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Description
Dust devils have proven to be commonplace on Mars, although their occurrence is unevenly distributed across the surface. They were imaged or inferred by all six successful landed spacecraft: the Viking 1 and 2 Landers (VL-1 and VL-2), Mars Pathfinder Lander, the Mars Exploration Rovers Spirit and Opportunity, and the

Dust devils have proven to be commonplace on Mars, although their occurrence is unevenly distributed across the surface. They were imaged or inferred by all six successful landed spacecraft: the Viking 1 and 2 Landers (VL-1 and VL-2), Mars Pathfinder Lander, the Mars Exploration Rovers Spirit and Opportunity, and the Phoenix Mars Lander. Comparisons of dust devil parameters were based on results from optical and meteorological (MET) detection campaigns. Spatial variations were determined based on comparisons of their frequency, morphology, and behavior. The Spirit data spanning three consecutive martian years is used as the basis of comparison because it is the most extensive on this topic. Average diameters were between 8 and 115 m for all observed or detected dust devils. The average horizontal speed for all of the studies was roughly 5 m/s. At each site dust devil densities peaked between 09:00 and 17:00 LTST during the spring and summer seasons supporting insolation-driven convection as the primary formation mechanism. Seasonal number frequency averaged ~1 dust devils/ km2/sol and spanned a total of three orders of magnitude. Extrapolated number frequencies determined for optical campaigns at the Pathfinder and Spirit sites accounted for temporal and spatial inconsistencies and averaged ~19 dust devils/km2/sol. Dust fluxes calculated from Pathfinder data (5x10-4 kg/m2/s and 7x10-5 kg/m2/s) were well with in the ranges calculated from Spirit data (4.0x10-9 to 4.6x10-4 kg/m2/s for Season One, 5.2x10-7 to 6.2x10-5 kg/m2/s during Season Two, and 1.5x10-7 to 1.6x10-4 kg/m2/s during Season Three). Based on the results a campaign is written for improvements in dust devil detection at the Mars Science Laboratory's (MSL) site. Of the four remaining candidate MSL sites, the dusty plains of Gale crater may potentially be the site with the highest probability of dust devil activity.
ContributorsWaller, Devin (Author) / Greeley, Ronald (Thesis advisor) / Christensen, Philip R. (Philip Russel) (Committee member) / Cerveny, Randall (Committee member) / Arizona State University (Publisher)
Created2011
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Description
Among volcanic gases, sulfur dioxide (SO2) is by far the most commonly measured. More than a monitoring proxy for volcanic degassing, SO2 has the potential to alter climate patterns. Persistently active explosive volcanoes are characterized by short explosive bursts, which often occur at periodic intervals numerous times per day,

Among volcanic gases, sulfur dioxide (SO2) is by far the most commonly measured. More than a monitoring proxy for volcanic degassing, SO2 has the potential to alter climate patterns. Persistently active explosive volcanoes are characterized by short explosive bursts, which often occur at periodic intervals numerous times per day, spanning years to decades. SO2 emissions at those volcanoes are poorly constrained, in large part because the current satellite monitoring techniques are unable to detect or quantify plumes of low concentration in the troposphere. Eruption plumes also often show high concentrations of ash and/or aerosols, which further inhibit the detection methods. In this work I focus on quantifying volcanic gas emissions at persistently active explosive volcanoes and their variations over short timescales (minutes to hours), in order to document their contribution to natural SO2 flux as well as investigate the physical processes that control their behavior.

In order to make these measurements, I first develop and assemble a UV ground-based instrument, and validate it against an independently measured source of SO2 at a coal-burning power plant in Arizona. I establish a measurement protocol and demonstrate that the instrument measures SO2 fluxes with < 20 % error. Using the same protocol, I establish a record of the degassing patterns at Semeru volcano (Indonesia), a volcano that has been producing cycles of repeated explosions with periods of minutes to hours for the past several decades. Semeru produces an average of 21-71 tons of SO2 per day, amounting to a yearly output of 8-26 Mt.

Using the Semeru data, along with a 1-D transient numerical model of magma ascent, I test the validity of a model in which a viscous plug at the top of the conduit produces cycles of eruption and gas release. I find that it can be a valid hypothesis to explain the observed patterns of degassing at Semeru. Periodic behavior in such a system occurs for a very narrow range of conditions, for which the mass balance between magma flux and open-system gas escape repeatedly generates a viscous plug, pressurizes the magma beneath the plug, and then explosively disrupts it.
ContributorsSmekens, Jean-François (Author) / Clarke, Amanda (Thesis advisor) / Christensen, Philip R. (Philip Russel) (Committee member) / Williams, Stanley (Committee member) / Burton, Michael (Committee member) / Fink, Jonathan (Committee member) / Moore, Gordon (Committee member) / Arizona State University (Publisher)
Created2015
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Description
Atmospheric particulate matter (PM) has a pronounced effect on our climate, and exposure to PM causes negative health outcomes and elevated mortality rates in urban populations. Reactions that occur in fog can form new secondary organic aerosol material from gas-phase species or primary organic aerosols. It is important to understand

Atmospheric particulate matter (PM) has a pronounced effect on our climate, and exposure to PM causes negative health outcomes and elevated mortality rates in urban populations. Reactions that occur in fog can form new secondary organic aerosol material from gas-phase species or primary organic aerosols. It is important to understand these reactions, as well as how organic material is scavenged and deposited, so that climate and health effects can be fully assessed. Stable carbon isotopes have been used widely in studying gas- and particle-phase atmospheric chemistry. However, the processing of organic matter by fog has not yet been studied, even though stable isotopes can be used to track all aspects of atmospheric processing, from particle formation, particle scavenging, reactions that form secondary organic aerosol material, and particle deposition. Here, carbon isotope analysis is used for the first time to assess the processing of carbonaceous particles by fog.

This work first compares carbon isotope measurements (δ13C) of particulate matter and fog from locations across the globe to assess how different primary aerosol sources are reflected in the atmosphere. Three field campaigns are then discussed that highlight different aspects of PM formation, composition, and processing. In Tempe, AZ, seasonal and size-dependent differences in the δ13C of total carbon and n-alkanes in PM were studied. δ13C was influenced by seasonal trends, including inversion, transport, population density, and photochemical activity. Variations in δ13C among particle size fractions were caused by sources that generate particles in different size modes.

An analysis of PM from urban and suburban sites in northeastern France shows how both fog and rain can cause measurable changes in the δ13C of PM. The δ13C of PM was consistent over time when no weather events occurred, but particles were isotopically depleted by up to 1.1‰ in the presence of fog due to preferential scavenging of larger isotopically enriched particles. Finally, the δ13C of the dissolved organic carbon in fog collected on the coast of Southern California is discussed. Here, temporal depletion of the δ13C of fog by up to 1.2‰ demonstrates its use in observing the scavenging and deposition of organic PM.
ContributorsNapolitano, Denise (Author) / Herckes, Pierre (Thesis advisor) / Fraser, Matthew (Committee member) / Shock, Everett (Committee member) / Arizona State University (Publisher)
Created2018