Matching Items (73)
Description
Understanding and predicting climate changes at the urban scale have been an important yet challenging problem in environmental engineering. The lack of reliable long-term observations at the urban scale makes it difficult to even assess past climate changes. Numerical modeling plays an important role in filling the gap of observation and predicting future changes. Numerical studies on the climatic effect of desert urbanization have focused on basic meteorological fields such as temperature and wind. For desert cities, urban expansion can lead to substantial changes in the local production of wind-blown dust, which have implications for air quality and public health. This study expands the existing framework of numerical simulation for desert urbanization to include the computation of dust generation related to urban land-use changes. This is accomplished by connecting a suite of numerical models, including a meso-scale meteorological model, a land-surface model, an urban canopy model, and a turbulence model, to produce the key parameters that control the surface fluxes of wind-blown dust. Those models generate the near-surface turbulence intensity, soil moisture, and land-surface properties, which are used to determine the dust fluxes from a set of laboratory-based empirical formulas. This framework is applied to a series of simulations for the desert city of Erbil across a period of rapid urbanization. The changes in surface dust fluxes associated with urbanization are quantified. An analysis of the model output further reveals the dependence of surface dust fluxes on local meteorological conditions. Future applications of the models to environmental prediction are discussed.
ContributorsTahir, Sherzad Tahseen (Author) / Huang, Huei-Ping (Thesis advisor) / Phelan, Patrick (Committee member) / Herrmann, Marcus (Committee member) / Chen, Kangping (Committee member) / Clarke, Amanda (Committee member) / Arizona State University (Publisher)
Created2019
Description
Human endeavors move 7x more volume of earth than the world’s rivers accelerating the removal of Earth’s soil surface. Measuring anthropogenic acceleration of soil erosion requires knowledge of natural rates through the study of 10Be, but same-watershed comparisons between anthropogenically-accelerated and natural erosion rates do not exist for urbanizing watersheds. Here I show that urban sprawl from 1989 to 2013 accelerated soil erosion between 1.3x and 15x above natural rates for different urbanizing watersheds in the metropolitan Phoenix region, Sonoran Desert, USA, and that statistical modeling a century of urban sprawl indicates an acceleration of only 2.7x for the Phoenix region. Based on studies of urbanization’s erosive effects, and studies comparing other land-use changes to natural erosion rates, we expected a greater degree of urban acceleration. Given that continued urban expansion will add a new city of a million every five days until 2050, given the potential importance of urban soils for absorbing anthropogenically-released carbon, and given the role of urban-sourced pollution, quantifying urbanization’s acceleration of natural erosion in other urban settings could reveal important regional patterns. For example, a comparison of urban watersheds to nearby non-urban watersheds suggests that the Phoenix case study is on the low-end of the urban acceleration factor. This new insight into the urban acceleration of soil erosion in metropolitan Phoenix can help reduce the acute risk of flooding for many rapidly urbanizing desert cities around the globe. To reduce this risk, properly engineered Flood Control Structures must account for sediment accumulation as well as flood waters. While the Phoenix area used regional data from non-urban, non-desert watersheds to generate sediment yield rates, this research presents a new analysis of empirical data for the Phoenix metropolitan region, where two regression models provide estimates of a more realistic sediment accumulation for arid regions and also urbanization of a desert cities. The new model can be used to predict the realistic sediment accumulation for helping provide data where few data exists in parts of arid Africa, southwest Asia, and India.
