understand environmental concerns commonly found in ecolabel criteria and the implications they have within the life cycle of a product. A life cycle assessment (LCA) case study of cosmetic products is used in comparison with current ecolabel program criteria to assess whether or not ecolabels are effectively driving environmental improvements in high impact areas throughout the life cycle of a product. Focus is placed on determining the general issues addressed by ecolabelling criteria and how these issues relate to hotspots derived through a practiced scientific methodology. Through this analysis, it was determined that a majority the top performing supply chain environmental impacts are covered, in some fashion, within ecolabelling criteria, but some, such as agricultural land occupation, are covered to a lesser extent or not at all. Additional criteria are suggested to fill the gaps found in ecolabelling programs and better address the environmental impacts most pertinent to the supply chain. Ecolabels have also been found to have a broader coverage then what can currently be addressed using LCA. The results of this analysis have led to a set of recommendations for furthering the integration between ecolabels and life cycle tools.
ContributorsBernardo, Melissa (Author) / Dooley, Kevin (Thesis advisor) / Chester, Mikhail (Thesis advisor) / Fox, Peter (Committee member) / Arizona State University (Publisher)
Created2012
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Description
With high potential for automobiles to cause air pollution and greenhouse gas emissions, there is concern that automobiles accessing or egressing public transportation may cause emissions similar to regular automobile use. Due to limited literature and research that evaluates and discusses environmental impacts from first and last mile portions of

With high potential for automobiles to cause air pollution and greenhouse gas emissions, there is concern that automobiles accessing or egressing public transportation may cause emissions similar to regular automobile use. Due to limited literature and research that evaluates and discusses environmental impacts from first and last mile portions of transit trips, there is a lack of understanding on this topic. This research aims to comprehensively evaluate the life cycle impacts of first and last mile trips on multimodal transit. A case study of transit and automobile travel in the greater Los Angeles region is evaluated by using a comprehensive life cycle assessment combined with regional household travel survey data to evaluate first-last mile trip impacts in multimodal transit focusing on automobile trips accessing or egressing transit. First and last mile automobile trips were found to increase total multimodal transit trip emissions by 2 to 12 times (most extreme cases were carbon monoxide and volatile organic compounds). High amounts of coal-fired energy generation can cause electric propelled rail trips with automobile access or egress to have similar or more emissions (commonly greenhouse gases, sulfur dioxide, and mono-nitrogen oxides) than competing automobile trips, however, most criteria air pollutants occur remotely. Methods to reduce first-last mile impacts depend on the characteristics of the transit systems and may include promoting first-last mile carpooling, adjusting station parking pricing and availability, and increased emphasis on walking and biking paths in areas with low access-egress trip distances.
ContributorsHoehne, Christopher G (Author) / Chester, Mikhail V (Thesis advisor) / Salon, Deborah (Committee member) / Zhou, Xuesong (Committee member) / Arizona State University (Publisher)
Created2016
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Description
Healthcare infection control has led to increased utilization of disposable medical devices, which has subsequently led to increased adverse environmental effects attributed to healthcare and its supply chain. In dental practice, the dental bur is a commonly used instrument that can either be reused or used once and then disposed.

Healthcare infection control has led to increased utilization of disposable medical devices, which has subsequently led to increased adverse environmental effects attributed to healthcare and its supply chain. In dental practice, the dental bur is a commonly used instrument that can either be reused or used once and then disposed. To evaluate the disparities in environmental impacts of disposable and reusable dental burs, a comparative life cycle assessment (LCA) was performed. The comparative LCA evaluated a reusable dental bur (specifically, a 2.00mm Internal Irrigation Pilot Drill) reused 30 instances versus 30 identical burs used as disposables. The LCA methodology was performed using framework described by the International Organization for Standardization (ISO) 14040 series. Sensitivity analyses were performed with respect to ultrasonic and autoclave loading. Findings from this research showed that when the ultrasonic and autoclave are loaded optimally, reusable burs had 40% less of an environmental impact than burs used on a disposable basis. When the ultrasonic and autoclave were loaded to 66% capacity, there was an environmental breakeven point between disposable and reusable burs. Eutrophication, carcinogenic impacts, non-carcinogenic impacts, and acidification were limited when cleaning equipment (i.e., ultrasonic and autoclave) were optimally loaded. Additionally, the bur's packaging materials contributed more negative environmental impacts than the production and use of the bur itself. Therefore, less materially-intensive packaging should be used. Specifically, the glass fiber reinforced plastic casing should be substituted for a material with a reduced environmental footprint.
ContributorsUnger, Scott (Author) / Landis, Amy (Thesis advisor) / Wilson, Natalia (Committee member) / Chester, Mikhail (Committee member) / Arizona State University (Publisher)
Created2013