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Monsoon hazards routinely affect the community, economy, and environment of the American Southwest. A common link for hazard development during the North American Monsoon concerns the interplay between temperature, moisture, and wind in the vertical atmosphere controlled by an unstable monsoon circulation. This dissertation investigates vertical atmospheric patterns using in-situ

Monsoon hazards routinely affect the community, economy, and environment of the American Southwest. A common link for hazard development during the North American Monsoon concerns the interplay between temperature, moisture, and wind in the vertical atmosphere controlled by an unstable monsoon circulation. This dissertation investigates vertical atmospheric patterns using in-situ sounding data, specifically, 1) environments favorable for severe hail on the Colorado Plateau, 2) significant parameters distinguishing unhealthy versus healthy ozone days in Phoenix, Arizona, and 3) vertical profile alignments associated with distinct ranges in ozone concentrations observed in Phoenix having defined health impacts.

The first study (published in the Journal of the Arizona-Nevada Academy of Science) determines significant variables on Flagstaff, Arizona 12Z rawinsonde data (1996-2009) found on severe hail days on the Colorado Plateau. Severe hail is related to greater sub-300 hectopascals (hPa) moisture, a warmer atmospheric column, lighter above surface wind speeds, more southerly to southeasterly oriented winds throughout the vertical (except at the 700 hPa pressure level), and higher geopotential heights.

The second study (published in Atmospheric Environment) employs principal component, linear discriminant, and synoptic composite analyses using Phoenix, Arizona rawinsonde data (2006-2016) to identify common monsoon patterns affecting ozone accumulation in the Phoenix metropolitan area. Unhealthy ozone occurs with amplified high-pressure ridging over the Four Corners region, 500 hPa heights often exceeding 5910 meters, surface afternoon temperatures typically over 40°C, lighter wind speeds in the planetary boundary layer under four ms-1, and persistent light easterly flow between 700-500 hPa countering the daytime mountain-valley circulation.

The final study (under revision in Weather and Forecasting) assesses composite atmospheric sounding analysis to forecast Air Quality Index ozone classifications of Good, Moderate, and collectively categories exceeding the U.S. EPA 2015 standard. The analysis, using Phoenix 12Z rawinsonde data (2006-2017), identifies the existence of “pollutant dispersion windows” for ozone accumulation and dispersal in Phoenix.

Ultimately, monsoon hazards result from a complex and evolving vertical atmosphere. This dissertation demonstrates the viability using available in-situ vertical upper-air data to anticipate recurring atmospheric states contributing to specific hazards. These results will improve monsoon hazard prediction in an effort to protect public and infrastructure.
ContributorsMalloy, Jonny William (Author) / Cerveny, Randall S. (Thesis advisor) / Selover, Nancy J (Committee member) / Brazel, Anthony J. (Committee member) / Balling, Robert C. (Committee member) / Arizona State University (Publisher)
Created2019
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Description
Air pollution is a serious problem in most urban areas around the world, which has a number of negative ecological and human health impacts. As a result, it's vitally important to detect and characterize air pollutants to protect the health of the urban environment and our citizens. An important early