ContributorsJeong, Ara (Author) / Dorn, Ronald I. (Thesis advisor) / Schmeeckle, Mark (Committee member) / Walker, Ian J. (Committee member) / Arizona State University (Publisher)
Created2019
Description
Biodiversity is required to guarantee proper ecosystem structure and function. However, increasing anthropogenic threats are causing biodiversity loss around the world at an unprecedented rate, in what has been deemed the sixth mass extinction. To counteract this crisis, conservationists seek to improve the methods used in the design and implementation of protected areas, which help mitigate the impacts of human activities on species. Marine mammals are ecosystem engineers and important indicator species of ocean and human wellbeing. They are also disproportionally less known and more threatened than terrestrial mammals. Therefore, surrogates of biodiversity must be used to maximize their representation in conservation planning. Some of the most effective surrogates of biodiversity known have only been tested in terrestrial systems. Here I test complementarity, rarity, and environmental diversity as potential surrogates of marine mammal representation at the global scale, and compare their performance against species richness, which is the most popular surrogate used to date. I also present the first map of marine mammal complementarity, and assess its relationship with environmental variables to determine if environmental factors could also be used as surrogates. Lastly, I determine the global complementarity-based hotspots of marine mammal biodiversity, and compare their distributions against current marine protected area coverage and exposure to global indices of human threats, to elucidate the effectiveness of current conservation efforts. Results show that complementarity, rarity, and environmental diversity are all efficient surrogates, as they outcompete species richness in maximizing marine mammal species representation when solving the minimum-set coverage problem. Results also show that sea surface temperature, density, and bathymetry are the top environmental variables most associated with complementarity of marine mammals. Finally, gap analyses show that marine mammals are overall poorly protected, yet moderately exposed to hotspots of cumulative human impacts. The wide distribution of marine mammals justify global studies like the ones here presented, to determine the best strategy for their protection. Overall, my findings show that less popular surrogates of biodiversity are more effective for marine mammals and should be considered in their management, and that the expansion of protected areas in their most important habitats should be prioritized.
ContributorsAstudillo-Scalia, Yaiyr (Author) / Albuquerque, Fabio (Thesis advisor) / Deviche, Pierre (Thesis advisor) / Polidoro, Beth (Committee member) / Kellar, Nicholas (Committee member) / Arizona State University (Publisher)
Created2019
Description
This dissertation critically evaluated methodologies and devices for assessing and protecting the health of human populations, with particular emphasis on groundwater remediation and the use of wastewater-based epidemiology (WBE) to inform population health. A meta-analysis and assessment of laboratory-scale treatability studies for removing chlorinated solvents from groundwater found that sediment microcosms operated as continuous-flow columns are preferable to batch bottles when seeking to emulate with high fidelity the complex conditions prevailing in the subsurface in contaminated aquifers (Chapter 2). Compared to monitoring at the field-scale, use of column microcosms also showed (i) improved chemical speciation, and (ii) qualitative predictability of field parameters (Chapter 3). Monitoring of glucocorticoid hormones in wastewater of a university campus showed (i) elevated stress levels particularly at the start of the semester, (ii) on weekdays relative to weekend days (p = 0.05) (161 ± 42 μg d-1 per person, 122 ± 54 μg d-1 per person; p ≤ 0.05), and (iii) a positive association between levels of stress hormones and nicotine (rs: 0.49) and caffeine (0.63) consumption in this student population (Chapter 4). Also, (i) alcohol consumption determined by WBE was in line with literature estimates for this young sub-population (11.3 ± 7.5 g d-1 per person vs. 10.1 ± 0.8 g d-1 per person), whereas caffeine and nicotine uses were below (114 ± 49 g d-1 per person, 178 ± 19 g d-1 per person; 627 ± 219 g d-1 per person, 927 ± 243 g d-1 per person). The introduction of a novel continuous in situ sampler to WBE brought noted benefits relative to traditional time-integrated sampling, including (i) a higher sample coverage (93% vs. 3%), (ii) an ability to captured short-term analyte pulses (e.g., heroin, fentanyl, norbuprenorphine, and methadone), and (iii) an overall higher mass capture for drugs of abuse like morphine, fentanyl, methamphetamine, amphetamine, and the opioid antagonist metabolite norbuprenorphine (p ≤ 0.01). Methods and devices developed in this work are poised to find applications in the remediation sector and in human health assessments.
