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- All Subjects: Origami
- Creators: Zhuang, Houlong
In this dissertation, vapor phase transport is used to synthesize layer structured gallium chalcogenide nanomaterials with highly controlled structure, morphology and properties, with particular emphasis on GaSe, GaTe and GaSeTe alloys. Multiple routes are used to manipulate the physical properties of these materials including strain engineering, defect engineering and phase engineering. First, 2D GaSe with controlled morphologies is synthesized on Si(111) substrates and the bandgap is significantly reduced from 2 eV to 1.7 eV due to lateral tensile strain. By applying vertical compressive strain using a diamond anvil cell, the band gap can be further reduced to 1.4 eV. Next, pseudo-1D GaTe nanomaterials with a monoclinic structure are synthesized on various substrates. The product exhibits highly anisotropic atomic structure and properties characterized by high-resolution transmission electron microscopy and angle resolved Raman and photoluminescence (PL) spectroscopy. Multiple sharp PL emissions below the bandgap are found due to defects localized at the edges and grain boundaries. Finally, layer structured GaSe1-xTex alloys across the full composition range are synthesized on GaAs(111) substrates. Results show that GaAs(111) substrate plays an essential role in stabilizing the metastable single-phase alloys within the miscibility gaps. A hexagonal to monoclinic phase crossover is observed as the Te content increases. The phase crossover features coexistence of both phases and isotropic to anisotropic structural transition.
Overall, this work provides insights into the controlled synthesis of gallium chalcogenides and opens up new opportunities towards optoelectronic applications that require tunable material properties.
The goal of this experiment was to examine the energy absorption properties of origami-inspired honeycomb and standard honeycomb structures. These structures were 3D printed with two different materials: thermoplastic polyurethane (TPU) and acrylonitrile butadiene styrene (ABS). Quasi-static compression testing was performed on these structures for both types and materials at various wall thicknesses. The energy absorption and other material properties were analyzed for each structure. Overall, the results indicate that origami-inspired structures perform best at energy absorption at a higher wall thickness with a rigid material. The results also indicated that standard honeycomb structures perform better with lower wall thickness, and also perform better with a rigid, rather than a flexible material. Additionally, it was observed that a flexible material, like TPU, better demonstrates the folding and recovery properties of origami-inspired structures. The results of this experiment have applications wherever honeycomb structures are used, mostly on aircraft and spacecraft. In vehicles with structures of a sufficiently high wall thickness with a rigid material, origami-inspired honeycomb structures could be used instead of current honeycomb structures in order to better protect the passengers or payload through improved energy absorption.