Air pollution is a serious problem in most urban areas around the world, which has a number of negative ecological and human health impacts. As a result, it's vitally important to detect and characterize air pollutants to protect the health of the urban environment and our citizens. An important early step in this process is ensuring that the air pollution monitoring network is properly designed to capture the patterns of pollution and that all social demographics in the urban population are represented. An important aspect in characterizing air pollution patterns is scale in space and time which, along with pattern and process relationships, is a key subject in the field of landscape ecology. Thus, using multiple landscape ecological methods, this dissertation research begins by characterizing and quantifying the multi-scalar patterns of ozone (O3) and particulate matter (PM10) in the Phoenix, Arizona, metropolitan region. Results showed that pollution patterns are scale-dependent, O3 is a regionally-scaled pollutant at longer temporal scales, and PM10 is a locally-scaled pollutant with patterns sensitive to season. Next, this dissertation examines the monitoring network within Maricopa County. Using a novel multiscale indicator-based approach, the adequacy of the network was quantified by integrating inputs from various academic and government stakeholders. Furthermore, deficiencies were spatially defined and recommendations were made on how to strengthen the design of the network. A sustainability ranking system also provided new insight into the strengths and weaknesses of the network. Lastly, the study addresses the question of whether distinct social groups were experiencing inequitable exposure to pollutants - a key issue of distributive environmental injustice. A novel interdisciplinary method using multi-scalar ambient pollution data and hierarchical multiple regression models revealed environmental inequities between air pollutants and race, ethnicity, age, and socioeconomic classes. The results indicate that changing the scale of the analysis can change the equitable relationship between pollution and demographics. The scientific findings of the scale-dependent relationships among air pollution patterns, network design, and population demographics, brought to light through this study, can help policymakers make informed decisions for protecting the human health and the urban environment in the Phoenix metropolitan region and beyond.
ContributorsPope, Ronald L (Author) / Wu, Jianguo (Thesis advisor) / Boone, Christopher G. (Committee member) / Brazel, Anthony J. (Committee member) / Forzani, Erica S. (Committee member) / Fraser, Matthew P. (Committee member) / Arizona State University (Publisher)
Created2014
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Description
Fossil fuel CO2 (FFCO2) emissions are recognized as the dominant greenhouse gas driving climate change (Enting et. al., 1995; Conway et al., 1994; Francey et al., 1995; Bousquet et. al., 1999). Transportation is a major component of FFCO2 emissions, especially in urban areas. An improved understanding of on-road FFCO2 emission

Fossil fuel CO2 (FFCO2) emissions are recognized as the dominant greenhouse gas driving climate change (Enting et. al., 1995; Conway et al., 1994; Francey et al., 1995; Bousquet et. al., 1999). Transportation is a major component of FFCO2 emissions, especially in urban areas. An improved understanding of on-road FFCO2 emission at high spatial resolution is essential to both carbon science and mitigation policy. Though considerable research has been accomplished within a few high-income portions of the planet such as the United States and Western Europe, little work has attempted to comprehensively quantify high-resolution on-road FFCO2 emissions globally. Key questions for such a global quantification are: (1) What are the driving factors for on-road FFCO2 emissions? (2) How robust are the relationships? and (3) How do on-road FFCO2 emissions vary with urban form at fine spatial scales?

This study used urban form/socio-economic data combined with self-reported on-road FFCO2 emissions for a sample of global cities to estimate relationships within a multivariate regression framework based on an adjusted STIRPAT model. The on-road high-resolution (whole-city) regression FFCO2 model robustness was evaluated by introducing artificial error, conducting cross-validation, and assessing relationship sensitivity under various model specifications. Results indicated that fuel economy, vehicle ownership, road density and population density were statistically significant factors that correlate with on-road FFCO2 emissions. Of these four variables, fuel economy and vehicle ownership had the most robust relationships.

A second regression model was constructed to examine the relationship between global on-road FFCO2 emissions and urban form factors (described by population

ii

density, road density, and distance to activity centers) at sub-city spatial scales (1 km2). Results showed that: 1) Road density is the most significant (p<2.66e-037) predictor of on-road FFCO2 emissions at the 1 km2 spatial scale; 2) The correlation between population density and on-road FFCO2 emissions for interstates/freeways varies little by city type. For arterials, on-road FFCO2 emissions show a stronger relationship to population density in clustered cities (slope = 0.24) than dispersed cities (slope = 0.13). FFCO2 3) The distance to activity centers has a significant positive relationship with on-road FFCO2 emission for the interstate and freeway toad types, but an insignificant relationship with the arterial road type.
ContributorsSong, Yang (Author) / Gurney, Kevin (Thesis advisor) / Kuby, Michael (Committee member) / Golub, Aaron (Committee member) / Chester, Mikhail (Committee member) / Selover, Nancy (Committee member) / Arizona State University (Publisher)
Created2018