ContributorsDriver, Erin Michelle (Author) / Halden, Rolf (Thesis advisor) / Conroy-Ben, Otakuye (Committee member) / Kavazanjian, Edward (Committee member) / Krajmalnik-Brown, Rosa (Committee member) / Arizona State University (Publisher)
Created2018
Description
Monsoon hazards routinely affect the community, economy, and environment of the American Southwest. A common link for hazard development during the North American Monsoon concerns the interplay between temperature, moisture, and wind in the vertical atmosphere controlled by an unstable monsoon circulation. This dissertation investigates vertical atmospheric patterns using in-situ sounding data, specifically, 1) environments favorable for severe hail on the Colorado Plateau, 2) significant parameters distinguishing unhealthy versus healthy ozone days in Phoenix, Arizona, and 3) vertical profile alignments associated with distinct ranges in ozone concentrations observed in Phoenix having defined health impacts.
The first study (published in the Journal of the Arizona-Nevada Academy of Science) determines significant variables on Flagstaff, Arizona 12Z rawinsonde data (1996-2009) found on severe hail days on the Colorado Plateau. Severe hail is related to greater sub-300 hectopascals (hPa) moisture, a warmer atmospheric column, lighter above surface wind speeds, more southerly to southeasterly oriented winds throughout the vertical (except at the 700 hPa pressure level), and higher geopotential heights.
The second study (published in Atmospheric Environment) employs principal component, linear discriminant, and synoptic composite analyses using Phoenix, Arizona rawinsonde data (2006-2016) to identify common monsoon patterns affecting ozone accumulation in the Phoenix metropolitan area. Unhealthy ozone occurs with amplified high-pressure ridging over the Four Corners region, 500 hPa heights often exceeding 5910 meters, surface afternoon temperatures typically over 40°C, lighter wind speeds in the planetary boundary layer under four ms-1, and persistent light easterly flow between 700-500 hPa countering the daytime mountain-valley circulation.
The final study (under revision in Weather and Forecasting) assesses composite atmospheric sounding analysis to forecast Air Quality Index ozone classifications of Good, Moderate, and collectively categories exceeding the U.S. EPA 2015 standard. The analysis, using Phoenix 12Z rawinsonde data (2006-2017), identifies the existence of “pollutant dispersion windows” for ozone accumulation and dispersal in Phoenix.
Ultimately, monsoon hazards result from a complex and evolving vertical atmosphere. This dissertation demonstrates the viability using available in-situ vertical upper-air data to anticipate recurring atmospheric states contributing to specific hazards. These results will improve monsoon hazard prediction in an effort to protect public and infrastructure.
The first study (published in the Journal of the Arizona-Nevada Academy of Science) determines significant variables on Flagstaff, Arizona 12Z rawinsonde data (1996-2009) found on severe hail days on the Colorado Plateau. Severe hail is related to greater sub-300 hectopascals (hPa) moisture, a warmer atmospheric column, lighter above surface wind speeds, more southerly to southeasterly oriented winds throughout the vertical (except at the 700 hPa pressure level), and higher geopotential heights.
The second study (published in Atmospheric Environment) employs principal component, linear discriminant, and synoptic composite analyses using Phoenix, Arizona rawinsonde data (2006-2016) to identify common monsoon patterns affecting ozone accumulation in the Phoenix metropolitan area. Unhealthy ozone occurs with amplified high-pressure ridging over the Four Corners region, 500 hPa heights often exceeding 5910 meters, surface afternoon temperatures typically over 40°C, lighter wind speeds in the planetary boundary layer under four ms-1, and persistent light easterly flow between 700-500 hPa countering the daytime mountain-valley circulation.
The final study (under revision in Weather and Forecasting) assesses composite atmospheric sounding analysis to forecast Air Quality Index ozone classifications of Good, Moderate, and collectively categories exceeding the U.S. EPA 2015 standard. The analysis, using Phoenix 12Z rawinsonde data (2006-2017), identifies the existence of “pollutant dispersion windows” for ozone accumulation and dispersal in Phoenix.
