Matching Items (8)
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- All Subjects: Geochemistry
- Creators: Whipple, Kelin
- Creators: School of Earth and Space Exploration
- Resource Type: Text
- Status: Published
Description
In this study, the influence of fluid mixing on temperature and geochemistry of hot spring fluids is investigated. Yellowstone National Park (YNP) is home to a diverse range of hot springs with varying temperature and chemistry. The mixing zone of interest in this paper, located in Geyser Creek, YNP, has been a point of interest since at least the 1960’s (Raymahashay, 1968). Two springs, one basic (~pH 7) and one acidic (~pH 3) mix together down an outflow channel. There are visual bands of different photosynthetic pigments which suggests the creation of temperature and chemical gradients due to the fluids mixing. In this study, to determine if fluid mixing is driving these changes of temperature and chemistry in the system, a model that factors in evaporation and cooling was developed and compared to measured temperature and chemical data collected downstream. Comparison of the modeled temperature and chemistry to the measured values at the downstream mixture shows that many of the ions, such as Cl⁻, F⁻, and Li⁺, behave conservatively with respect to mixing. This indicates that the influence of mixing accounts for a large proportion of variation in the chemical composition of the system. However, there are some chemical constituents like CH₄, H₂, and NO₃⁻, that were not conserved, and the concentrations were either depleted or increased in the downstream mixture. Some of these constituents are known to be used by microorganisms. The development of this mixing model can be used as a tool for predicting biological activity as well as building the framework for future geochemical and computational models that can be used to understand the energy availability and the microbial communities that are present.
ContributorsOrrill, Brianna Isabel (Author) / Shock, Everett (Thesis director) / Howells, Alta (Committee member) / School of Life Sciences (Contributor) / School of Earth and Space Exploration (Contributor) / Barrett, The Honors College (Contributor)
Created2021-05
Description
There are many outstanding questions regarding the petrologic processes that give rise to andesitic and basaltic magmas in subduction zones, including the specifics that govern their geographical distribution in a given arc segment. Here I investigate the genesis of calc-alkaline and tholeiitic basalts from the Lassen Volcanic Center in order to determine the pressure, temperature, source composition, and method of melting that lead to the production of melt in the mantle below Lassen. To this aim, a suite of primitive basalts (i.e. SiO2<52 and Mg#>65) are corrected for fractional crystallization by adding minerals back to the bulk rock composition with the goal of returning them to a primary composition in equilibrium with the mantle. Thermobarometry of the primary melt compositions is conducted to determine temperature and pressure of melting, in addition to a forward mantle modeling technique to simulate mantle melting at varying pressures to constrain source composition and method of melting (batch vs. fractional). The results from the two techniques agree on an average depth of melt extraction of 36 km and a source composition similar to that of depleted mantle melted by batch melting. Although attempted for both calc-alkaline and tholeiitic basalts, the fractional crystallization correction and thus the pressure-temperature calculations were only successful for tholeiitic basalts due to the hydrous nature of the calc-alkaline samples. This leaves an opportunity to repeat this study with parameters appropriate for hydrous basalts, allowing for the comparison of calc-alkaline and tholeiitic melting conditions.
