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Description
The volume of end-of-life photovoltaic (PV) modules is increasing as the global PV market increases, and the global PV waste streams are expected to reach 250,000 metric tons by the end of 2020. If the recycling processes are not in place, there would be 60 million tons of end-of-life PV modules lying in the landfills by 2050, that may not become a not-so-sustainable way of sourcing energy since all PV modules could contain certain amount of toxic substances. Currently in the United States, PV modules are categorized as general waste and can be disposed in landfills. However, potential leaching of toxic chemicals and materials, if any, from broken end-of-life modules may pose health or environmental risks. There is no standard procedure to remove samples from PV modules for chemical toxicity testing in the Toxicity Characteristic Leaching Procedure (TCLP) laboratories as per EPA 1311 standard. The main objective of this thesis is to develop an unbiased sampling approach for the TCLP testing of PV modules. The TCLP testing was concentrated only for the laminate part of the modules, as they are already existing recycling technologies for the frame and junction box components of PV modules. Four different sample removal methods have been applied to the laminates of five different module manufacturers: coring approach, cell-cut approach, strip-cut approach, and hybrid approach. These removed samples were sent to two different TCLP laboratories, and TCLP results were tested for repeatability within a lab and reproducibility between the labs. The pros and cons of each sample removal method have been explored and the influence of sample removal methods on the variability of TCLP results has been discussed. To reduce the variability of TCLP results to an acceptable level, additional improvements in the coring approach, the best of the four tested options, are still needed.
ContributorsLeslie, Joswin (Author) / Tamizhmani, Govindasamy (Thesis advisor) / Srinivasan, Devarajan (Committee member) / Kuitche, Joseph (Committee member) / Arizona State University (Publisher)
Created2018
Description
ABSTRACT The high percentage and the steady growth of Hispanic/Latino students in Arizona demand that special attention be placed on improving academic achievement and attainment. The need to support Hispanic/Latino parents in becoming meaningful positive contributors to their children's schooling continues to surface as a critical issue in school improvement efforts in many Arizona districts. American Dream Academy, part of the Center for Community Development and Civil Rights at Arizona State University, has aimed to address this critical issue. Their focus has been to change Latino parents' beliefs about, knowledge of, and behaviors related to their children's education from pre-kindergarten to the post-secondary level. The Hoover-Dempsey and Sandler model, Realizing the American Dream, for parental involvement was the basis for the design of the curriculum used by the American Dream Academy. The purpose of this study was to analyze the efficacy of the American Dream Academy in changing the beliefs, knowledge, and behaviors of parents. The data sources were demographic and pre- and post-academy surveys taken by 719 parents representing 42 Title 1 school districts throughout Maricopa County, Arizona during the spring semester of 2012. Two tailed t tests and the significant p values revealed statistically significant changes after participation in the academy for each one of the survey statement constructs, beliefs, knowledge, and behaviors. A computation of the effect sizes using Cohen's d revealed that there were moderate to large effect sizes for each of the constructs. The knowledge construct had the largest effect size. Pearson correlation coefficients revealed that the gains for each construct were positively correlated with each of the other constructs and that the relationships were statistically significant. The significant effects of the American Dream Academy's curriculum were considerable in changing parents' beliefs, knowledge, and behaviors as to pre-kindergarten and post-secondary education. Of special notice is the effect that the academy had on parents' knowledge of how to help their children as they navigate through the United States' educational system. It is recommended that school districts partner with the American Dream Academy in efforts to engage parents in meaningful participation.
ContributorsPortillo, Danelia (Author) / Spencer, Dee Ann (Thesis advisor) / Appleton, Nicholas A (Committee member) / Diaz, René X (Committee member) / Arizona State University (Publisher)
Created2013