Matching Items (2)
Filtering by
- Creators: Hartnett, Hilairy
Description
Shallow earthquakes in the upper part of the overriding plate of subduction zones can be devastating due to their proximity to population centers despite the smaller rupture extents than commonly occur on subduction megathrusts that produce the largest earthquakes. Damaging effects can be greater in volcanic arcs like Java because ground shaking is amplified by surficial deposits of uncompacted volcaniclastic sediments. Identifying the upper-plate structures and their potential hazards is key for minimizing the dangers they pose. In particular, the knowledge of the regional stress field and deformation pattern in this region will help us to better understand how subduction and collision affects deformation in this part of the overriding plate. The majority of the upper plate deformation studies have been focused on the deformation in the main thrusts of the fore-arc region. Study of deformation within volcanic arc is limited despite the associated earthquake hazards. In this study, I use maps of active upper-plate structures, earthquake moment tensor data and stress orientation deduced from volcano morphology analysis to characterize the strain field of Java arc. In addition, I use sandbox analog modeling to evaluate the mechanical factors that may be important in controlling deformation. My field- and remotely-based mapping of active faults and folds, supplemented by results from my paleoseismic studies and physical models of the system, suggest that Java’s deformation is distributed over broad areas along small-scale structures. Java is segmented into three main zones based on their distinctive structural patterns and stress orientation. East Java is characterized by NW-SE normal and strike-slip faults, Central Java has E-W folds and thrust faults, and NE-SW strike-slip faults dominate West Java. The sandbox analog models indicate that the strain in response to collision is partitioned into thrusting and strike-slip faulting, with the dominance of margin-normal thrust faulting. My models test the effects of convergence obliquity, geometry, preexisting weaknesses, asperities, and lateral strength contrast. The result suggest that slight variations in convergence obliquity do not affect the deformation pattern significantly, while the margin shape, lateral strength contrast, and perturbation of deformation from asperities each have a greater impact on deformation.
ContributorsMarliyani, Gayatri Indah (Author) / Arrowsmith, J Ramon (Thesis advisor) / Clarke, Amanda B (Committee member) / Hartnett, Hilairy (Committee member) / Whipple, Kelin (Committee member) / Garnero, Edward (Committee member) / Arizona State University (Publisher)
Created2016
Description
Organic compounds are influenced by hydrothermal conditions in both marine and terrestrial environments. Sedimentary organic reservoirs make up the largest share of organic carbon in the carbon cycle, leading to petroleum generation and to chemoautotrophic microbial communities. There have been numerous studies on the reactivity of organic compounds in water at elevated temperatures, but these studies rarely explore the consequences of inorganic solutes in hydrothermal fluids. The experiments in this thesis explore new reaction pathways of organic compounds mediated by aqueous and solid phase metals, mainly Earth-abundant copper. These experiments show that copper species have the potential to oxidize benzene and toluene, which are typically viewed as unreactive. These pathways add to the growing list of known organic transformations that are possible in natural hydrothermal systems. In addition to the characterization of reactions in natural systems, there has been recent interest in using hydrothermal conditions to facilitate organic transformations that would be useful in an applied, industrial or synthetic setting. This thesis identifies two sets of conditions that may serve as alternatives to commonplace industrial processes. The first process is the oxidation of benzene with copper to form phenol and chlorobenzene. The second is the copper mediated dehalogenation of aryl halides. Both of these processes apply the concepts of geomimicry by carrying out organic reactions under Earth-like conditions. Only water and copper are needed to implement these processes and there is no need for exotic catalysts or toxic reagents.
ContributorsLoescher, Grant (Author) / Shock, Everett (Thesis advisor) / Hartnett, Hilairy (Committee member) / Gould, Ian (Committee member) / Arizona State University (Publisher)
Created2020