Ultimately, monsoon hazards result from a complex and evolving vertical atmosphere. This dissertation demonstrates the viability using available in-situ vertical upper-air data to anticipate recurring atmospheric states contributing to specific hazards. These results will improve monsoon hazard prediction in an effort to protect public and infrastructure.
ContributorsMalloy, Jonny William (Author) / Cerveny, Randall S. (Thesis advisor) / Selover, Nancy J (Committee member) / Brazel, Anthony J. (Committee member) / Balling, Robert C. (Committee member) / Arizona State University (Publisher)
Created2019
Description
Six high-production-volume neonicotinoids were traced through a municipal wastewater treatment plant (WWTP) and engineered wetland located downstream, in a study motivated by reports on these insecticides posing threats to non-target invertebrate species and potentially playing a role in the global honeybee colony collapse disorder. An array of automated samplers was deployed in a five-day monitoring campaign and resultant flow-weighted samples were analyzed by liquid chromatography tandem mass spectrometry (LC-MS/MS) using the isotope dilution method. Concentrations in WWTP influent and effluent were 54.7 ± 2.9 and 48.6 ± 2.7 ng/L for imidacloprid, respectively, and 3.7 ± 0.3 and 1.8 ± 0.1 ng/L for acetamiprid, respectively. A mass balance over the WWTP showed no (p=0.09, CI = 95%) removal of imidacloprid, and 56 ± 6% aqueous removal of acetamiprid. In the constructed wetland downstream, a lack of removal was noted for both imidacloprid (from 54.4 ± 3.4 ng/L to 49.9 ± 14.6 ng/L) and acetamiprid (from 2.00 ± 0.03 ng/L to 2.30 ± 0.21 ng/L). Clothianidin was detected only inconsistently in the WWTP and wetland (>2 to 288 ng/L; 60% detection frequency), whereas thiamethoxam (<10 ng/L), thiacloprid (<2 ng/L), and dinotefuran (<180 ng/L) were not detected at all. Thus, imidacloprid and acetamiprid were identified as recalcitrant sewage constituents (estimated U.S. WWTP discharge of 1920- 4780 kg/y) that persist during conventional wastewater treatment to enter U.S. surface waters at potentially harmful concentrations.
ContributorsSadaria, Akash Mahendra (Author) / Halden, Rolf (Thesis advisor) / Fox, Peter (Committee member) / Popat, Sudeep (Committee member) / Arizona State University (Publisher)
Created2015
Description
Residents of the United States increasingly support organic and local food systems. New Social Movement theorists have described alternative agriculture as a social movement that transcends social class. Other scholars have critiqued alternative agriculture for catering to a middle-class, white public. Simultaneously, geographers have identified communities across the United States that struggle with reduced access to healthy fruits and vegetables. In some of these neighborhoods, known as “food deserts,” local groups are redefining an inequitable distribution of healthy food as a social injustice, and they have begun initiatives to practice “food justice.” The overarching research questions of this study are: 1) How do communities become food deserts? 2) How do food justice movements crystallize and communities practice food justice? 3) What are the social outcomes of food justice movements? Using an Ecology of Actors framework, this study analyzes the actors and operational scales of three food justice movements in Phoenix, Arizona. A narrative analysis of historical scholarly materials and other artifacts reveals that, for more than a century, some communities have tried to create minority-operated local food systems. However, they were thwarted by racist policies and market penetration of the conventional US food system. Interviews with residents, garden organizers and food justice advocates living and working in the city create a narrative of the present day struggle for food justice. Results of this work show that contemporary residents describe their foodscape as one of struggle, and carless residents rely upon social networks to access healthy food. Garden organizers and gardeners are creating networks of community gardens, market gardens, and informal farmers’ markets. They are actively transforming their communities’ landscapes with sophisticated garden ecology in an intense urban heat island. However, the movement’s continued success may be threatened. Many new Phoenix-based local food coalitions and national alternative agriculture social movements are now working to alter Phoenix’s foodscape. Composed of well-educated professionals, who have adopted a justice-based language around food, these organizations may unintentionally co-opt the local food justice movements.