ContributorsSheppard, Katherine Davis (Author) / Till, Christy (Thesis director) / Hervig, Richard (Committee member) / Barrett, The Honors College (Contributor) / School of Earth and Space Exploration (Contributor)
Created2015-05
Description
The South Tibetan Detachment System (STDS) marks a major decoupling horizon in the Himalaya, separating the highly metamorphosed infrastructure in the footwall from the weakly to unmetamorphosed superstructure in the hanging wall. The STDS stretches the entire range and is likely one of the most significant deformational features of the orogen, but its spatial and temporal evolution remain relatively unconstrained. As its name suggests, the STDS is a system of faults which occur at slightly different structural levels and are often diachronous. Detailed studies on the different strands are needed to understand the slip history of the system as a whole, which in turn will improve understanding of Himalayan orogenesis, thus informing tectonic models for continental orogenesis in general. I focus on some of the best exposed strands of the STDS which are located in the Annapurna region of Nepal. Outcrops within the shear zones of basal structures in the Kali Gandaki and Marsyandi valleys – the Annapurna and Chame detachments – contain leucogranites that are variably deformed via ductile slip on the detachments. I used U/Pb zircon and Th/Pb monazite geochronology to constrain emplacement ages of these leucogranites, which suggest ductile slip ceased prior to 14.95 ± 0.78 Ma and 16.0 ± 1.1 Ma on the Annapurna and Chame detachments respectively. 40Ar/ 39Ar muscovite and biotite, (U-Th)/He zircon and apatite thermochronology data and resulting thermal-kinematic models for samples I collected in the shear zones and footwalls of these detachments suggest further slip was ongoing on both detachments until ca. 12 Ma, although the majority of slip on the Chame detachment likely ceased by ca. 15-14 Ma. I also collected samples in the footwall of a structurally higher detachment in the Marsyandi and the resulting cooling ages and thermal-kinematic models suggest slip was contemporaneous with that on the lower Chame detachment. The new constraints on N-S extension on the STDS in the Annapurna region presented in this dissertation call into question the popular idea of a geodynamic change from N-S to E-W extension in the central Himalaya during the early Miocene, and emphasize the importance of the STDS as a major decoupling horizon.
ContributorsPye, Alexandra Eleanor (Author) / Hodges, Kip (Thesis advisor) / Whipple, Kelin (Committee member) / Barboni, Melanie (Committee member) / van Soest, Matthijs (Committee member) / McDonald, Christopher (Committee member) / Arizona State University (Publisher)
Created2022
Description
The Greater Obsidian Pool Area just south of the Mud Volcano area in Yellowstone National Park is an active and ever-changing hot spring region. Situated next to a lake in a meadow between several hills of glacial deposits, north of the Elephant Back rhyolite flow, a diverse group of hot springs has been developing. This study examines the geologic and geomorphic context of the hot springs, finding evidence for a previously undiscovered hydrothermal explosion crater and examining the deposits around the region that contribute to properties of the groundwater table. Hot spring geochemical measurements (Cl- and SO4-2) taken over the course of 20 years are used to determine fluid sourcing of the springs. The distribution of Cl-, an indicator of water-rock interaction, in the hot springs leads to the theory of a fissure delivering hydrothermal fluid in a line across the hot spring zone, with meteoric water from incoming groundwater diluting hot springs moving further from the fissure. A possible second dry fissure delivering mostly gas is also a possible explanation for some elevated sulfate concentrations in certain springs. The combination of geology, geomorphology, and geochemistry reveals how the surface and subsurface operate to generate different hot spring compositions.
ContributorsAlexander, Erin (Author) / Shock, Everett (Thesis director) / Whipple, Kelin (Committee member) / Barrett, The Honors College (Contributor) / School of Earth and Space Exploration (Contributor) / School of Molecular Sciences (Contributor)
Created2022-05
Description
During the Dawn mission, bright spots were discovered on the surface of the dwarf planet Ceres, which were determined to be evaporite deposits of sodium carbonate, ammonium carbonate, and hydrohalite. These deposits are significant because they indicate the presence of subsurface water and potential geologic activity on Ceres. These evaporites form from the brine-water mixture in the deep Ceres reservoir, which likely possesses the conditions ideal for forming complex organics. Here, we report the results of a suite of laboratory techniques (CHN Elemental Analyzer, Secondary Ion Mass Spectrometry, Fourier-Transform Infrared Spectroscopy, Gas Chromatography, and Brunauer-Emmett-Teller Analysis) for quantifying the likelihood of primordial carbon survival and distribution in analog materials found on Ceres, particularly in salt evaporates. We are specifically looking at if the amino acid glycine can be preserved in sodium chloride crystals. Our results conclude that if the Ceres brine reservoir is saturated with organics, and with the lower limits that we have for our instrumentation thus far, these techniques should be more than sufficient to measure glycine content should we ever receive samples from Ceres.
