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- All Subjects: air monitoring
- Creators: Brown, Albert
Description
Second-generation biofuel feedstocks are currently grown in land-based systems that use valuable resources like water, electricity and fertilizer. This study investigates the potential of near-shore marine (ocean) seawater filtration as a source of planktonic biomass for biofuel production. Mixed marine organisms in the size range of 20µm to 500µm were isolated from the University of California, Santa Barbara (UCSB) seawater filtration system during weekly backwash events between the months of April and August, 2011. The quantity of organic material produced was determined by sample combustion and calculation of ash-free dry weights. Qualitative investigation required density gradient separation with the heavy liquid sodium metatungstate followed by direct transesterification and gas chromatography with mass spectrometry (GC-MS) of the fatty acid methyl esters (FAME) produced. A maximum of 0.083g/L of dried organic material was produced in a single backwash event and a study average of 0.036g/L was calculated. This equates to an average weekly value of 7,674.75g of dried organic material produced from the filtration of approximately 24,417,792 liters of seawater. Temporal variations were limited. Organic quantities decreased over the course of the study. Bio-fouling effects from mussel overgrowth inexplicably increased production values when compared to un-fouled seawater supply lines. FAMEs (biodiesel) averaged 0.004% of the dried organic material with 0.36ml of biodiesel produced per week, on average. C16:0 and C22:6n3 fatty acids comprised the majority of the fatty acids in the samples. Saturated fatty acids made up 30.71% to 44.09% and unsaturated forms comprised 55.90% to 66.32% of the total chemical composition. Both quantities and qualities of organics and FAMEs were unrealistic for use as biodiesel but sample size limitations, system design, geographic and temporal factors may have impacted study results.
ContributorsPierre, Christophe (Author) / Olson, Larry (Thesis advisor) / Sommerfeld, Milton (Committee member) / Brown, Albert (Committee member) / Arizona State University (Publisher)
Created2011
Description
United States Environmental Protection Agency (USEPA) had identified and recommended air quality monitoring to take place at 63 schools throughout the country. Unfortunately, tribal schools were not considered during the time USEPA conducted the analysis. The importance of identifying any air toxic pollutants affecting school children needs to be analyzed. Conducting an air monitoring toxic analysis on the Navajo Nation at Church Rock Elementary School, Church Rock, New Mexico (CRNM) was carried out. The current school location posed a concern, in regards to the surrounding stationary, mobile, and natural emissions emitted all types of toxic pollutants. USEPA sponsors various air monitoring program, which Tribal Air Monitoring Support (TAMS) program undertook, and offered tribal programs, organizations or agencies to utilized air monitoring equipment's. The air monitoring setup was conducted with the contract Eastern Research Group, Inc. (ERG) laboratory, where collection of 24-hour ambient air samples for 60 days on a 6-day sampling interval were performed. The analysis for volatile organic compounds (VOCs)were collected from canister samples using USEPA Compendium Method TO-15, polycyclic aromatic hydrocarbons (PAHs) from polyurethane foam (PUF) and XAD-2 resin samples using USEPA Compendium Method TO-13A. Carbonyl compounds were collected by sorbent cartridge samples using USEPA Compendium Method TO-11A, and trace of metals from filters were sampled using USEPA Compendium Method IO-3.5 and FEM EQL-0512-202. A total of 53 VOC concentrations were greater than 1 μg/m3, where dichlorodifluoromethane, trichlorofluoromethane, chloromethane, dichloromethane, propylene, toluene, acrolein and acetylene were detected. A total of 23 carbonyl compound concentrations were greater than 1 μg/m3, where acetone and formaldehyde were measured. Naphthalene average with the highest average for PAHs, where phenanthrene and retene were the second and third highest averages. As for the metals the highest averages resulted from manganese, chromium and lead. Overall, the air toxic pollutants resulted from CRNM surrounding monitoring site were detected. Identifying the potential emitter source or sources cannot be assessed.
ContributorsBilley, Karmen (Author) / Olson, Larry (Thesis advisor) / Peterson, Danny (Committee member) / Brown, Albert (Committee member) / Arizona State University (Publisher)
Created2015