ContributorsBleasdale, Thomas (Author) / Harlan, Sharon L (Thesis advisor) / McHugh, Kevin (Committee member) / Bolin, Bob (Committee member) / Arizona State University (Publisher)
Created2015
Description
Marine pico-cyanobacteria of the genera Synechococcus and Prochlorococcus carry out nearly two thirds of the primary production in oligotrophic oceans. These cyanobacteria are also considered an important constituent of the biological carbon pump, the photosynthetic fixation of CO2 to dissolved and particulate organic carbon and subsequent export to the ocean’s interior. But single cells of these cyanobacteria are too small to sink, so their carbon export has to be mediated by aggregate formation and/or consumption by zooplankton that produce sinking fecal pellets. In this dissertation, I investigated for the first time the aggregation of these cyanobacteria by studying the marine Synechococcus sp. strain WH8102 as a model organism. I first found in culture experiments that Synechococcus cells aggregated and that such aggregation of cells was related to the production of transparent exopolymeric particles (TEP), known to provide the main matrix of aggregates of eukaryotic phytoplankton. I also found that despite the lowered growth rates, cells in the nitrogen or phosphorus limited cultures had a higher cell-normalized TEP production and formed a greater total volume of aggregates with higher settling velocities compared to cells in the nutrient replete cultures. I further studied the Synechococcus aggregation in roller tanks that allow the simulation of aggregates settling in the water column, and investigated the effects of the clays kaolinite and bentonite that are commonly found in the ocean. In the roller tanks, Synechococcus cells formed aggregates with diameters of up to 1.4 mm and sinking velocities of up to 440 m/d, comparable to those of larger eukaryotic phytoplankton such as diatoms. In addition, the clay minerals increased the number but reduced the size of aggregates, and their ballasting effects increased the sinking velocity and the carbon export potential of the aggregates. Lastly, I investigated the effects of heterotrophic bacteria on the Synechococcus aggregation, and found that heterotrophic bacteria generally resulted in the formation of fewer, but larger and faster sinking aggregates, and eventually led to an enhanced aggregation of cells and particles. My study contributes to the understanding of the role of marine pico-cyanobacteria in the ecology and biogeochemistry of oligotrophic oceans.
ContributorsDeng, Wei (Author) / Neuer, Susanne (Thesis advisor) / Anbar, Ariel (Committee member) / Passow, Uta (Committee member) / Vermaas, Willem (Committee member) / Arizona State University (Publisher)
Created2016
Description
N-Nitrosodimethylamine (NDMA), a probable human carcinogen, has been found in clouds and fogs at concentration up to 500 ng/L and in drinking water as disinfection by-product. NDMA exposure to the general public is not well understood because of knowledge gaps in terms of occurrence, formation and fate both in air and water. The goal of this dissertation was to contribute to closing these knowledge gaps on potential human NDMA exposure through contributions to atmospheric measurements and fate as well as aqueous formation processes.
Novel, sensitive methods of measuring NDMA in air were developed based on Solid Phase Extraction (SPE) and Solid Phase Microextraction (SPME) coupled to Gas Chromatography-Mass Spectrometry (GC-MS). The two measuring techniques were evaluated in laboratory experiments. SPE-GC-MS was applicable in ambient air sampling and NDMA in ambient air was found in the 0.1-13.0 ng/m3 range.
NDMA photolysis, the main degradation atmospheric pathway, was studied in the atmospheric aqueous phase. Water soluble organic carbon (WSOC) was found to have more impact than inorganic species on NDMA photolysis by competing with NDMA for photons and therefore could substantially increase the NDMA lifetime in the atmosphere. The optical properties of atmospheric WSOC were investigated in aerosol, fog and cloud samples and showed WSOC from atmospheric aerosols has a higher mass absorption efficiency (MAE) than organic matter in fog and cloud water, resulting from a different composition, especially in regards of volatile species, that are not very absorbing but abundant in fogs and clouds.