ContributorsReynoso, Lucas (Author) / Bose, Maitrayee (Thesis director) / Castillo-Rogez, Julie (Committee member) / Barrett, The Honors College (Contributor) / Mechanical and Aerospace Engineering Program (Contributor) / School of Earth and Space Exploration (Contributor)
Created2023-05
Description
Chemical and physical interactions of flowing ice and rock have inexorably shaped planetary surfaces. Weathering in glacial environments is a significant link in biogeochemical cycles – carbon and strontium – on Earth, and may have once played an important role in altering Mars’ surface. Despite growing recognition of the importance of low-temperature chemical weathering, these processes are still not well understood. Debris-coated glaciers are also present on Mars, emphasizing the need to study ice-related processes in the evolution of planetary surfaces. During Earth’s history, subglacial environments are thought to have sheltered communities of microorganisms from extreme climate variations. On Amazonian Mars, glaciers such as lobate debris aprons (LDA) could have hosted chemolithotrophic communities, making Mars’ present glaciers candidates for life preservation. This study characterizes glacial processes on both Earth and Mars.
Chemical weathering at Robertson Glacier, a small alpine glacier in the Canadian Rocky Mountains, is examined with a multidisciplinary approach. The relative proportions of differing dissolution reactions at various stages in the glacial system are empirically determined using aqueous geochemistry. Synthesis of laboratory and orbital thermal infrared spectroscopy allows identification of dissolution rinds on hand samples and characterization of carbonate dissolution signals at orbital scales, while chemical and morphological evidence for thin, discontinuous weathering rinds at microscales are evident from electron microscopy. Subglacial dissolution rates are found to outpace those of the proglacial till plain; biologically-mediated pyrite oxidation drives the bulk of this acidic weathering.
Second, the area-elevation relationship, or hypsometry, of LDA in the midlatitudes of Mars is characterized. These glaciers are believed to have formed ~500 Ma during a climate excursion. Hypsometric measurements of these debris-covered glaciers enable insight into past flow regimes and drive predictions about past climate scenarios. The LDA in this study fall into three major groups, strongly dependent on basal elevation, implying regional and climatic controls on ice formation and flow.
I show that biologically-mediated mineral reactions drive high subglacial dissolution rates, such that variations within the valley can be detected with remote sensing techniques. In future work, these insights can be applied to examining Mars’ glacial regions for signs of chemical alteration and biosignatures.
Chemical weathering at Robertson Glacier, a small alpine glacier in the Canadian Rocky Mountains, is examined with a multidisciplinary approach. The relative proportions of differing dissolution reactions at various stages in the glacial system are empirically determined using aqueous geochemistry. Synthesis of laboratory and orbital thermal infrared spectroscopy allows identification of dissolution rinds on hand samples and characterization of carbonate dissolution signals at orbital scales, while chemical and morphological evidence for thin, discontinuous weathering rinds at microscales are evident from electron microscopy. Subglacial dissolution rates are found to outpace those of the proglacial till plain; biologically-mediated pyrite oxidation drives the bulk of this acidic weathering.
Second, the area-elevation relationship, or hypsometry, of LDA in the midlatitudes of Mars is characterized. These glaciers are believed to have formed ~500 Ma during a climate excursion. Hypsometric measurements of these debris-covered glaciers enable insight into past flow regimes and drive predictions about past climate scenarios. The LDA in this study fall into three major groups, strongly dependent on basal elevation, implying regional and climatic controls on ice formation and flow.
I show that biologically-mediated mineral reactions drive high subglacial dissolution rates, such that variations within the valley can be detected with remote sensing techniques. In future work, these insights can be applied to examining Mars’ glacial regions for signs of chemical alteration and biosignatures.
