Matching Items (2)
Filtering by

Clear all filters

149998-Thumbnail Image.png
Description
As the 3rd generation solar cell, quantum dot solar cells are expected to outperform the first 2 generations with higher efficiency and lower manufacture cost. Currently the main problems for QD cells are the low conversion efficiency and stability. This work is trying to improve the reliability as well as

As the 3rd generation solar cell, quantum dot solar cells are expected to outperform the first 2 generations with higher efficiency and lower manufacture cost. Currently the main problems for QD cells are the low conversion efficiency and stability. This work is trying to improve the reliability as well as the device performance by inserting an interlayer between the metal cathode and the active layer. Titanium oxide and a novel nitrogen doped titanium oxide were compared and TiOxNy capped device shown a superior performance and stability to TiOx capped one. A unique light anneal effect on the interfacial layer was discovered first time and proved to be the trigger of the enhancement of both device reliability and efficiency. The efficiency was improved by 300% and the device can retain 73.1% of the efficiency with TiOxNy when normal device completely failed after kept for long time. Photoluminescence indicted an increased charge disassociation rate at TiOxNy interface. External quantum efficiency measurement also inferred a significant performance enhancement in TiOxNy capped device, which resulted in a higher photocurrent. X-ray photoelectron spectrometry was performed to explain the impact of light doping on optical band gap. Atomic force microscopy illustrated the effect of light anneal on quantum dot polymer surface. The particle size is increased and the surface composition is changed after irradiation. The mechanism for performance improvement via a TiOx based interlayer was discussed based on a trap filling model. Then Tunneling AFM was performed to further confirm the reliability of interlayer capped organic photovoltaic devices. As a powerful tool based on SPM technique, tunneling AFM was able to explain the reason for low efficiency in non-capped inverted organic photovoltaic devices. The local injection properties as well as the correspondent topography were compared in organic solar cells with or without TiOx interlayer. The current-voltage characteristics were also tested at a single interested point. A severe short-circuit was discovered in non capped devices and a slight reverse bias leakage current was also revealed in TiOx capped device though tunneling AFM results. The failure reason for low stability in normal devices was also discussed comparing to capped devices.
ContributorsYu, Jialin (Author) / Jabbour, Ghassan E. (Thesis advisor) / Alford, Terry L. (Thesis advisor) / Yu, Hongbin (Committee member) / Arizona State University (Publisher)
Created2011
157065-Thumbnail Image.png
Description
The detection and segmentation of objects appearing in a natural scene, often referred to as Object Detection, has gained a lot of interest in the computer vision field. Although most existing object detectors aim to detect all the objects in a given scene, it is important to evaluate whether these

The detection and segmentation of objects appearing in a natural scene, often referred to as Object Detection, has gained a lot of interest in the computer vision field. Although most existing object detectors aim to detect all the objects in a given scene, it is important to evaluate whether these methods are capable of detecting the salient objects in the scene when constraining the number of proposals that can be generated due to constraints on timing or computations during execution. Salient objects are objects that tend to be more fixated by human subjects. The detection of salient objects is important in applications such as image collection browsing, image display on small devices, and perceptual compression.

This thesis proposes a novel evaluation framework that analyses the performance of popular existing object proposal generators in detecting the most salient objects. This work also shows that, by incorporating saliency constraints, the number of generated object proposals and thus the computational cost can be decreased significantly for a target true positive detection rate (TPR).

As part of the proposed framework, salient ground-truth masks are generated from the given original ground-truth masks for a given dataset. Given an object detection dataset, this work constructs salient object location ground-truth data, referred to here as salient ground-truth data for short, that only denotes the locations of salient objects. This is obtained by first computing a saliency map for the input image and then using it to assign a saliency score to each object in the image. Objects whose saliency scores are sufficiently high are referred to as salient objects. The detection rates are analyzed for existing object proposal generators with respect to the original ground-truth masks and the generated salient ground-truth masks.

As part of this work, a salient object detection database with salient ground-truth masks was constructed from the PASCAL VOC 2007 dataset. Not only does this dataset aid in analyzing the performance of existing object detectors for salient object detection, but it also helps in the development of new object detection methods and evaluating their performance in terms of successful detection of salient objects.
ContributorsKotamraju, Sai Prajwal (Author) / Karam, Lina J (Thesis advisor) / Yu, Hongbin (Committee member) / Jayasuriya, Suren (Committee member) / Arizona State University (Publisher)
Created2019