NDMA formation kinetics during chloramination were studied in aqueous samples including wastewater, surface water and ground water, at two monochloramine concentrations. A simple second order NDMA formation model was developed using measured NDMA and monochloramine concentrations at select reaction times. The model fitted the NDMA formation well (R2 >0.88) in all water matrices. The proposed model was then optimized and applied to fit the data of NDMA formation from natural organic matter (NOM) and model precursors in previously studies. By determining the rate constants, the model was able to describe the effect of water conditions such as DOC and pH on NDMA formation.
Novel, sensitive methods of measuring NDMA in air were developed based on Solid Phase Extraction (SPE) and Solid Phase Microextraction (SPME) coupled to Gas Chromatography-Mass Spectrometry (GC-MS). The two measuring techniques were evaluated in laboratory experiments. SPE-GC-MS was applicable in ambient air sampling and NDMA in ambient air was found in the 0.1-13.0 ng/m3 range.
NDMA photolysis, the main degradation atmospheric pathway, was studied in the atmospheric aqueous phase. Water soluble organic carbon (WSOC) was found to have more impact than inorganic species on NDMA photolysis by competing with NDMA for photons and therefore could substantially increase the NDMA lifetime in the atmosphere. The optical properties of atmospheric WSOC were investigated in aerosol, fog and cloud samples and showed WSOC from atmospheric aerosols has a higher mass absorption efficiency (MAE) than organic matter in fog and cloud water, resulting from a different composition, especially in regards of volatile species, that are not very absorbing but abundant in fogs and clouds.
NDMA formation kinetics during chloramination were studied in aqueous samples including wastewater, surface water and ground water, at two monochloramine concentrations. A simple second order NDMA formation model was developed using measured NDMA and monochloramine concentrations at select reaction times. The model fitted the NDMA formation well (R2 >0.88) in all water matrices. The proposed model was then optimized and applied to fit the data of NDMA formation from natural organic matter (NOM) and model precursors in previously studies. By determining the rate constants, the model was able to describe the effect of water conditions such as DOC and pH on NDMA formation.
ContributorsZhang, Jinwei (Author) / Herckes, Pierre (Thesis advisor) / Westerhoff, Paul (Thesis advisor) / Fraser, Matthew (Committee member) / Shock, Everett (Committee member) / Arizona State University (Publisher)
Created2016
Description
The worldwide supply of potable fresh water is ever decreasing. While 2.5% of Earth's water is fresh, only 1% is accessible. Of this water, the World Health Organization estimates that only one-third can be used to meet our daily needs while the other two-thirds are unusable due to contamination. As the world population continues to grow and climate change reduces water security, we must consider not only solutions, but evaluate the perceptions and reactions of individuals in order to successfully implement such solutions. To that end, the goal of this dissertation is to explore human attitudes, beliefs, and behaviors around water issues by conducting cross-cultural comparisons of (1) water risks and solutions, (2) wastewater knowledge and acceptance, and (3) motivators for willingness to use treated wastewater. Previous research in these domains has primarily focused on a single site or national context. While such research is valuable for establishing how and why cultural context matters, comparative studies are also needed to help link perceptions at local and global scales. Adopting an interdisciplinary approach grounded in anthropological methods and theory, I use interview data collected in a range of international sites as part of the Arizona State University's Global Ethnohydrology Study. With funding from National Science Foundation grants to the Decision Center for a Desert City (DCDC) and the Central Arizona-Phoenix Long-Term Ecological Research project (CAP LTER), this dissertation explores cross-cultural perceptions of water threats and management strategies, specifically wastewater reclamation and reuse, in order to make recommendations for policy makers and water managers.
ContributorsStotts, Rhian (Author) / Wutich, Amber (Thesis advisor) / BurnSilver, Shauna (Committee member) / Grossman, Gary (Committee member) / White, Dave (Committee member) / Arizona State University (Publisher)
Created2016