ContributorsRutledge, Alicia Marie (Author) / Christensen, Philip R. (Thesis advisor) / Shock, Everett (Committee member) / Clarke, Amanda (Committee member) / Sharp, Thomas (Committee member) / Whipple, Kelin (Committee member) / Arizona State University (Publisher)
Created2015
Description
Shallow earthquakes in the upper part of the overriding plate of subduction zones can be devastating due to their proximity to population centers despite the smaller rupture extents than commonly occur on subduction megathrusts that produce the largest earthquakes. Damaging effects can be greater in volcanic arcs like Java because ground shaking is amplified by surficial deposits of uncompacted volcaniclastic sediments. Identifying the upper-plate structures and their potential hazards is key for minimizing the dangers they pose. In particular, the knowledge of the regional stress field and deformation pattern in this region will help us to better understand how subduction and collision affects deformation in this part of the overriding plate. The majority of the upper plate deformation studies have been focused on the deformation in the main thrusts of the fore-arc region. Study of deformation within volcanic arc is limited despite the associated earthquake hazards. In this study, I use maps of active upper-plate structures, earthquake moment tensor data and stress orientation deduced from volcano morphology analysis to characterize the strain field of Java arc. In addition, I use sandbox analog modeling to evaluate the mechanical factors that may be important in controlling deformation. My field- and remotely-based mapping of active faults and folds, supplemented by results from my paleoseismic studies and physical models of the system, suggest that Java’s deformation is distributed over broad areas along small-scale structures. Java is segmented into three main zones based on their distinctive structural patterns and stress orientation. East Java is characterized by NW-SE normal and strike-slip faults, Central Java has E-W folds and thrust faults, and NE-SW strike-slip faults dominate West Java. The sandbox analog models indicate that the strain in response to collision is partitioned into thrusting and strike-slip faulting, with the dominance of margin-normal thrust faulting. My models test the effects of convergence obliquity, geometry, preexisting weaknesses, asperities, and lateral strength contrast. The result suggest that slight variations in convergence obliquity do not affect the deformation pattern significantly, while the margin shape, lateral strength contrast, and perturbation of deformation from asperities each have a greater impact on deformation.
ContributorsMarliyani, Gayatri Indah (Author) / Arrowsmith, J Ramon (Thesis advisor) / Clarke, Amanda B (Committee member) / Hartnett, Hilairy (Committee member) / Whipple, Kelin (Committee member) / Garnero, Edward (Committee member) / Arizona State University (Publisher)
Created2016
Description
The collision between the Indian and Eurasian tectonic plates marked the onset of the rise of the Himalayan-Tibetan orogen, but also brought about profound changes to the Earth's oceans and climate. The exact sequence of events that occurred during this collision is poorly understood, leading to a wide range of estimates of its age. The Indus and Yarlung sutures are generally considered to represent the final collision between India and Eurasia, and together form a mostly continuous belt that can be traced over 2000 km along strike. In the western portions of the orogen the Karakoram Fault introduces a key complexity to the study of timing of collision by offsetting the Indus and Yarlung sutures. Recent work has used the complexities introduced by the Karakoram Fault to suggest that the more northerly Shyok suture, not the Indus suture, represents the India-Eurasia collision zone. Estimates for timing of the India-Eurasia collision fall into one of three groups: 40-34 Ma, 55-50 Ma, and 66-60 Ma. Attempts to reconcile these models have thus far been unsuccessful. In order to provide additional data that might further clarify the timing and location of collision, studies have been performed along the Shyok suture in India and along the Yarlung suture in Tibet at Sangsang. A study along the Shyok suture argues that the suture formed between 92-85 Ma. This timing precludes an interpretation that the Shyok suture marks the location of the India-Eurasia collision. A second study demonstrates the utility of two new geochronometers, (U-Th)/Pb joaquinite and 40Ar/39Ar neptunite, that play an important role in unraveling the tectonic history of the Yarlung suture. A third study is an investigation of the structure and geochronology of the Sangsang ophiolite complex. Here, multiple (U-Th)/Pb and 40Ar/39Ar systems record magmatism and metamorphism spanning ca. 125-52 Ma. By tying these chronometers to tectonic process, a history is reconstructed of the southern margin of Tibet that includes Early Cretaceous to Late Cretaceous forearc rifting associated with mid ocean ridge subduction, Paleocene accretionary wedge uplift and erosion, and finally Eocene metasomatism and collision.
ContributorsBorneman, Nathaniel (Author) / Hodges, Kip (Thesis advisor) / Reynolds, Stephen (Committee member) / Whipple, Kelin (Committee member) / Sharp, Thomas (Committee member) / Tyburczy, James (Committee member) / Arizona State University (Publisher)
Created2016